介绍了1种新型的锂离子电池正极活性材料LiFePO4并解释了材料的结构特征和电化学过程.LiFePO4具有较高的比容量和良好的循环稳定性等优良的电化学性能,但是目前还存在着制约容量释放的锂离子扩散系数小以及材料导电性能不太好等问题.在回顾该材料研究状态的基础上,说明了只要通过选取适当的制备工艺和进行合适的表面改性可以制备出具有优良电化学性能的LiFePO4粉体.这种粉体具有环境相容性、便宜以及资源丰富等诸多优点,是1种颇具潜力的锂离子电池正极替代材料.
参考文献
| [1] | Colin .[J].Solid State Ionics,2000,134:159-167. |
| [2] | Dong;Rolison W .[J].Electrochemical and Solid-State Letters,2000,3:457-459. |
| [3] | 张丽娟,赵新兵,蒋小兵,吕春萍.金属间化合物CoSb3的电化学嵌锂特性研究[J].稀有金属材料与工程,2001(04):268-272. |
| [4] | Tarascon;Armand M .[J].Nature,2001,1414:359-367. |
| [5] | Megahed .[J].Journal of Power Sources,1994,51:79-104. |
| [6] | Anna S;Andersson;Beata Kalska et al.[J].Solid State Ionics,2000,130:41-52. |
| [7] | Nishijima M;Takeda Y;Imanishi N et al.[J].Journal of Solid State Chemistry,1994,113:205. |
| [8] | Sakurai Y Arai H;Yamaki J .[J].Solid State Ionics,1998,113:29-34. |
| [9] | Takahashi M et al.[J].Journal of Power Sources,2001,1998(08):508-511. |
| [10] | Yang S F .[J].Electrochemistry Communications,2001,3(09):505-508. |
| [11] | Andersson AS.;Haggstrom L.;Thomas JO.;Kalska B. .Lithium extraction/insertion in LiFePO4: an X-ray diffraction and Mossbauer spectroscopy study[J].Solid state ionics,2000(1/2):41-52. |
| [12] | Padhi .[J].Journal of the Electrochemical Society,1997,144(05):1609-1613. |
| [13] | Padhi .[J].Journal of the Electrochemical Society,1997,144(04):1188-1194. |
| [14] | Andersson A S;Thomas J O .[J].Journal of the Electrochemical Society,2001,148(03):97-98,498-502. |
| [15] | Prosini P P et al.[J].Journal of the Electrochemical Society,2002,149(07):A886-A890. |
| [16] | Yamada A;Chung S C .[J].Journal of the Electrochemical Society,2001,148(03):A224-A172. |
| [17] | Huang .[J].Electrochemical and Solid-State Letters,2001,4(10):A170-A172. |
| [18] | Chen Z H;Dahn J R .[J].Journal of the Electrochemical Society,2002,149(09):Al184-A1189. |
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