{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以桥联硅氧烷1,1'-双[(2-三乙氧基硅基)乙基]<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>(BTEF)和正硅酸乙酯为前驱体,以十六烷基三甲基溴化铵为结构导向剂,采用共聚法制备了<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>功能化的周期介孔有机硅烷材料(PMO-Fc).同时以BTEF为修饰剂,以甲苯为分散剂,采用嫁接法制备了Fc-MCM-41杂化介孔材料,采用N2物理吸附、X射线衍射、透射电镜和红外光谱等手段对材料进行了表征,评价了其催化苯羟化反应活性.结果表明,PMO-Fc具有有序的<span style=\"color:red\">二</span>维六方形孔道结构,较大的比表面积和孔体积,在苯羟化反应中表现出比Fc-MCM-41更高的催化活性,苯酚的选择性和收率分别为65.3%和20.2%.","authors":[{"authorName":"张<span style=\"color:red\">铁</span>明","id":"ae61bc41-5280-4534-a813-cae51688766e","originalAuthorName":"张铁明"},{"authorName":"高鹏飞","id":"52dc5650-94e3-404c-bd18-c143ed19cef1","originalAuthorName":"高鹏飞"},{"authorName":"高春光","id":"b05146e4-3b37-4b42-8df8-1444f809d5fc","originalAuthorName":"高春光"},{"authorName":"杨恒权","id":"859376bb-0ee0-4cfe-bd6a-c2b9e2b76e48","originalAuthorName":"杨恒权"},{"authorName":"赵永祥","id":"a13ef723-5563-4d5a-a4ca-1ae497886829","originalAuthorName":"赵永祥"}],"doi":"10.3724/SP.J.1088.2010.91150","fpage":"701","id":"6dbd049a-fa8c-4938-bdae-e87f5e7ac74a","issue":"6","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报   "},"keywords":[{"id":"4c8a88d5-95c8-4ad2-8044-c2b239d506e9","keyword":"嫁接","originalKeyword":"嫁接"},{"id":"36d38b9e-8dbc-47c1-a133-637630c61fa1","keyword":"共聚","originalKeyword":"共聚"},{"id":"a95a5639-bd99-49dc-b981-361ace26d8d0","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>","originalKeyword":"二茂铁"},{"id":"1e0c25c0-9cd2-47d5-a2d8-864e32c6e5d2","keyword":"桥联硅氧烷","originalKeyword":"桥联硅氧烷"},{"id":"89905ae6-3533-462a-99d0-2d31bb0e6ace","keyword":"介孔材料","originalKeyword":"介孔材料"},{"id":"9d3436d5-25f7-4c74-a38f-5652da00cf81","keyword":"杂化","originalKeyword":"杂化"},{"id":"2610803d-abd0-4680-a066-e7ec4e7653ff","keyword":"苯","originalKeyword":"苯"},{"id":"1a0dbfec-1635-4b27-9cb8-2437b6696253","keyword":"羟化","originalKeyword":"羟化"},{"id":"498e96c3-acd0-4f74-8477-d8f129336846","keyword":"苯酚","originalKeyword":"苯酚"}],"language":"zh","publisherId":"cuihuaxb201006018","title":"共聚法和嫁接法制备<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>杂化介孔材料及其催化性能","volume":"31","year":"2010"},{"abstractinfo":"用SEM、TEM和XRD为主要分析手段比较研究了<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>在420℃和490℃加压炭化产物的组成与结构,结果表明:<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>在420℃的炭化产物组成为α-Fe,Fe3C和Fe-O,而490℃的炭化产物主要由Fe2.5C构成,说明温度的提高促使<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>向生成碳化物的方向发展.TEM测试表明产物Fe/C粒子呈现纳米级分散,说明通过控制<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>的热解温度可以由此制备具有不同组成的纳米Fe/C材料.","authors":[{"authorName":"宋怀河","id":"04b4700e-20cc-4aec-9919-e9b7f62dab9a","originalAuthorName":"宋怀河"},{"authorName":"陈晓红","id":"8fc65cf5-d417-4130-8544-c1368bb50262","originalAuthorName":"陈晓红"},{"authorName":"周成","id":"183fcc97-48b3-4c31-aade-546202