通过熔融共混制备了有机蒙脱土(OMMT)/聚氧化乙烯(PEO)-聚丙烯(PP)复合材料,采用TEM、SEM、DSC、透光率分析等手段研究了OMMT在PEO-PP共混物中的分布及OMMT对共混物相形态、OMMT含量对复合材料透光率的影响.结果表明,OMMT选择性分布在PEO分散相内部及两相界面,对PEO-PP共混物起到增容作用,OMMT的加入使PEO相粒径得到细化,粒径尺寸趋于均匀,PP球晶尺寸明显减小,复合材料的透明性显著增加.
参考文献
| [1] | Feng Meng,Gong Fangling,Zhao Chungui.Effect of clay on the morphology of blends of polypropylene and polyamide 6/clay nanocomposites[J].Polymer International,2004,53(10):1529-1537. |
| [2] | Su Quansheng,Feng Meng,Zhang Shimin.Melt blending of polypropylene-blend-polyamide 6-blend-organoclay systems[J].Polymer International,2007,56(1):50-56. |
| [3] | Kelarakis A,Yoon K.Optical transparency in a polymer blend induced by clay nanofillers[J].European Polymer Journal,2008,44(12):3941-3945. |
| [4] | Gelfer M Y,Song H H,Liu L,et al.Effects of organoclays on morphology and thermal and rheological properties of polystyrene and poly(methyl methacrylate)blends[J].Journal of Polymer Science Part B:Polymer Physics,2003,41(1):44-54. |
| [5] | Wang Y,Zhang Q,Fu Q Compatibilization of immiscible poly(propylene)/polystyrene blends using clay[J].Macromolecular Rapid Communications,2003,24(3):231-235. |
| [6] | Zhu Yan,Ma Haiyun,Tong Lifang,et al."Cutting effect"of organoclay platelets in compatibilizing immiscible polypropylene/potystyrene blends[J].Journal of Zhejiang University Science A,2008,9(11):1614-1620. |
| [7] | Si M,Araki T,Ade H,et al.Compatibilizing bulk polymer blends by using organoclays[J].Maeromoleeules,2006,39(14):4793-4801. |
| [8] | Austin J R,Kontopoulou M.Effect of organoclay content on the rheology morphology,and physical properties of polyolefin elastomers and their blends with polypropylene[J].Polymer Engineering and Science,2006,46(11):1491-1501. |
| [9] | 于杰,严伟,秦舒浩,等.SMA、OMMT对PA6/ABS共混物聚集态结构及性能影响的研究[J].高分子学报,2009(9):896-902.Yu Jie,Yan Wei,Qin Shuhao,et al.The effect of SMA,OMMT on the morphology and mechanical properties of PA6/ABS blends[J].Acta Polymerica Sinica,2009(9):896-902. |
| [10] | 严伟,秦舒浩,于杰,等.有机蒙脱土对ABS-PA6共混物形态结构与力学性能的影响[J].复合材料学报,2010,27(2):37-41.Yan Wei,Qin Shuhao,Yu Jie,et al.Effects of organic montmorillonite on morphology and mechanical properties of acrylonitrile-butadiene-styrene(ABS)-polyamide 6(PA6)blends[J].Acts Materiae Compositae Sinica,2010,27(2):37-41. |
| [11] | Li Y,Shimizu H.Novel morphologies of poly(phenylene oxide)(PPO)/polyamide 6(PA6)blend nanocomposites[J].Polymer,2004,45(22):7381-7388. |
| [12] | Khatua B B,Lee D J,Kim H Y,et al.Effect of organoclay platelets on morphology of nylon-6 and poly(ethylene-ranpropylene)rubber blends[J].Macromolecules,2004,37(7):2454-2459. |
| [13] | Li Yuanqing,Fu Shaoyin,Mai Yiuwing,et al.Preparation and characterization of transparent ZnO/epoxy nanocomposites with high-UV shielding efficiency[J].Polymer,2006,47(6):2127-2132. |
| [14] | Ryszkowska J.Zawadzak E A,Lojkowski W,et al.Structure and properties of polyurethane nanocomposites with zirconium oxide including Eu[J].Mater Sci Eng C,2007,27(5/8):994-997. |
| [15] | Sumita M,Sakata K,Asai S.et al.Dispersion of fillers and the electrical conductivity of polymer blends filled with carbon black[J].Polymer Bulletin,1991,25(2):265-271. |
| [16] | 美国科诺工业有限公司.Solid surface energy data(SFE)for common polymers[EB/OL].[2007-11-20].http://www.surface-tension.de/solid-surface-energy.htm. |
| [17] | Xue Jiangjiang,Zhang Yong,Zhang Yinxi.Crystallization behavior of dynamically cured polypropylene/epoxy blends[J].Journal of Polymer Science Part B:Polymer Physics,2004,42(7):1181-1191. |
| [18] | 程金树,郑伟宏,楼贤春,等.MgO/ZnO对锂铝系微晶玻璃性能的影响[J].武汉理工大学学报,2006,28(2):4-6.Cheng Jinshu,Zheng Weihong,Lou Xianchun,et al.Influence of MgO/ZnO on the properties of LAS glass-ceramic[J].Journal of Wuhan University of Technology,2006,28(2):4-6. |
| [19] | Kerker M.The scattering of light and other electromagnetic radiation[M].New York;Academic Press,1969:666. |
| [20] | Li Yuanqing,Fu Shaoyun,Yang Yang,et al.Mai facile synthesis of highly transparent polymer nanocomposites by introduction of core-shell structured nanoparticles[J].Chemistry of Materials,2008,20(8):2637-2643. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%