{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"讨论了葵花油改性醇酸树脂的合成、TDI/TMP固化剂的制备及氨基树脂的选择,确定了氨基树脂和醇酸树脂与固化剂的配比,简介了自干型氨基漆的技术指标.","authors":[{"authorName":"热合曼","id":"2341ce5a-4304-4814-9651-82c8156d8dcf","originalAuthorName":"热合曼"}],"doi":"10.3969/j.issn.0253-4312.2000.12.007","fpage":"18","id":"c881b691-c6a8-4a37-a625-45cc9afa55b3","issue":"12","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"03842f76-8ff4-4388-9a83-d253d8c05477","keyword":"自干型","originalKeyword":"自干型"},{"id":"900b4aa9-61b5-4eca-b165-582015707ec5","keyword":"氨基树脂","originalKeyword":"氨基树脂"},{"id":"c54f6868-e3ce-4521-9868-d457017e1fce","keyword":"醇酸树脂","originalKeyword":"醇酸树脂"},{"id":"4dbe2e32-fb0a-481c-a5e5-1541709ce3d7","keyword":"TDI/TMP","originalKeyword":"TDI/TMP预聚物"}],"language":"zh","publisherId":"tlgy200012007","title":"TDI/TNP 固化型自干氨基醇酸树脂漆","volume":"30","year":"2000"},{"abstractinfo":"讨论了甲苯二异氰酸酯-三羟甲基丙烷(TDI-TMP)的固体分、投料比、反应温度和溶剂等因素对对贮存稳定性的影响,确定了制备贮存稳定性好的TDI-TMP的工艺条件.","authors":[{"authorName":"郑绍成","id":"dc0771b7-66db-4b04-9592-7998a4f94bd9","originalAuthorName":"郑绍成"}],"doi":"10.3969/j.issn.0253-4312.2002.06.007","fpage":"17","id":"b6d410e8-37ba-4c8e-8719-611692c38f73","issue":"6","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"fcdd0c42-0a3d-4af7-a081-94343d894d5d","keyword":"贮存稳定性","originalKeyword":"贮存稳定性"},{"id":"10448880-62dd-429a-aaef-cfed544abb5c","keyword":"影响因素","originalKeyword":"影响因素"},{"id":"9309a5c2-f28b-4e04-82ee-6f6aedcdfed2","keyword":"TDI-TMP","originalKeyword":"TDI-TMP"}],"language":"zh","publisherId":"tlgy200206007","title":"影响TDI-TMP贮存稳定性的因素","volume":"32","year":"2002"},{"abstractinfo":"阐述了直接合成法制造低游离TDI多异氰酸酯的配方设计中配方参数平衡的原理.提供了通过大量的试验归纳得出的各组低游离TDI的可取的实用配方参数范围.从配方参数的角度讨论了直接合成法的优缺点及应用前景.","authors":[{"authorName":"方旭升","id":"b4a75655-bfa6-4fc5-91ea-bb4e95b49aeb","originalAuthorName":"方旭升"},{"authorName":"张彩珍","id":"97878141-17ca-48df-b416-146cefe323a5","originalAuthorName":"张彩珍"}],"doi":"10.3969/j.issn.0253-4312.2007.01.017","fpage":"55","id":"db8d65f6-88a2-4597-af6d-2dcca68a6cfc","issue":"1","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"a510aa07-122d-4731-bae4-a5f5d87abe95","keyword":"直接合成法","originalKeyword":"直接合成法"},{"id":"2b5266cb-30c9-4b60-ae82-91a58eed8741","keyword":"多异氰酸酯","originalKeyword":"多异氰酸酯预聚物"},{"id":"d31ebab1-f619-4ba4-af25-45da47ae0337","keyword":"游离TDI","originalKeyword":"游离TDI"},{"id":"3212e20b-6a10-4afb-b380-af5d16f0e608","keyword":"配方参数","originalKeyword":"配方参数"}],"language":"zh","publisherId":"tlgy200701017","title":"直接合成法制造低游离TDI多异氰酸酯的配方设计与实用配方参数","volume":"37","year":"2007"},{"abstractinfo":"在不加催化剂的条件下用化学分析法研究了甲苯二异氰酸酯(TDI)和三羟甲基丙烷(TMP)的反应动力学,结果表明:-NCO与-OH的反应属于二级反应,由于TDI中对位-NCO基(C4-NCO)和邻位-NCO基(C2,6-NCO)反应活性的差异,在动力学曲线上呈现出一个明显的折点,该折点被认为是C4-NCO和C2,6-NCO反应活性的分界点.同时计算了不同温度下C4-NCO和C2,6-NCO的反应速率常数(K1,K2)和活化能(Ea1,Ea2),随着温度的升高,C4-NCO和C2,6-NCO反应活性都增加但两者的差异逐渐减小.