The geochemical characteristics of rare earth elements (REEs) in intertidal sediments in Tianjin coastal zone were systematically studied. The environmental behaviors of REEs in polluted river were also examined. The source of REEs in intertidal sediments was discussed on the basis of distribution pattern of REEs. The results can be summed up in the following aspects: (1) The average content of total REEs in the intertidal sediments is 164.5 mg*kg-1, and different in different sections of the coast. (2) Residual REEs in the coastal zone decrease from north to south, and Fe-Mn oxides and organic matter-bound REEs increase. Compared with those in Changjiang River, ratio between residual and carbonate REEs is obviously low. (3) Distribution patterns of REEs show that light REEs is relatively high and Eu-anomaly is slightly negative. They are similar to the patterns in coastal and inland rivers and different from those in continental shelf.
参考文献
[1] | Wang L J;Zhang S;Zhang C S et al.Aquatic environmental geochemistry characteristics of rare earth elements in the middle-lower reaches of Changjiang (Yangtzi) river[J].Acta Scientiae Circumatantiae(in Chinese),1995,15(01):57. |
[2] | Zhu W.;Deleer EWB.;Zhou H.;Alaerts GJFR.;Kennedy M. .DISTRIBUTION AND MODELLING OF RARE EARTH ELEMENTS IN CHINESE RIVER SEDIMENTS[J].Science of the Total Environment,1997(3):233-243. |
[3] | HOLYE J;ElderfieldH;Greaves M .The behavior of the rare earth elements during mixing of river and seawater[J].Geochemica et Cocmochemica Acta,1995,Acta 48:143. |
[4] | GOUVEIA M A;Araujo M F D;Dias J M A .Rare earth elements distribution on sediments from the Minho river and estuary (Portugal)-a preliminary study[J].Chemical Geology,1993(107):379. |
[5] | 王立军,张朝生,章申.珠江广州江段水体中稀土元素的地球化学特征[J].地理学报,1998(05):453. |
[6] | Sholkovitz E R .The aquatic chemistry of rare earth elements in rivers and estuaries[J].Aquatic Geochemistry,1995,1:64. |
[7] | TESSIER A;Campbell P G C;Bisson M .Sequential extraction procedure for the speciation of particulate trace metals[J].Analytical Chemistry,1979,51(07):844. |
[8] | WANG Y Q;Sun J X .Contents and distribution of rare earth elements in soil[J].Environmental Science,1991,12(05):51. |
[9] | Wang Z G;Yu X Y;ZHAO Z H.Geochemistry of rare earth elements[M].北京:科学出版社,1989:5-19,90. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%