偕胺肟螯合树脂对重金属离子有高的选择性和较大的吸附量,可用于污水处理和回收利用废矿、废液中的重金属离子.本文介绍了偕胺肟螯合树脂的合成方法,阐述了偕胺肟基螯合树脂的物理化学性质及其表征手段,对偕胺肟螯合树脂作为吸附分离材料的研究现状进行了评述,展望了偕胺肟螯合树脂的应用前景.
参考文献
[1] | Fetscher C A .Extraction of heavy metals from solutions with polyamidoximes[P].US 3088798,1963-05-07. |
[2] | EI Aamrani F Z;Duro L;De Pablo J et al.Experimental study and modeling of the sorption of uranium (Ⅵ) onto olivine-rock[J].Geochemistry,2002,17(04):399-408. |
[3] | Xianghua Song;Poernomo Gunawan;Rongrong Jiang;Susanna Sujan Leong;Kean Wang, Rong Xu.Surface activated carbon nanospheres for fast adsorption of silver ions from aqueous solutions[J].Journal of hazardous materials,2011:162-168. |
[4] | MATTHEW J.ECKELMANl;T.E.GRAEDEL .Silver Emissions and their Environmental Impacts:A Multilevel Assessment[J].Environmental Science & Technology: ES&T,2007(17):6283-6289. |
[5] | Hosoba M;Oshita K;Katarina R K et al.Synthesis of novel chitosan resin possessing histamine moiety and its application to the determination of trace silver by ICP-AES coupled with triplet automated pretreatment system[J].Analytica Chimica Acta,2009,639:51-56. |
[6] | Nuri Uenlue;Mustafa Ersoz .Adsorption characteristics of heavy metal ions onto a low cost biopolymeric sorbent from aqueous solutions[J].Journal of hazardous materials,2006(2):272-280. |
[7] | Coruh S;Senel G;Ergun O N .A comparison of the properties of natural clinoptilolites and their ion-exchange capacities for silver removal[J].Journal of Hazardous Materials,2010,180(01):486-492. |
[8] | Kartik R. Desai;Z.V.P. Murthy.Removal of silver from aqueous solutions by complexation-ultrafiltration using anionic polyacrylamide[J].Chemical engineering journal,2012:187-192. |
[9] | Abd E1-Ghaffar M A;Mohamed M H;Elwakeel K Z .Adsorption of silver (Ⅰ) on synthetic chelating polymer derived from 3-amino-1,2,4-triazole-5-thiol and glutaraldehyde[J].CHEMICAL ENGINEERING,2009,151(01):30-38. |
[10] | Lu QF;Huang MR;Li XG .Synthesis and heavy-metal-ion sorption of pure sulfophenylenediamine copolymer nanoparticles with intrinsic conductivity and stability[J].Chemistry: A European journal,2007(21):6009-6018. |
[11] | Lu X;Yin Q;Xin Z et al.Powerful adsorption of silver (Ⅰ) onto thiol-functionalized polysilsesquioxane microspheres[J].Chemical engineering science,2010,65(24):6471-6477. |
[12] | 熊洁,许云书,黄玮.偕胺肟基螯合吸附分离材料研究进展[J].材料导报,2006(07):102-104,108. |
[13] | Rivas BL.;Villegas S.;Maturana HA. .Adsorption behavior of metal ions by amidoxime chelating resin[J].Journal of Applied Polymer Science,2000(9):1994-1999. |
[14] | 王瑞芳,史作清,施荣富,张静泽,欧来良.胺基化超高交联吸附树脂对苯酚和苯胺吸附行为的研究[J].高分子学报,2005(03):339-344. |
[15] | 刘志国,蒋玉仁.苯乙偕胺肟的合成[J].益阳师专学报,1995(06):65-68. |
[16] | 蒋玉仁;薛玉兰 .一种偕胺肟合成方法[P].CN 00102094.3,2001-19. |
[17] | 周宜遂;苏新海 .含腈基化合物肟化反应的新方法[P].CN 02158739.6,2004-07-07. |
[18] | 赵莹,叶翠层,李姣娟,杨志.无水AlCl3催化氯苯胺与丙烯腈的加成反应[J].化学通报(印刷版),2006(06):438-441. |