同时还研究了不同-NCO和-OH配比下反应动力学.","authors":[{"authorName":"雷鸣","id":"93e58557-6817-4cb0-a703-d5991c256d5a","originalAuthorName":"雷鸣"},{"authorName":"黄洪","id":"442d57d6-6e7f-4ae0-835a-773c0bbce4c1","originalAuthorName":"黄洪"},{"authorName":"何勇","id":"785e9d69-434e-47a5-8bfa-9f6850e8aac3","originalAuthorName":"何勇"},{"authorName":"张心亚","id":"e4ad6eb1-5952-4a32-807f-fe181b0cd471","originalAuthorName":"张心亚"},{"authorName":"殷代武","id":"e4cae5e3-356a-4e63-b57f-e4c6b4dea119","originalAuthorName":"殷代武"}],"doi":"10.3969/j.issn.0253-4312.2011.06.006","fpage":"22","id":"5256a6ca-36d8-4843-b122-81fd4c771912","issue":"6","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"8c4bab1e-8b86-44eb-9546-462ef6470227","keyword":"聚氨酯固化剂","originalKeyword":"聚氨酯固化剂"},{"id":"7d23a7b1-c6f4-4077-bff6-de9d9e2515fb","keyword":"动力学","originalKeyword":"动力学"},{"id":"c4618f95-1ef0-4789-bf0e-faad02498449","keyword":"甲苯二异氰酸酯","originalKeyword":"甲苯二异氰酸酯"},{"id":"d050ab31-3e6b-47a5-88df-9493f023ddd7","keyword":"三羟甲基丙烷","originalKeyword":"三羟甲基丙烷"}],"language":"zh","publisherId":"tlgy201106006","title":"TDI-TMP合成反应动力学研究","volume":"41","year":"2011"},{"abstractinfo":"以甲苯二异氰酸酯(TDI)、三羟甲基丙烷(TMP)为原料,采用金属离子催化聚合法合成了低游离TDI含量的聚氨酯固化剂.结果表明:自制的金属离子催化剂A101的催化效果最佳.合成的产品符合国家标准,残留TDI单体的含量小于0.5%.探讨了A101的催化机理,并计算了反应体系的活化能.计算表明:添加A101催化剂能够有效降低反应的活化能.","authors":[{"authorName":"郭双华","id":"29849028-9fd8-48f9-a6c6-d4cab9befa3f","originalAuthorName":"郭双华"},{"authorName":"张巨生","id":"1bd814ac-da86-4f0f-b7d7-d497cbd34874","originalAuthorName":"张巨生"},{"authorName":"刘志刚","id":"db59f22c-796b-4f77-b312-0192915ae9ef","originalAuthorName":"刘志刚"},{"authorName":"吕祖舜","id":"12f063e2-29db-47cb-8783-4c93add19442","originalAuthorName":"吕祖舜"}],"doi":"10.3969/j.issn.0253-4312.2008.09.003","fpage":"11","id":"24a1066c-449c-4537-b724-c919ab77798b","issue":"9","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"c489df58-da3c-4ce1-9a0d-657b96c6113e","keyword":"低游离TDI","originalKeyword":"低游离TDI"},{"id":"99902926-9f4b-4539-94ca-a4f0b5fdb83c","keyword":"催化聚合","originalKeyword":"催化聚合"},{"id":"519d0441-c851-4f4f-9490-e36eb7d908d5","keyword":"TDI-TMP","originalKeyword":"TDI-TMP"}],"language":"zh","publisherId":"tlgy200809003","title":"降低TDI-TMP固化剂中游离TDI含量的研究","volume":"38","year":"2008"},{"abstractinfo":"简述了固化剂TMP-TDI(三羟甲基丙烷-甲苯二异氰酸酯)中的有机溶剂和游离TDI对人体和环境的危害.介绍了环保型固化剂TMP-TDI的无溶剂化和降低固化剂中游离TDI的研究进展.重点介绍了降低游离TDI的各种方法,并进行了比较.提出了在我国现阶段适用的方法.","authors":[{"authorName":"陈立军","id":"1fe163e3-c8cc-419d-bc8a-6a678125e4bc","originalAuthorName":"陈立军"},{"authorName":"陈焕钦","id":"fdd71768-c903-42ce-9634-32b01748b1fa","originalAuthorName":"陈焕钦"}],"doi":"10.3969/j.issn.0253-4312.2004.07.012","fpage":"38","id":"919c8edc-28be-4c02-b6c8-47a8ecdb2f8a","issue":"7","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"dd0c2e21-8b5d-431c-a279-2ad7006484f0","keyword":"聚