b89512","originalAuthorName":"周成"}],"doi":"10.3969/j.issn.1007-8827.2002.01.003","fpage":"10","id":"56cc9da5-c7c0-4cec-a99b-1dd47908d091","issue":"1","journal":{"abbrevTitle":"XXTCL","coverImgSrc":"journal/img/cover/XXTCL.jpg","id":"70","issnPpub":"1007-8827","publisherId":"XXTCL","title":"新型炭材料"},"keywords":[{"id":"2bd208c2-68d8-48cb-96b8-f65da65e0291","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>","originalKeyword":"二茂铁"},{"id":"18c5285c-7c6a-4044-891d-7e27a6d7d231","keyword":"炭化","originalKeyword":"炭化"},{"id":"753c36eb-4715-4cf0-b8f4-e5649fefaee3","keyword":"纳米颗粒","originalKeyword":"纳米颗粒"}],"language":"zh","publisherId":"xxtcl200201003","title":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>加压炭化的研究","volume":"17","year":"2002"},{"abstractinfo":"研究了<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>加入铝碳耐火材料中后,铝碳耐火材料性能的变化.与仅添加Si和Al试样的性能相比,添加<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>的试样的强度,抗氧化性明显增大,且<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>的含量为1%～3%左右时,复合添加Si、Al和<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>的试样的强度及抗氧化性均有较大提高.","authors":[{"authorName":"郭巍","id":"f3d15a00-08f3-460e-bb6d-142732ad8955","originalAuthorName":"郭巍"},{"authorName":"安胜利","id":"be6b9a5b-9803-4516-8135-9c0fee112ecb","originalAuthorName":"安胜利"}],"doi":"10.3969/j.issn.1001-1625.2007.05.035","fpage":"1011","id":"5276ca97-f870-46a8-87c3-3fda0af28c4e","issue":"5","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报   "},"keywords":[{"id":"c4b611a1-9294-49c5-9b2b-0b766aa4ff9d","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>","originalKeyword":"二茂铁"},{"id":"753474cd-04df-4a50-ac18-e996be6fc9f5","keyword":"强度","originalKeyword":"强度"},{"id":"b7e19a6b-5a3d-46d4-8417-3290aecb634d","keyword":"抗氧化性","originalKeyword":"抗氧化性"},{"id":"c1fc48cb-2779-411f-9db8-05d81c2d92ab","keyword":"铝碳耐火材料","originalKeyword":"铝碳耐火材料"}],"language":"zh","publisherId":"gsytb200705035","title":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>的加入对铝碳耐火材料性能的影响","volume":"26","year":"2007"},{"abstractinfo":"生漆中主要的成膜物质为漆酚,而漆酚<span style=\"color:red\">二</span>聚体或多聚体的含量直接影响生漆的干燥速率,常采用<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>催干.采用凝胶渗透色谱法(GPC)研究了<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>对生漆漆酚氧化聚合过程的影响,并考察了其对生漆漆酚成膜性能的影响.结果表明:<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>对生漆漆酚氧化聚合物形成的过程具有抑制作用,并且随着<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>加入量增大其对漆酚氧化聚合物的抑制作用越明显,在<span style=\"color:red\">二</span><span