利用JSM-5610LV扫描电镜(SEM)及能谱分析(EDS)等测量方法,研究了微量RE对Sn-2.5Ag-0.7Cu无铅钎料的显微组织、润湿特性、拉伸强度及焊点剪切强度和蠕变断裂寿命的影响。结果表明,向Sn-2.5Ag-0.7Cu中添加0.1%RE可明显细化钎料合金的显微组织,改善钎料合金的润湿特性,提高钎料合金的抗拉强度、伸长率及焊点剪切强度,增加焊点的蠕变断裂寿命。当RE添加量为0.5%时,由于形成了RE化合物而明显恶化钎料合金的性能。
Effect of RE on microstructure,wetting property,tensile strength of Sn2.5Ag0.7Cu solder alloy and shear strength,creep rupture life of its solder joints were investigated by means of scanning electronic microscopy(SEM) and energy dispersive spectrum analysis.The results show that adding 0.1% RE in Sn2.5Ag0.7Cu solder alloy can apparently refine the microstructure,greatly improve its wetting properties,tensile strength and elongation of the solder alloy.Meanwhile,shear strength and creep rupture life of the solder joints significantly increase.However,the addition of an excessive amount of RE deteriorates the properties of SnAgCu alloy because of the formation of RE compound.
参考文献
[1] | 田艳红,杨世华,王春青,王学林,林鹏荣.Sn3.0Ag0.5Cu/Cu无铅焊点剪切断裂行为的体积效应[J].金属学报,2010(03):366-371. |
[2] | ZHANG Liang,XUE Song-bai,GAO Li-li,ZENG Guang,CHEN Yan,YU Sheng-lin,SHENG Zhong.Creep behavior of SnAgCu solders with rare earth Ce doping[J].中国有色金属学报(英文版),2010(03):412-417. |
[3] | 许天旱,王党会.导液管突出高度对Sn-Ag-Cu无铅焊锡粉末特性的影响[J].材料热处理学报,2010(02):21-25. |
[4] | Li G Y;Shi X Q .Effects of bismuth on growth of intermetallic compounds in SnAgCu Pb-free solder joints[J].Transactions of Nonferrous Metals Society of China,2006,16(z2):739-746. |
[5] | Wu B Y;Chan Y C;Alam M O .Electrochemical corrosion study of Pb-free solders[J].Journal of Materials Research,2006,21(01):62-66. |
[6] | Gao F;Takemoto T;Nishikawa H .Effects of Co and Ni addition on reactive diffusion between Sn3.5Ag solder and Cu during soldering and annealing[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,2006,40(1-2):39-43. |
[7] | MOON GI CHO;SUNG K.RANG;DA-YUAN SHIH .Effects of Minor Additions of Zn on Interfacial Reactions of Sn-Ag-Cu and Sn-Cu Solders with Various Cu Substrates during Thermal Aging[J].Journal of Electronic Materials,2007(11):1501-1509. |
[8] | 张柯柯,王双其,余阳春,王要利,樊艳丽,程光辉,韩丽娟.SnAgCuRE系无铅钎料与表面贴装元器件的润湿适配性[J].中国有色金属学报,2006(11):1908-1912. |
[9] | 王丽凤,孙凤莲,吕烨,申旭伟.Sn-3.0Ag-0.5Cu-xNi无铅焊料及焊点的性能[J].焊接学报,2009(01):9-12. |
[10] | Gong Jicheng;Liu Changqing;Paul P et al.Silberschmidt.Initial formation of CuSn intermetallic compounds betweenmohen SnAgCu solder and Cu substrate[J].Scripta Materialia,2009,60:333-335. |
[11] | 韩运侠,张柯柯.表面组装焊点形态模型的建立及求解[J].数学的实践与认识,2009(11):57-61. |
[12] | 杨洁,张柯柯,程光辉,余阳春,周旭东.片式元件与基板间隙对无铅焊点可靠性的影响[J].电子元件与材料,2006(02):58-61. |
[13] | 王要利,张柯柯,韩丽娟,温洪洪.Sn-2.5Ag-0.7Cu(0.1RE)/Cu焊点界面区微观组织与Cu6Sn5的生长动力学[J].中国有色金属学报,2009(04):708-713. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%