锂离子电池负极用硅／碳纳米复合材料制备方法和性能的研究进展

机械工程材料, 2012, 36(9): 1-7.

锂离子电池负极用硅／碳纳米复合材料制备方法和性能的研究进展

赵智泉 ^1, , 刘庆雷 ^2, , 黄大成 ^3, , 周凤羽 ^4, , 刘元超 ^5, , 张荻 ^6,

1.上海交通大学金属基复合材料国家重点实验室,上海200240

2.上海交通大学金属基复合材料国家重点实验室,上海200240

3.上海交通大学金属基复合材料国家重点实验室,上海200240

4.上海交通大学金属基复合材料国家重点实验室,上海200240

5.上海交通大学金属基复合材料国家重点实验室,上海200240

6.上海交通大学金属基复合材料国家重点实验室,上海200240

基金项目: 国家自然科学基金资助项目(51001070)

关键词：锂离子电池 , 硅/碳复合材料 , 负极 , 可逆比容量

Research Development of Preparation Methods and Properties of Si/C Nanocomposites Used for Cathode of Lithium-Ion Battery

Keywords： lithium ion battery , Si/C nanocomposite , cathode , reversible specific capacity

介绍了近十年来锂离子电池负极用硅／碳纳米复合材料的主要制备方法，包括热解法、化学气相沉积法、球磨法、水热法以及溶胶凝胶法等，以及硅／碳复合材料的微结构特征及其对复合材料比容量和循环性能的影响。最后，对硅／碳纳米复合材料的研究方向进行了展望。

The main preparation methods for Si/C nanocomposites used for cathode of lithium-ion battery in the last decade were introduced, including pyrolysis, chemical vapor deposition, milling, hydrothermal, gel method and so on. The microstructure characteristics of Si/C composite and their effects on specific capacity and cycling performance of composite were introduced, too. At last, the prospects of study direction of Si/C nanocomposites were showed.

参考文献

[1]	Teki, R;Datta, MK;Krishnan, R;Parker, TC;Lu, TM;Kumta, PN;Koratkar, N .Nanostructured Silicon Anodes for Lithium Ion Rechargeable Batteries[J].Small,2009(20):2236-2242.
[2]	Kang YM;Lee SM;Kim SJ;Jeong GJ;Sung MS;Choi WU;Kim SS .Phase transitions explanatory of the electrochemical degradation mechanism of Si based materials[J].Electrochemistry communications,2007(5):959-964.
[3]	Morita T;Takami N .Nano Si cluster-SiOx-C composite material as high-capacity anode material for rechargeable lithium batteries[J].Journal of the Electrochemical Society,2006(2):A425-A430.
[4]	Ding, N;Xu, J;Yao, YX;Wegner, G;Fang, X;Chen, CH;Lieberwirth, I .Determination of the diffusion coefficient of lithium ions in nano-Si[J].Solid state ionics,2009(2/3):222-225.
[5]	Liu Y;Hanai K;Yang J;Imanishi N;Hirano A;Takeda Y .Morphology-stable silicon-based composite for Li-intercalation[J].Solid state ionics,2004(1/2):61-68.
[6]	Wang K;He XM;Wang L;Ren JG;Jiang CY;Wan CR .Si, Si/Cu core in carbon shell composite as anode material in lithium-ion batteries[J].Solid state ionics,2007(1/2):115-118.
[7]	Cui LF;Ruffo R;Chan CK;Peng HL;Cui Y .Crystalline-Amorphous Core-Shell Silicon Nanowires for High Capacity and High Current Battery Electrodes[J].Nano letters,2009(1):491-495.
[8]	Uday Kasavajjula;Chunsheng Wang;A. John Appleby .Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells[J].Journal of Power Sources,2007(2):1003-1039.
[9]	Larcher D.;George A.E.;Porter V.;Gharghouri M.;Dahn J.R.;Mudalige C. .Si-containing disordered carbons prepared by pyrolysis of pitch/polysilane blends: effect of oxygen and sulfur[J].Solid state ionics,1999(1/4):71-83.
[10]	Z. S. Wen;J. Yang;B. F. Wang;K. Wang;Y. Liu .High capacity silicon/carbon composite anode materials for lithium ion batteries[J].Electrochemistry communications,2003(2):165-168.
[11]	Michael Holzapfel;Hilmi Buqa;Werner Scheifele;Petr Novak;Frank-Martin Petrat .A new type of nano-sized silicon/carbon composite electrode for reversible lithium insertion[J].Chemical communications,2005(12):1566-1568.
[12]	Zhaojun Luo;Dongdong Fan;Xianlong Liu;Huanyu Mao;Caifang Yao;Zhongyi Deng .High performance silicon carbon composite anode materials for lithium ion batteries[J].Journal of Power Sources,2009(1):16-21.
[13]	Y. Zhang;X. G. Zhang;H. L. Zhang;Z. G. Zhao;F. Li;C. Liu;H. M. Cheng .Composite anode material of silicon/graphite/carbon nanotubes for Li-ion batteries[J].Electrochimica Acta,2006(23):4994-5000.
[14]	Heon-Young Lee;Sung-Man Lee .Carbon-coated nano-Si dispersed oxides/graphite composites as anode material for lithium ion batteries[J].Electrochemistry communications,2004(5):465-469.
[15]	Wei Wang;Prashant N. Kumta .Reversible high capacity nanocomposite anodes of Si/C/SWNTs for rechargeable Li-ion batteries[J].Journal of Power Sources,2007(2):650-658.
[16]	Yong-Sheng Hu;Rezan Demir-Cakan;Maria-Magdalena Titirici .Superior Storage Performance of a Si@SiO_x/C Nanocomposite as Anode Material for Lithium-Ion Batteries[J].Angewandte Chemie,2008(9):1645-1649.
[17]	Wang GX;Ahn JH;Yao J;Bewlay S;Liu HK .Nanostructured Si-C composite anodes for lithium-ion batteries[J].Electrochemistry communications,2004(7):689-692.
[18]	Yoon Seok Jung;Kyu T. Lee;Seung M. Oh .Si-carbon core-shell composite anode in lithium secondary batteries[J].Electrochimica Acta,2007(24):7061-7067.
[19]	Peter G. Bruce;Bruno Scrosati;Jean-Marie Tarascon .Nanomaterials for Rechargeable Lithium Batteries[J].Angewandte Chemie,2008(16):2930-2946.
[20]	Kim H;Cho J .Superior Lithium Electroactive Mesoporous Si@Carbon Core-Shell Nanowires for Lithium Battery Anode Material[J].Nano letters,2008(11):3688-3691.
[21]	Cui, LF;Yang, Y;Hsu, CM;Cui, Y .Carbon-Silicon Core-Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries[J].Nano letters,2009(9):3370-3374.
[22]	Liwen Ji;Xiangwu Zhang .Fabrication of porous carbon/Si composite nanofibers as high-capacity battery electrodes[J].Electrochemistry communications,2009(6):1146-1149.
[23]	Wang, W.;Kumta, P.N. .Nanostructured hybrid silicon/carbon nanotube heterostructures: Reversible high-capacity lithium-ion anodes[J].ACS nano,2010(4):2233-2241.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网