style=\"color:red\">茂</span>铁质量分数为5％时对漆酚氧化聚合物抑制作用最大;同时<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>对生漆漆膜性能影响不大.","authors":[{"authorName":"李松标","id":"d44032c6-ce3a-4f9c-9c11-fd3dcf7b6585","originalAuthorName":"李松标"},{"authorName":"魏铭","id":"ca2b0a2b-4177-4069-8476-03900dc74868","originalAuthorName":"魏铭"},{"authorName":"丁方煜","id":"edb99cb3-62d8-4788-8a23-87e337ec810c","originalAuthorName":"丁方煜"},{"authorName":"王勤","id":"34a493d6-8ff0-4770-a991-6919200a8f7f","originalAuthorName":"王勤"},{"authorName":"刘晓芳","id":"39b5d9ac-e5db-4597-9fb5-3af86583c16c","originalAuthorName":"刘晓芳"},{"authorName":"徐梦婷","id":"20944022-9e9b-49aa-8212-22d47de4e4c7","originalAuthorName":"徐梦婷"}],"doi":"","fpage":"44","id":"f84d36c6-d2eb-4e3d-98b2-09cb77e34794","issue":"4","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"c1fbf27b-e076-4ae4-a588-ebb1e0eafaea","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>","originalKeyword":"二茂铁"},{"id":"7aaf2e11-e9b7-448c-9d42-e004901345c8","keyword":"漆酚","originalKeyword":"漆酚"},{"id":"63ebaa93-6d8b-4927-8be1-11af4fb447dd","keyword":"氧化聚合物","originalKeyword":"氧化聚合物"},{"id":"1f3c2157-fe27-4077-b680-8298d4b7392d","keyword":"漆膜性能","originalKeyword":"漆膜性能"}],"language":"zh","publisherId":"clbh201604013","title":"催干剂<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>对生漆成膜过程及漆膜性能的影响","volume":"49","year":"2016"},{"abstractinfo":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>是一类具有夹心结构的有机金属配合物,有良好的氧化-还原特性,可有效改善传感器电极上的电子传递效率.本文评述了近年来<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>及其衍生物在酶生物传感器、免疫传感器和离子传感器上的研究状况,并对其今后的发展方向做出展望.","authors":[{"authorName":"屈枫锦","id":"8b4b9923-da6b-4cf4-bb3e-e0f66f39f5a7","originalAuthorName":"屈枫锦"},{"authorName":"陈芳","id":"cb1f5de9-beeb-447c-b100-44d785bee030","originalAuthorName":"陈芳"},{"authorName":"侯秀璋","id":"c19e8505-9aee-4f97-b9aa-0bbc30698c8d","originalAuthorName":"侯秀璋"},{"authorName":"马晓燕","id":"5cb0f8fc-166a-4cef-b870-dd6cce1f9082","originalAuthorName":"马晓燕"}],"doi":"10.3724/SP.J.1095.2013.30062","fpage":"1393","id":"87cb721f-11d0-438e-aedd-1620abcf96bf","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"ea88f292-0c4c-4fbe-921c-beb3dd71582f","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>","originalKeyword":"二茂铁"},{"id":"a57eb11e-078f-4d94-8f81-aff78688e81b","keyword":"电子传递介体","originalKeyword":"电子传递介体"},{"id":"8f7876e3-2f66-4b49-9fdc-c2e96fc7ca0c","keyword":"传感器","originalKeyword":"传感器"},{"id":"48bccc4d-a0b6-4289-9c07-c2ebaad0bd08","keyword":"酶生物传感器","originalKeyword":"酶生物传感器"},{"id":"2b545d11-3c9d-46ac-bd0d-b5140cf69bae","keyword":"修饰电极","originalKeyword":"修饰电极"}],"language":"zh","publisherId":"yyhx201312003","title":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>及其衍生物在传感器上的应用进展","volume":"30","year":"2013"},{"abstractinfo":"以液体苯(C6H4)为放电介质,<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>为催化剂,石墨做电极,可大量制备洋葱状富勒烯(Onion-like Fullerenes:OLFs).