欢迎登录材料期刊网

材料期刊网

高级检索

Li4Ti5O12作为锂离子电池负极材料,在Li嵌入和脱出的过程中,其晶型不发生改变,被公认为"零应变"材料,具有优良的循环性能和使用寿命.详细地评迷了蒸发溶剂法、Sol-gel法及水热法等软化学法合成Li4Ti5O12的制备工艺及研究现状,并比较了它们的优缺点,探讨了Li4Ti5O12的未来发展方向.

参考文献

[1] Gurefi A;Charest P;Kinoshita K et al.Nano electronically conductive titanium-spinel as lithium-ion storage negative[J].Journal of Power Sources,2004,126:163.
[2] Kim D H;Ahn Y S;Kim J .Polyol-mediated synthesis of Li4Ti5O12 nanoparticle and its electrochemical properties[J].Electrochera Commun,2004,6:1093.
[3] Leonidov I A;Leonidova O N;Perelyaeva L A et al.Structure ionic conduction and phase transformation in lithium titanate Li4Ti5O12[J].Physics of the Solid State,2003,45(11):2183.
[4] Tsutomu Ohzuku;Atsushi Ueda;Nofihiro Yamamoto .Zero-strain insertion material of Li[Li1/3 Ti5/3] 4 for rechargeable lithium cells[J].Journal of the Electrochemical Society,1995,142:1431.
[5] Amatucci Glenn G .Nanostructure lithium titanate electrode for high cycle rate recharge.able electrochemical cell[P].US,7211350,2007-05-01.
[6] Kiyoshi Nakahara;Ryosuke Nakajima;Tomoko Matsushima et al.Preparation of particulate Li4Ti5O12 having excellent characteristics as an electrode active material for power storage cells[J].Journal of Power Sources,2003,117:131.
[7] Peramunage D;Abraham K M .The Li4Ti5O12/PAN dectrolyte/LiMn2O4 rechargeable battery with passivation-free electrodes[J].Journal of the Electrochemical Society,1998,145(08):2615.
[8] 李运姣,洪良仕,习小明.锂离子电池正极材料LiFePO4的湿化学合成研究进展[J].矿冶工程,2005(04):58-61.
[9] 徐如人;庞文琴.无机合成与制备化学[M].北京:高等教育出版社,2001
[10] 王欣,林振汉,唐辉,张强.液相法制备纳米ZrO2粉体的研究进展[J].稀有金属快报,2007(01):33-39.
[11] 董殿权,郑春辉.尖晶石型Li4Ti5O12纳米粉体的合成[J].青岛科技大学学报(自然科学版),2007(02):103-106.
[12] Wen Zhaoyin;Gu Zhonghua;Huang Shahua et al.Research on spray-dried lithium titanate as electrode materials for lithiumion batteries[J].Journal of Power Sources,2005,146:670.
[13] 赵改青,王晓波,刘维民.喷雾干燥技术在制备超微及纳米粉体中的应用及展望[J].材料导报,2006(06):56-59.
[14] 杨建文,钟晖,钟海云,戴艳阳,李荐,赵绚.Synthesis and electrochemical properties of nanocrystalline Li[Li1/3Ti5/3O4] by complex sol-gel method[J].中国有色金属学会会刊(英文版),2004(05):1012-1016.
[15] Venkateswarlu M;Chen C H;Do J S et al.Electrochemical properties of nano-sized Li4 Ti5O12 powders synthesized by a sol-gel process and characterized by X-ray absorption spectroscopy[J].Journal of Power Sources,2005,146:204.
[16] Hao Yanjing;Lai Qiongyn;Lu Jizheng et al.Synthesis and characterization of spinel Li4 Ti5O12 anode material by oxalic acid-assisted sol-gel method[J].Journal of Power Sources,2006,158:1358.
[17] Hao Yanjing;Lai Qiongyu;Liu Dongqiang et al.Synthesis by citric acid sol-gel method and electrochemical properties of Li4 Ti5O12 anode material for lithium-ion battery[J].Materials Chemistry and Physics,2005,94:38.
[18] Hao Yanjing;Lai Qiongyu;Lu Jizbeng et al.Synthesis by TEA sol-gel method and electrochemical properties of Li4 Ti5O12anode material for lithiura-ion battery[J].Solid State forties,2005,176:1201.
[19] Hao Yanjing;Lai Qiongyu;Lu Jizheng et al.Influence of various complex agents on electrochemical property of Li4 Ti5O12anode material[J].Journal of Alloys and Compounds,2007,439:330.
[20] 贺慧,程璇,张颖.锂离子电池负极材料Li4Ti5O12的结构和性能[J].材料研究学报,2007(01):82-86.
[21] 王斌,瞿美臻,林浩强,于作龙.煅烧温度对Li4Ti5O12的电化学性能的影响[J].合成化学,2006(06):631-633.
[22] 高剑,姜长印,应皆荣,万春荣.锂离子电池负极材料球形Li4Ti5O12的合成及性能研究[J].无机材料学报,2007(01):176-180.
[23] 何则强,刘文萍,熊利芝,陈上,吴显明,樊绍兵.锂离子电池用Li4Ti5O12-碳复合材料的制备与电化学性能[J].无机化学学报,2007(04):733-737.
[24] 何则强,熊利芝,陈上,吴显明,刘文萍,黄可龙.Li4Ti5O12-聚苯胺复合材料的合成与表征[J].无机化学学报,2007(08):1382-1386.
[25] Dina Fattakhova;Petr Krtil .Electrochemical Activity of Hydrothermally Synthesized Li-Ti-O Cubic Oxides toward Li Insertion[J].Journal of the Electrochemical Society,2002(9):A1224-A1229.
[26] Li Junrong;Tang Zilong;Zhang Zhongtai .Controllable formation and electrochemical properties of one-dimensional nanostructured spinel Li4 Ti5O12[J].Electrochemistry Communications,2005,7:894.
[27] J. Li;Z. Tang;Z. Zhang .Excellent Low-Temperature Lithium Intercalation Performance of Nanostructured Hydrogen Titanate Electrodes[J].Electrochemical and solid-state letters,2005(11):A570-A573.
[28] Dina Fattakhova;Valery Petryldn;Jiri Brus et al.Solvothermal synthesis of electrochemical behavior of nanocrystalline cubic Li-Ti-O oxides with cationic disorder[J].Solid State Ionics,2005,176:1877.
[29] Tereza Kostlanova;Jiff Dedecek;Petr Krtil .The effect of the inner particle structure on the electronic structure of the nano-crystalline Li-Ti-O spinels[J].Electrochimica Acta,2007(5):1847-1856.
[30] Petr Krtil;Jiri Dedecek;Tereza Kostlanova .~6Li MAS NMR Study of Lithium Insertion into Hydrothermally Prepared Li-Ti-O Spinel[J].Electrochemical and solid-state letters,2004(7):A163-A166.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%