氨酯涂料","originalKeyword":"聚氨酯涂料"},{"id":"b0a61e2d-d20a-4293-b962-ae7c89713916","keyword":"固化剂","originalKeyword":"固化剂"},{"id":"8530d671-bcf5-4423-a1de-c09e4ebfc5d2","keyword":"甲苯二异氰酸酯","originalKeyword":"甲苯二异氰酸酯"},{"id":"cebb02e6-3b15-4ffb-8f85-6b116b998dbd","keyword":"三羟甲基丙烷","originalKeyword":"三羟甲基丙烷"},{"id":"e206af43-b117-4c75-af19-a7a7123f0a66","keyword":"环保型涂料","originalKeyword":"环保型涂料"}],"language":"zh","publisherId":"tlgy200407012","title":"环保型双组分聚氨酯固化剂TMP-TDI的研究进展","volume":"34","year":"2004"},{"abstractinfo":"将桐油用无水AlCl3引发聚合为低分子,再与沥青继续进行聚合反应以对其改性. 改性后的沥青针入指数和低温延度均有改善. 用红外、特性粘数[η]及薄层色谱方法对反应、聚合度及改性沥青进行了分析. 发现物主要与沥青中的胶质、沥青质发生了反应. 反应可以作为界面剂增加沥青中其它组分的相容性. 在沥青质上加成桐油后,可以克服其刚性强、互容性差的缺点,对稳定沥青的胶体结构、改善沥青的针入指数、低温延度有较好作用. 桐油体在沥青混合中的质量分数为3%~6%时沥青可具有较好的性能改善结果. ","authors":[{"authorName":"李国锋","id":"15b18e31-a120-43e1-a5bc-865327842fd9","originalAuthorName":"李国锋"},{"authorName":"胡克良","id":"546e97b5-349d-4d1f-b0e3-cb89b937a76f","originalAuthorName":"胡克良"},{"authorName":"黄允兰","id":"bfe447e2-dd21-4827-8ce1-031ee69febdd","originalAuthorName":"黄允兰"},{"authorName":"杨海洋","id":"f4d7cca4-711d-4524-9635-b363d390c5a3","originalAuthorName":"杨海洋"},{"authorName":"季明荣","id":"e2e17c52-7f76-4b26-9b1a-226e11b3fc4d","originalAuthorName":"季明荣"}],"doi":"10.3969/j.issn.1000-0518.2002.06.008","fpage":"544","id":"1d9a062f-5d38-465f-9581-03bd12d880e3","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"a8810d54-83e7-45d3-b94b-bcd99281a401","keyword":"沥青改性","originalKeyword":"沥青改性"},{"id":"5d688716-053e-4ae5-8529-f74b8f5f03d4","keyword":"桐油","originalKeyword":"桐油预聚物"},{"id":"250f912f-2a53-4a1f-b0ee-f595a86c12fd","keyword":"低温延度","originalKeyword":"低温延度"},{"id":"b65de888-8b61-4065-a528-eecfed10ebf8","keyword":"针入指数","originalKeyword":"针入指数"}],"language":"zh","publisherId":"yyhx200206008","title":"桐油改性沥青","volume":"19","year":"2002"},{"abstractinfo":"用于与TDI等二异氰酸酯反应制备多异氰酸酯的各种多元醇,包括单体多元醇、蓖麻油及其醇解、多羟基树脂等,可以归纳于\"的多元醇母体\"的概念之中.PU涂料中的\"多元醇\",应当明确区分为\"的多元醇母体\"与\"2KPU涂料的羟基组分\"两类.阐述了多元醇母体在中的基本作用与注重对多元醇母体进行研究的意义.","authors":[{"authorName":"方旭升","id":"4bbf7718-0bae-4747-a466-706c2a406e3d","originalAuthorName":"方旭升"},{"authorName":"张彩珍","id":"6207c81c-31d1-4080-8976-c9092476b215","originalAuthorName":"张彩珍"}],"doi":"10.3969/j.issn.0253-4312.2008.09.017","fpage":"57","id":"df57c4ce-3963-49fb-b1b1-5da4958099bc","issue":"9","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"8d43d522-2ca9-4f2b-9970-70d4cc47c033","keyword":"聚氨酯涂料","originalKeyword":"聚氨酯涂料"},{"id":"7f8eee34-50e7-42d2-ad15-73d86e18ba2c","keyword":"多异氰酸酯","originalKeyword":"多异氰酸酯"},{"id":"4e3ae8d7-5d9c-499e-bf71-684a7fabfb2c","keyword":"","originalKeyword":"预聚物"},{"id":"c327f68b-8e74-4ebb-8175-f9dc5718548b","keyword":"多元醇母体","originalKeyword":"多元醇母体"}],"language":"zh","publisherId":"tlgy200809017","title":"氨基甲酸酯型多异氰酸的多元醇母体研究","volume":"38","year":"2008"},{"abstractinfo":"探讨了利用MDI(二苯基甲烷二异氰酸酯)低毒、低饱和蒸汽压、优异的低温性能来制备固化剂的时代背景、方法及其漆膜性能和在木器漆中的应用.