用溶液法在铜片表面制备Cu2O膜,再用十二硫醇对表面进行修饰,制备出接触角达157.7°、滚动角小于2°的超疏水Cu2O表面.用场发射扫描电镜(FESEM)、X射线衍射仪(XRD)、光学视频接触角仪以及电化学工作站表征和分析了试样的表面.结果表明,制备的超疏水Cu2O表面具有优异的不粘附性和耐腐蚀性能.具有超疏水特性的铜片表面与液体接触时,形成的“气垫”阻碍了水和腐蚀性溶液(如CI-)对铜片的接触;铜片表面修饰的十二硫醇能延缓腐蚀性溶液对铜片表面的渗透,使表面具有超疏水性.
参考文献
[1] | T.Peter,A.Gilbert,Review of recent work on corrosion behavior of copper alloys in sea water,Materials Performance,21(2),47(1982) |
[2] | J.M.Galbraith,K.L.Lofgren,Update on monitoring microbial corrosion in Prudhce Bay' s produced water and sea water floods,Materials Performance,26(9),47(1987) |
[3] | Y.M.Zheng,X.F.Gao,L.Jiang,Directional adhesion of superhydrophobic butterfly wings,Soft Matter,3,178(2007) |
[4] | G.S Watson,J.A.Watson,Natural nano-structures on insects--possible functions of ordered arrays characterized by atomic force microscopy,Applied Surface Science,235(1),139(2004) |
[5] | X.J.Feng,L.Jiang,Design and creation of superwetting/antiwetting surfaces,Advanced Materials,18(23),3063(2006) |
[6] | T.Sun,L.Feng,X.Gao,L.Jiang,Bioinspired surfaces with special wettability,Accounts of Chemical Research,38(8),644(2005) |
[7] | X.Yao,Y.Song,L.Jiang,Applications ofbio-inspired special wettable surfaces,Advanced Materials,23(6),719(2011) |
[8] | X.Zhu,Z.Zhang,X.Men,J.Yang,X.Zhou,Q.Xue,Rapid control of switchable oil wettability and adhesion on the copper substrate,Langmuir,27(23),14508(2011) |
[9] | X.Chen,L.Kong,D.Dong,G.Yang,L.Yu,J.Chen,Synthesis and characterization of superhydrophobic functionalized Cu(OH)2 nanotube arrays on copper foil,Applied Surface Science,255,4015(2009) |
[10] | E.D.Mishina,K.Nagai,S.Nakabayashi,Self-assembled Cu/Cu2Omultilayers:deposition,structure and optical properties,Nano Letters,1(8),401(2001) |
[11] | L.Gou,C.J.Murphy,Solution-phase synthesis of Cu2O nanocubes,Nano Letters,3(2),231(2003) |
[12] | C.A.N.Femando,P.H.C.De Silva,S.K Wethasinha,Investigation of n-type Cu2O layers prepared by a low cost chemical method for use in photo-voltaic thin film solar cells,Renewable Energy,26(4),521 (2002) |
[13] | C.A.N.Femando,S.K.Wetthasinghe,Investigation ofphotoelectrochemical characteristics of n-type Cu2O films,Solar Energy Materials and Solar Cells,63(3),299(2000) |
[14] | V.S.Dilimon,J.Denayer,J.Delhalle,Z.Mekhalif,Electrochemical and spectroscopic study of the self-assembling mechanism of normal and chelating alkanethiols on copper,Langmuir,28(17),6857(2012) |
[15] | P.Chinwangso,A.C.Jamison,Multidentate adsorbates for self-assembled monolayer films,Accounts of Chemical Research,44(7),511(2011)9 |
[16] | P.E.Laibinis,G.M.Whitesides,Self-assembled monolayers of nalkanethiolates on copper are barrier films that protect the metal against oxidation by air,Journal of the American Chemical Society,114(23),9022(1992) |
[17] | A.B.D.Cassie,Contact angles,Discussions of the Faraday Society,3,11(1948) |
[18] | L.Gao,T.J.McCarthy,Teflon is hydrophilic.Comments on definitions of hydrophobic,shear versus tensile hydrophobicity,and wettability characterization,Langrnuir,24(17),9183 (2008) |
[19] | A.Shaban,E.Kalman,J.Telegdi,An investigation of copper corrosion inhibition in chloride solutions by benzo-hydroxamic acids,Electrochimica Acta,43(1),159(1998) |
[20] | G.H(a)hner,R.Hofer,I.Klingenfuss,Order and orientation in selfassembled long chain alkanephosphate monolayers adsorbed on metal oxide surfaces,Langmuir,17(22),7047(2001) |
[21] | H.Fan,S.Li,Z.Zhao,H.Wang,Z.Shi,L.Zhang,Inhibition of brass corrosion in sodium chloride solutions by self-assembled silane films,Corrosion Science,63(12),4273(2011) |
[22] | R.N.Wenzel,Resistance of solid surfaces to wetting by water,Industrial and Engineering Chemistry,28(8),988(1936) |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%