以甲基丙烯酸十二氟庚酯(DHFMA)和甲基丙烯酸(MAA)为单体,通过溶液聚合制备出MAA含量不同的羧基氟碳共聚物(DHFMA-co-MAA),并通过静电纺丝装置制备了羧基氟碳共聚物纤维膜.研究了MAA含量和溶剂对纤维膜形貌的影响,分析了纤维膜的耐光降解性能,结果表明:MAA含量25%的DHFMA-co-MAA以DMF作为纺丝溶剂,MAA含量10%的DHFMA-co-MAA以丁酮+DMF(质量比为2∶8)作为纺丝溶剂,均可以制备出表面平滑、纤维直径较小、形态均一的纤维膜;MAA含量10%的DHFMA-co-MAA纤维膜的光稳定性能更好,更适合用作光催化剂载体.
参考文献
[1] | Moghaddam AB;Ganjali MR;Dinarvand R;Mohammadi A;Norouzi P .Electrochemical and scanning electron microscopic studies of the influence of anatase TiO2 nanoparticles on the electropolymerization of aniline[J].Mendeleev Communications,2008(2):90-91. |
[2] | Fu, HK;Kuo, SW;Huang, CF;Chang, FC;Lin, HC .Preparation of the stimuli-responsive ZnS/PNIPAM hollow spheres[J].Polymer,2009(5):1246-1250. |
[3] | Ji, LW;Medford, AJ;Zhang, XW .Electrospun polyacrylonitrile/zinc chloride composite nanofibers and their response to hydrogen sulfide[J].Polymer,2009(2):605-612. |
[4] | Miaomiao He;Wenjuan Fan;Haihong Ma.Preparation of ZnS-AgIn5S8/fluoropolymer fiber composites and its photocatalytic H2 evolution from splitting of water under similar sunlight irradiation[J].Catalysis Communications,2012:89-93. |
[5] | 左丹英,徐又一,曾秋霞,龚玉洁.浸没沉淀相转化法制备结晶性聚合物微孔膜的研究进展[J].化学通报(印刷版),2008(05):336-342. |
[6] | FAN W J;ZHOU Z F;XU W B et al.Preparation of ZnIn2S4/Fluoropolymer Fiber Composites and Its Photocatalytic H2 Evolution from Splitting of Water under Xe Lamp Irradiation[J].International Journal of Hydrogen Energy,2010,35:6525-6530. |
[7] | Zhengfa Zhou;Dian He;Weibing Xu .Preparing ZnS nanoparticles on the surface of carboxylic poly(vinyl alcohol) nanofibers[J].Materials Letters,2007(23/24):4500-4503. |
[8] | 刘瑞刚 .纤维素/NMMO/H2O溶液的制备、溶液性能的研究和loycell纤维的试制[D].上海:中国纺织大学,1998. |
[9] | MCKEE M G;WILKES G L;COLBY R H et al.Correlations Solution Rheology with Electrospun Fiber Formation of Linear and Branched Polyesters[J].MACROMOLECULES,2004,37(05):1760-1767. |
[10] | COLBY R H;FETTERS L J;FUNK W G .Effects of Concentration and Thermodynamic Interaction on the Viscoelastic Properties of Polymer Solutions[J].MACROMOLECULES,1999,24(13):3872-3883. |
[11] | KRAUSE W E;BELLOMO E G;COLBY R H .Rheology of Sodium Hyaluronate under Physiological Conditions[J].Biomacromolecules,2001,2(01):65-69. |
[12] | 李珍,王军.静电纺丝可纺性影响因素的研究成果[J].合成纤维,2008(09):6-11. |
[13] | 石巍,张军.聚氯乙烯紫外光稳定性研究进展[J].塑料科技,2007(02):88-95. |
[14] | 罗海.木塑复合材料的光降解与光稳定[J].中国塑料,2011(05):24-29. |
[15] | 吴茂英.塑料降解与稳定化(Ⅳ):光降解与光稳定(上)[J].塑料助剂,2010(06):51-55. |
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