[19] | Colleen M L;Delp S A;Blue E D et al.Addition of N-H and O-H bonds of amines and alcohols to electron-deficient olefins catalyzed by monomeric coppe (Ⅰ) systems:reaction scope,mechanistic details,and comparison of catalyst efficiency[J].ORGANOMETALLICS,2007,26:1483-1493. |
[20] | Ramesh Alleti;Woon Su Oh;Meher Perambuduru .Imidazolium-based polymer supported gadolinium triflate as a heterogeneous recyclable Lewis acid catalyst for Michael additions[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,2008(21):3466-3470. |
[21] | Lowe H;Hessel V;Lob P;Hubbard S .Addition of secondary amines to alpha,beta-unsaturated carbonyl compounds and nitriles by using microstructured reactors[J].Organic process research & development,2006(6):1144-1152. |
[22] | Khan AT;Ghosh S;Choudhury LH .Perchloric acid impregnated on silica gel (HClO4/SiO2): A versatile catalyst for Michael addition of thiols to the electron-deficient alkenes[J].European journal of organic chemistry,2006(9):2226-2231. |
[23] | Yi CS.;Yun SY.;He ZJ. .Conjugate addition of alcohols to acrylic compounds catalyzed by a bifunctional ruthenium-acetamido complex[J].Organometallics,2003(15):3031-3033. |
[24] | 夏友谊.聚丙烯腈基螯合纤维的研究进展[J].高科技纤维与应用,2006(04):34-38,44. |
[25] | 吴江华 .采用偕胺肟聚丙烯腈树脂从银钯硝酸盐混合溶液中吸附分离钯[D].中南大学,2012. |
[26] | Nilchi A;Maragheh M G;Khanchi A et al.Synthesis and ion-exchange properties of crystalline titanium and zirconium phosphates[J].Journal of Radioanalytical and Nuclear Chemistry,2004,261(02):393-400. |
[27] | Saeed K;Haider S;Oh T J et al.Preparation of amidoxime-modified polyacrylonitrile (PAN-oxime) nanofibers and their applications to metal ions adsorption[J].Journal of Membrane Science,2008,322(02):400-405. |
[28] | Synthesis of porous acrylonitrile/methyl acrylate copolymer beads by suspended emulsion polymerization and their adsorption properties after amidoximation[J].Journal of hazardous materials,2010(1/3):1014. |
[29] | 高学超,高保娇,赵婧.螯合吸附材料PAO/SiO2对重金属离子的螯合吸附行为[J].化学研究与应用,2010(06):690-694. |
[30] | 辛浩;波吴航;杨金凤 .偕胺肟基功能高分子膜对铀的吸附过程研究[J].离子交换与吸附,2009,25(03):259-264. |
[31] | 董永春,武金娜,孙苏婷,郑戌,韩振邦,刘春燕.偕胺肟改性聚丙烯腈纤维与不同金属离子之间的配位反应性能[J].四川大学学报(工程科学版),2011(01):173-178. |
[32] | 苏玉芹,刘晓玲,张佐光.大孔偕胺肟树脂的合成及其对镓的吸附性能[J].过程工程学报,2010(05):893-898. |
[33] | 李尧 .极性单体改性St-DVB吸附树脂的孔结构与吸附性能研究[D].西安建筑科技大学,2008. |
[34] | 董怀昕 .氨基螯合树脂的制备及其性能研究[D].化学与化工学院,2011. |
[35] | 黄文强.吸附分离材料[M].北京:化学工业出版社,2005 |
[36] | 曾理,肖连生,李青刚,向小艳.离子交换法从钼酸铵溶液中分离钼钒的研究[J].稀有金属与硬质合金,2006(02):1-4,20. |
[37] | Oriol Font;Xavier Querol;Roberto Juan;Raquel Casado;Carmen R. Ruiz;Angel Lopez-Soler;Pilar Coca;Francisco Garcia Pena .Recovery of gallium and vanadium from gasification fly ash[J].Journal of hazardous materials,2007(3):413-423. |
[38] | 王永江.高分子螯合树脂及其应用研究[J].丽水师范专科学校学报,2001(05):27-29. |
[39] | Baojiao Gao;Yuechao Gao;Yanbin Li .Preparation and chelation adsorption property of composite chelating material poly(amidoxime)/SiO2 towards heavy metal ions[J].Chemical engineering journal,2010(3):542-549. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%