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在双酚A环氧树脂(DGEBA)-改性二乙烯三胺(DETA)体系中加入环氧大豆油(ESO),制得了不同ESO含量(0~15.15%)改性的环氧树脂涂层;用三点弯曲试验测试了改性涂层的临界断裂强度因子(KIC),用静态浸泡试验得到了涂层的质量增加率-时间曲线,测试了玻璃转化温度Tg,并计算出了水分子在改性涂层中的扩散系数D.结果表明:随着ESO含量的增加,涂层的KIC先增加后降低,而Tg和质量增加率则降低,D则先降后升;当ESO质量分数为7.35%时,改性涂层的耐水分子扩散性能最优.

参考文献

[1] Zhang JT;Hu JM;Zhang JQ;Cao CN .Studies of water transport behavior and impedance models of epoxy-coated metals in NaCl solution by EIS[J].Progress in Organic Coatings: An International Review Journal,2004(2):145-151.
[2] MinYoung Shon;HyukSang Kwon .Effects of surface modification with amino branched polydimethylsiloxane (ABP) on the corrosion protection of epoxy coating[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2007(11):4259-4275.
[3] 徐丽,司徒粤,胡剑峰,陈焕钦,曾汉维.双重改性酚醛树脂的合成及性能研究[J].粘接,2008(10):5-8.
[4] Iain McEwan;Richard A. Pethrick;Stephen J. Shaw .Water absorption in a rubber-modified epoxy resin; carboxy terminated butadiene acrylonitrile-amine cured epoxy resin system[J].Polymer: The International Journal for the Science and Technology of Polymers,1999(15):4213-4222.
[5] Grave C.;Pethrick RA.;McEwan I. .Influence of stoichiometric ratio on water absorption in epoxy resins[J].Journal of Applied Polymer Science,1998(12):2369-2376.
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