文章根据双膜理论,分析了气液反应的吸收机理,用图像边界识别法测量亚硫酸盐强制氧化气液反应速率.在测量氧化速率时,让单个氧气泡在亚硫酸钠溶液中反应,用数码相机拍下氧气泡由于反应而不断缩小的照片,用图像处理程序进行分析、识别,最后计算得出氧化速率.实验结果与理论分析结果相同,证明了该方法的正确性及其可以作为气液传质理论研究的测量方法.
参考文献
[1] | Whitman W G .The Two-Film Theory of Gas Absorption[J].Chemical and Metallurgical Engineering,1923,29(04):147-150. |
[2] | Higbie R .Penetrate Theory of Gas Absorption TransAm[J].Institute of Chemical Engineers,1935,31(04):365-370. |
[3] | Danckwerts P V .Significance of Liquid-Film Coefficients in Gas Absorption[J].Industrial and Engineering Chemistry Research,1951,43(06):1460-1465. |
[4] | TOOR H L;Marchello J M .Film-Penetration Model for Mass and Heat Transfer[J].AICHE Journal,1958,4(01):97-104. |
[5] | 杜谦,吴少华,朱群益,秦裕琨.湿法烟气脱硫环境下亚硫酸钙的非催化氧化[J].化工学报,2003(10):1490-1493. |
[6] | Linek V;Vacek Ⅴ .Chemical Engineering Use of Catalyzed Sulfite Oxidation Kinetics for the Determination of Mass Transfer Characteristics of Gas-Liquid Contactors[J].Chemical engineering science,1981,36:1747-1768. |
[7] | 项斯芬;严宣申;曹庭礼.无机化学丛书[M].北京:科学出版社,1998 |
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