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According to the experimental data of phase transition taken from DTA, metallography, SEM and microzone composition, two vertical sections of the ternary phase diagram (B=5.88 at.-%, Nd≤45.41 at.-% andNd_2Fe_(14)BNd_(1.1)Fe_4B_4 , B≤44.56 at.-%) have been drawn in detail. It is verified that the crystallization of both Nd_2Fe_(14)B and Nd_(1.1)Fe_4B_4 phase, during cooling from melt, would take peritectic reaction instead of solid-liquid congruent precipita- tion.

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