设计温度70℃,反应时间4 h,理论-NCO含量为12.7%,固体分75%,并对产物进行表征.发现MDI/TMP固化剂具有高活性,优异的漆膜柔韧性,特别适合低温固化.分析了MDI/TMPTDI/TMP这2种聚氨酯固化剂物化性能及在木器漆中的异同点.","authors":[{"authorName":"周俊锋","id":"ec863941-dc51-47c1-971b-4cee275ded0d","originalAuthorName":"周俊锋"},{"authorName":"肖玉新","id":"8cd7adc5-5a05-445d-975f-6def79483f72","originalAuthorName":"肖玉新"},{"authorName":"华成明","id":"5fb6f8d5-6f3d-4ccc-a1e9-199bad843893","originalAuthorName":"华成明"},{"authorName":"张琴","id":"7521898d-2c61-401d-8b43-7fd4edf7cc84","originalAuthorName":"张琴"},{"authorName":"唐进伟","id":"91272cc6-2238-41d9-a22d-544b713aaf03","originalAuthorName":"唐进伟"},{"authorName":"王培鹏","id":"b0e073fa-e24c-4c4d-a35e-70fd9ced498f","originalAuthorName":"王培鹏"}],"doi":"10.3969/j.issn.0253-4312.2010.07.006","fpage":"21","id":"eb09d236-5328-40fc-85fb-6adf4db76a52","issue":"7","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"26bb46ac-709b-46d0-855b-ff62f92c7f41","keyword":"MDI/TMP固化剂","originalKeyword":"MDI/TMP固化剂"},{"id":"214a7135-1992-4a0a-97f6-e9e302f56b98","keyword":"环保","originalKeyword":"环保"},{"id":"523b02c0-f477-4ff2-83b7-eb9dc00cc54d","keyword":"双组分","originalKeyword":"双组分"},{"id":"78c3acc1-ee55-41fb-9903-cae227f87bbf","keyword":"聚氨酯涂料","originalKeyword":"聚氨酯涂料"}],"language":"zh","publisherId":"tlgy201007006","title":"环保型双组分聚氨酯固化剂MDI/TMP的开发及应用","volume":"40","year":"2010"},{"abstractinfo":"薄膜蒸发技术在几种常见的降低聚氨酯固化剂中游离甲苯二异氰酸酯(TDI)的方法中,是最经济有效的.然而在实际的蒸发操作过程中存在一个重要难题:固化剂难从设备中流出来,导致堵塞设备,出现事故.本研究从小试到中试进行系统研究,提出并实施了系列的解决方法:1在合成的过程中加大TDI/TMP的配比到质量比为4.6∶1,合成出分子量小的;2在反应后期加入万分之二的磷酸作为分离时候的副反应抑制剂;3改进薄膜蒸发器主体设备-蒸发柱,使之适合于分离TDI-TMP.通过这三个方面的改进,能完全避免分离TDI堵塞现象的发生.","authors":[{"authorName":"胡孝勇","id":"c0e991b7-d6a3-4cd4-82c4-81a7c22d966d","originalAuthorName":"胡孝勇"},{"authorName":"胡孝琼","id":"4c725e9c-8f5a-4cff-ac6a-b1a3f08dbc07","originalAuthorName":"胡孝琼"},{"authorName":"郭祀远","id":"ae73171b-a18d-4a8a-923b-a5d5bbbc6f8c","originalAuthorName":"郭祀远"},{"authorName":"陈焕钦","id":"d5b2b219-554e-46d4-b0d8-39dc01d228df","originalAuthorName":"陈焕钦"}],"doi":"10.3969/j.issn.1671-5381.2007.02.003","fpage":"9","id":"35c73424-84ff-4793-af03-bce7533279b8","issue":"2","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"a6595217-0e00-44e3-aa20-92e575860af0","keyword":"薄膜蒸发","originalKeyword":"薄膜蒸发"},{"id":"37cd1af4-2e19-43c2-a34c-0a3164cb4530","keyword":"TDI","originalKeyword":"TDI"},{"id":"554ad994-a132-4b90-8752-ddd0f2a87e65","keyword":"合成","originalKeyword":"合成"},{"id":"8c8cab69-5e5b-453e-a7c4-e0ea923a3517","keyword":"聚氨酯","originalKeyword":"聚氨酯"},{"id":"70eafe32-265a-4fc7-a657-602ea7ba527d","keyword":"TDI-TMP","originalKeyword":"TDI-TMP预聚物"}],"language":"zh","publisherId":"hccllhyyy200702003","title":"用薄膜蒸发器分离聚氨酯固化剂中游离TDI关键技术开发","volume":"36","year":"2007"}],"totalpage":4630,"totalrecord":46298}