概括介绍了电容器用钽铌粉的研究进展,介绍了钽粉的3种钠还原制备方法的化学反应机理并进行了比较,同时还介绍了铌粉的制备方法,包括铝热还原法、电解还原法、蒸气还原法、钠还原法和金属热还原法;阐述了钽铌粉中杂质的测定方法以及有关钽铌粉的其它研究进展.
The progress of tantalum powder and niobium powder is reviewed. The chemical reaction mechanism with three sodium reduction methods is introduced and compared. New reduction process of tantalum powder is presented includeing electrochemical reduction, gas reduction, sodium reduction, metallothermic reduction, while niobium powder is prepared by aluminothermic reduction process. And the determination methods for impurities in tantalum powder and niobium powder are introduced. Other progress of tantalum powder and niobium powder is reviewed.
参考文献
[1] | 吴铭.钽、铌冶金工艺学[M].北京:中国有色金属工业总公司,1986:163. |
[2] | 何季麟,潘伦桃,郑爱国,李海军.氧化钽(铌)还原制取钽(铌)粉的新方法[C].中国有色金属学会第5届学术年会论文集,2003:6-8. |
[3] | 朱鸿民 .低温还原制备钽、铌超细粉及其反应机理研究[R].北京:TMS,1999. |
[4] | Zhu Hongmin;Sadoway Donald R .Synthesis of nanoscale particles of Ta and Nb3 Al by homogeneous reduction in liquid ammonia[J].Journal of Materials Research,2001,16(09):2544. |
[5] | 朱鸿民;何季麟 .微细钽、铌粉末的处理方法和由该方法制得的粉末[P].中国,ZL03122325.7,2003-04-30. |
[6] | 何季麟.钽铌电子材料新进展(Ⅰ)[J].稀有金属快报,2004(02):1-5. |
[7] | Chen G Z;Fray D J;Farthing T W .Direct electrochemical reduction of titanium dioxide to titanium in molten calcium chloride[J].NATURE,2000,407(21):361. |
[8] | George Z. Chen;Derek J. Fray .Voltammetric Studies of the Oxygen-Titanium Binary System in Molten Calcium Chloride[J].Journal of the Electrochemical Society,2002(11):E455-E467. |
[9] | 杨守春.PFC剑桥钛工艺法的开发现状[J].现代材料动态,2004(04):13. |
[10] | Yan X Y;Fray D J.Production of niobium powder by direct electro-chemical reduction of Nb2 O5 in a eutectic CaCl2-NaCl melt[J].Metallurgical Transactions B,2002(33):685. |
[11] | 郭胜惠,彭金辉,张世敏,张利波,范兴祥.CaCl2体系中电解还原TiO2制取钛的研究[J].稀有金属,2004(06):1091-1094. |
[12] | 李军义,刘卫国,赵红运,侯俊峰,袁强辉.电解法制备钽粉的研究[J].宁夏工程技术,2008(02):124-126. |
[13] | Yang W C;Brecher L E;Cleary J G.Chemical vapor deposition of tungsten from hydrogen reduction of WCl6 with dopants[A].Boston:Massachusetts,1973:382. |
[14] | Yoshizawa Aknori(Toho.Zinc.Co.,Ltd.) .Process for producing fine powdery metal[P].US,4383852,1983-05-17. |
[15] | 曹茂盛 .气相还原法制备α-Fe超细粉末[J].材料科学与工艺,1995,3(03):67. |
[16] | Park Kyun Young;Jang Hee Dong;Choi Cheong Song .Vaporphase synthesis anf characterization of ultrafine iron powders[J].Aerosol Sci Techn,1998,28(03):215. |
[17] | 朱骏,马春红,郭晓菲,朱鸿民.气相还原制备超细微铌和钽粉末[J].稀有金属,2007(01):53-56. |
[18] | 吴全兴.电容器用铌粉和钽粉制备技术的进展[J].稀有金属快报,2006(06):1-5. |
[19] | 邓丽琴,许茜,李兵,翟玉春,黄振奇.电脱氧法由Nb2O5直接制备金属铌[J].中国有色金属学报,2005(04):541-545. |
[20] | 胡小锋,许茜.CaCl2-NaCl熔盐电脱氧法制备金属Ta[J].金属学报,2006(03):285-289. |
[21] | D. J. Fray;G. Z. Chen .Reduction of titanium and other metal oxides using electrodeoxidation[J].Materials Science and Technology: MST: A publication of the Institute of Metals,2004(3):295-300. |
[22] | Serjak W A;Schechter L .Process In CARTS 2000Nb M[R].,2000. |
[23] | 刘世毅,喻小青,王静,宋金华.电感耦合等离子体质谱法测定钽粉中的磷[J].稀有金属与硬质合金,2005(04):35-37. |
[24] | 朱艳.高频红外吸收法测定钽粉、铌粉和碳化钽中的碳[J].化学分析计量,2004(04):49-50. |
[25] | 于红燕,蒋宁芬.钽铌复合物中氯含量的测定[J].稀有金属与硬质合金,2007(04):39-41. |
[26] | 李小莉.钽铌中氢质量含量的测定[J].宁夏工程技术,2007(04):353-354,357. |
[27] | 田孔泉,郝红梅,张卫杰,李亚琴,伏军胜,杨丽明.ICP-MS测定超高纯钽铌及其化合物中痕量杂质元素[J].光谱实验室,2004(03):551-555. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%