吸放氢热/动力学差及可逆条件苛刻是限制硼氢化物MBH<,4>(M=Li,Na)储氢材料广泛应用的最大"瓶颈".从价键特征以及吸放氢后相变化两个本质原因出发,分析总结了近年来硼氢化物储能材料的研究进展,重点阐述了反应物失稳法及纳米结构调制对其吸放氢性能的改善,并根据目前面临的主要问题提出了可能的发展趋势.
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