用环氧树脂、氨基聚丁二烯(ATB)和氨基丁腈(ATBN)、三乙烯四胺制备了软段含量从59％至82％的ATB/ATBN系列试样.利用动态力学分析、应力-应变、扫描电镜等方法研究了系列试样的低温性质,并且在恒应变下进行了动态力学分析验证.结果表明,环氧树脂与ATB/ATBN能在广泛的比例反应,具有两相结构.软段丁g不随软段含量变化,而硬段Tg随硬段含量变化.ATB系列在宽温域模量为一个平台,在低温(可达-70℃)仍能保持弹性材料的特征.环氧增强的ATB和ATBN都可以作为低温弹性材料使用.
参考文献
| [1] | 孙涛,官建国,余剑英,苏良碧.端氨基聚氨酯的合成及增韧环氧树脂的研究[J].高分子材料科学与工程,2005(01):117-120,124. |
| [2] | 吕树斌,何毅,施太和,任建.钻杆用环氧树脂内涂层的微观结构及性能评价[J].表面技术,2011(02):101-103. |
| [3] | Hsieh, T.H.;Kinloch, A.J.;Masania, K.;Taylor, A.C.;Sprenger, S. .The mechanisms and mechanics of the toughening of epoxy polymers modified with silica nanoparticles[J].Polymer: The International Journal for the Science and Technology of Polymers,2010(26):6284-6294. |
| [4] | R. J. Day;P. A. Lovell;A. A. Wazzan .Toughened carbon/epoxy composites made by using core/shell particles[J].Composites science and technology,2001(1):41-56. |
| [5] | L. Calabrese;A. Valenza .The effect of a liquid CTBN rubber modifier on the thermo-kinetic parameters of an epoxy resin during a pultrusion process[J].Composites science and technology,2003(6):851-860. |
| [6] | Zhang, J.;Wang, Z.;Ding, G.;Quan, Y.;Chen, Q. .The effect of epoxy resin to reduce the compression set of polysulfide sealant[J].Journal of Applied Polymer Science,2012(1):390-395. |
| [7] | Kar S;Banthia AK .Synthesis and evaluation of liquid amine-terminated polybutadiene rubber and its role in epoxy toughening[J].Journal of Applied Polymer Science,2005(6):2446-2453. |
| [8] | 耿洪斌,汤继俊,王智勇,陈庆民.环氧/丁腈胶粘剂的两相结构、形态及性能[J].高分子材料科学与工程,2007(04):163-166. |
| [9] | Soares BG;Goncalez V;Galimberti R;Sirqueira AS;Barcia FL;Simao RA .Toughening of an epoxy resin with an isocyanate-terminated polyether[J].Journal of Applied Polymer Science,2008(1):159-166. |
| [10] | 潘勤彦,杨果,付绍云.聚氨酯改性环氧树脂体系的力学性能研究[J].绝缘材料,2007(02):28-30,32. |
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