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The martensitic transformation in Fe-Cr-W-V-C alloy has been investigated by TEM.The habit plane of martensite is near (252)_f, the austenite/martensite orientation relationship is Kurdjumov-Sachs'.In the martensite plates there are twins on (112)[ 1]_b,dislocation tangles and the lattice defects on (011)_b plane.In the austenite near the growing martensite plates,the dislocations with high density and stacking faults can be observed. The substructure of martensite may probably be the result of accommodation deformation during martensitic transformations.

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