应用溶胶-凝胶法制备了SiO2/SnO2复合凝胶,测定了红外光谱,采用静态吸附法测定了不同组成的SiO2/SnO2复合凝胶对丙酮气体和氨气的吸附动力学曲线.结果表明,SiO2与SnO2凝胶的复合有利于气体的吸附,在凝胶中含有一定的羟基是吸附性强的根源.数据拟合得到的吸附动力学方程分别为x=c1(1-exp(-c2t)和x=c′1t/(1+c2t)的形式,说明SiO2/SnO2复合凝胶对丙酮气体和氨气的吸附机理分别具有单活性位和双活性位吸附特征.
参考文献
[1] | Chaudhary V A;Mulla I S;Vijayamohanan K .Selective hydrogen sensing properties of surface functionalized Tin oxide[J].Sensors and Actuators B-Chemical,1999,55(2-3):154. |
[2] | 沈钟;王果庭.胶体与表面化学[M].北京:化学工业出版社,1997:170. |
[3] | Pan V H;Tao T;Zhou J W et al.Hydrogen bonding between acetone and silica gelas studied by NMR[J].Journal of Physical Chemistry B,1999(103):6930. |
[4] | Yichu Wu;Yufang Zheng;Deming Lin .Interfacial structure of nanocrystalline SnO_2 and SiO_2-doped SnO_2[J].Journal of Materials Science & Technology,1999(4):388-0. |
[5] | Wada K;Egashira M .Improvement of gas-sensing properties of a Pd/SnO2 sensor by SiO2 coating films fomed by dipping method[J].Journal of the Ceramic Society of Japan,1998,106(01):84. |
[6] | CARTURAN G;Ceccato R;Campostrini R et al.SnO2/SiO2and Sn/Sb-oxide/SiO2 gel-derived composites. 1. Struc tural evolution from a mossbauer study[J].Journal of Sol-Gel Science and Technology,1995,5(01):49. |
[7] | 蒲敏 .硅钛系氧化物气凝胶的纳米结构与量子尺寸效应研究[D].西安交通大学,1999. |
[8] | 朱步瑶;赵振国.界面化学基础[M].北京:化学工业出版社,1996:367. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%