欢迎登录材料期刊网

材料期刊网

高级检索

以双(烷氧-亚胺芳氧)基钛(Ⅳ)配合物(BAIP-Ti(Ⅳ))为催化剂催化D,L-丙交酯开环聚合合成的Ti-P聚乳酸,用静态水接触角、吸水率及降解实验考察其理化性能,以小鼠颅顶前骨细胞(MC3T3-E1)考察其在材料表面的增值和黏附铺展情况.结果表明:Ti-P聚乳酸比Sn-P聚乳酸有较低的亲水性和较高的抗水解性;MC3T3-E1细胞在Ti-P聚乳酸材料表面显示出的较好的增值活力以及细胞黏附与铺展能力;在Ti-P聚乳酸中残存的微量Ti(Ⅳ)金属配合物对MC3T3-E1细胞无细胞毒性,不影响MC3T3-E1细胞在其材料表面上生长.

参考文献

[1] Z.Zhong,P.J.Dijkstra,J.Feijen,Controlled and stereoselective polymerization of lactide:kinetics,selectivity,and microstructures,Journal of American Chemical Society,125(37),11291(2003)
[2] H.R.Kricheldoff,I.Kreiser-Saunders,C.Boettcherl,Polylactones:31.Sn(Ⅱ) octoate-initiated polymerization of L-Lactide:a mechanistic study,Polymer,36(6),1253(1995)
[3] C.P.Radano,G.L.Baker,M.R.Smith,Stereoselective polymerization of a racemic monomer with a racemic catalyst:direct preparation of the polylactic acid stereocomplex from racemic lactide,Journal of American Chemical Society,122(7),1552(2000)
[4] A.John,V.Katiyar,K.Pang,M.M.Shaikh,H.Nanavati,P.Ghosh,Ni(Ⅱ) and Cu(Ⅱ) complexes of phenoxy-ketimine ligands:synthesis,structures and their utility in bulk ring-opening polymerization (ROP) of L-Lactide,Polyhedron,26(15),4033(2007)
[5] A.Amgoune,C.M.Thomas,T.Roisnel,Ring-opening polymerization of lactide with group 3 metal complexes supported by dianionic alkoxy-amino-bisphenolate ligand:combining high activity,productivity,andselectivity,Chemistry-A European Journal,12(1),169 (2005)
[6] N.Nomura,R.Ishii,Y.Yamamoto,T.Kondo,Stereoselective ringopening polymeization of a racemic Lactide by using achiral salenand homosalen-aluminum complexes,Chemistry-A European Journal,13(16),4433(2007)
[7] D.J.Darensbourg,O.Karroonnirun,Stereoselective ring-opening polymerization of rac-Lactides catalyzed by chiral and achiral aluminum Half-Salen complexes,Organometallics,29(21),5627(2010)
[8] H.Ma,J.Okuda,Kinetic and Mechanism of L-lactide polymerization by rare earth metal silylamido complexes:effect of alcohol addition,Macromolecules,38(7),2665(2005)
[9] M.H.Chisholm,Catalytic formation of cyclic-esters and depsipeptides and chemical amplification by complexation with sodium ions,Journal of Organometallic Chemistry,693(5),808(2008)
[10] C.Hu,Y.Wang,H.Xiang,Y.Fu,C.Fu,J.Sun,Y.Xiang,C.Ruan,X.Li,Synthesis and characterization of Ti(Tbse)2 and its application as a catalyst for ROP of rac-Lactide,Polymer International,61 (10),1564(2012)
[11] C.Hu,Y.Fu,H.Xiang,Y.Fu,J.Sun,M.Deng,X.Xiang,The Novel[(dlME)2(HIM)P]2Ti (Ⅳ) Complex:synthesize,characterization and its utility in ROP of D,L-Lactide,Polymer Bulletin,69(5),511 (2012)
[12] HU Chengbo,FU Ya,XIANG Hongzhao,SUN Jiaoxia,RUAN Clangshun,LI Xiang,XIANG Yan,PENG Qin,WANG Yuanliang,ROP of D,L-Lactide catalyzed by bis(alkoxy-imine-phenoxy) titanium(Ⅳ) complex:kinetic and mechanism,Acta Chimica Sinica,69(21),2574(2011)(胡承波,傅亚,向鸿照,孙娇霞,阮长顺,李香,向燕,彭琴,王远亮,双(烷氧-亚胺芳氧)基钛(Ⅳ)配合物催化D,L-丙交酯开环聚合、动力学及机理,69(21),2574(2011))
[13] HU Chengbo,XU Qiang,WANG Yuanliang,ZHENG Shiyuan,Microstructure analysis of Ti-P polylactide synthesized by titanium (Ⅳ) complex as catalyst,21(4),18(2013)(胡承波,徐强,王远亮,郑士远,钛(Ⅳ)配合物催化合成TI-P聚乳酸材料微观结构分析,21(4),18(2013))
[14] S.Kalhara,S.Matsumura,A.G.Mikos,J.P.Fisher,Synthesis of poly(L-lactide) and polyglycolide by Ring-opening polymerization,Nature protocols,2(11),2767(2007)
[15] K.B.Vartanian,S.J.Kirkpatrick,S.R.Hanson,M.T.Hinds,Endothelial cell cytoskeletal alignment independent of fluid shear stress on micropatterned surfaces,Biochemical and Biophysical Research Communications,371(4),787(2008)
[16] CAI Qing,BEI Jianzhong,WANG Shenguo,WANG Changyong,FAN Ming,LIU Shuang,ZHAO Qiang,Study on the biocompatibility and degradation behavior of polyl(l-lactide-co-glycolide) in vitro and in vivo,Journal of Functional Polymers,13(3),249(2000)(蔡晴,贝建中,王身国,王常勇,范明,刘爽,赵强,乙交酯/丙交酯共聚物的体内外降解行为及生物相容性研究,功能高分子学报,13(3),249(2000))
[17] X.Wu,N.Wang,Synthesis,characterization,biodegradation,and drug delivery application of biodegradable lactic/glycolic acid polymers.Part Ⅱ:Biodegradation,Journal of Biomaterials SciencePolymer Edition,12(1),21(2001)
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%