本文重点考察了<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>对OLFs产量的影响,利用高分辨透射电镜(HRTEM)和 X-射线衍射(XRD)对所得产物进行了表征,结果表明:加入<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>可提高OLFs的产量;OLFs呈中空椭球状和多面体状,石墨化程度较高,OLFs直径分布可控制在10～30nm范围内.","authors":[{"authorName":"刘雯","id":"6e9bff73-2d11-4777-b4c1-8054140f5427","originalAuthorName":"刘雯"},{"authorName":"孟庆森","id":"59753131-bf55-4ecd-9d23-a7e18c99649b","originalAuthorName":"孟庆森"},{"authorName":"杨永珍","id":"d9e5eaae-9bd7-452b-8e49-8cd04f1d787c","originalAuthorName":"杨永珍"},{"authorName":"刘旭光","id":"aaea8c74-f3de-4e6e-9d9d-cc0af9c6629c","originalAuthorName":"刘旭光"},{"authorName":"许并社","id":"8e996587-be21-4434-983c-3f3a78061388","originalAuthorName":"许并社"}],"doi":"","fpage":"40","id":"d34ae001-04b4-4050-b805-12e7fe46c905","issue":"5","journal":{"abbrevTitle":"CLRCLXB","coverImgSrc":"journal/img/cover/CLRCLXB.jpg","id":"15","issnPpub":"1009-6264","publisherId":"CLRCLXB","title":"材料热处理学报"},"keywords":[{"id":"54b6a081-d627-4261-b179-600c59613734","keyword":"苯","originalKeyword":"苯"},{"id":"2169b5c8-f5ef-4215-a2c0-8f25dbb9de16","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>","originalKeyword":"二茂铁"},{"id":"d65d9763-bc94-4c56-950c-bbb6060d4c4f","keyword":"洋葱状富勒烯(OLFs)","originalKeyword":"洋葱状富勒烯(OLFs)"},{"id":"3980ae0c-54d3-4dc5-8013-a26c1ff2dbd4","keyword":"电弧放电","originalKeyword":"电弧放电"}],"language":"zh","publisherId":"jsrclxb200805010","title":"液苯加<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>溶液放电制备洋葱状富勒烯","volume":"29","year":"2008"},{"abstractinfo":"通过合成一种含<span style=\"color:red\">二</span>硫醚键的<span style=\"color:red\">二</span>胺及<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span><span style=\"color:red\">二</span>甲酰氯,将这两种单体进行低温溶液缩聚,合成出了聚芳硫醚<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>酰胺酰胺(FC-PASAA),通过红外、核磁证实了其化学结构,用DSC、TG等手段对FC-PASAA的热性能进行了表征,结果表明聚合物具有优良的热性能,通过X射线衍射表明FC-PASAA为无定形聚合物,溶解性试验表明FC-PASAA能溶解于DMF、DMSO、NMP等极性非质子溶剂,通过流延法制得了分离膜,其纯水通量为13.5～57.8L/m2·h.","authors":[{"authorName":"张刚","id":"3102df2e-a2bb-46e7-87af-ccbfa5cb5672","originalAuthorName":"张刚"},{"authorName":"范宇","id":"3332bdab-f617-475e-9067-2e59c8978038","originalAuthorName":"范宇"},{"authorName":"王言伦","id":"fbf6cfba-d8a8-4f54-8f6c-29de8e799a2d","originalAuthorName":"王言伦"},{"authorName":"龙盛如","id":"2e332e8b-7917-4c30-af39-25954d33ab81","originalAuthorName":"龙盛如"},{"authorName":"杨杰","id":"f774eac8-006d-40e8-a352-61c626017a88","originalAuthorName":"杨杰"}],"doi":"","fpage":"778","id":"1cbcb70c-8b78-4792-a68c-56c0de7634fa","issue":"5","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"203fe748-0c7c-4f16-a4d8-360ff2efcca4","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>","originalKeyword":"二茂铁"},{"id":"84e426de-1af5-4b02-9e26-18a32adf6bd5","keyword":"聚酰胺","originalKeyword":"聚酰胺"},{"id":"8cc88f48-b527-4a5c-b9b4-b6fa9152c9e2","keyword":"溶解性","originalKeyword":"溶解性"},{"id":"8bae0305-58fc-42ff-863a-be2f89ca82ba","keyword":"耐热性","originalKeyword":"耐热性"},{"id":"b4b4cf36-2dfe-4164-ad32-0ffc2240b288","keyword":"分离膜","originalKeyword":"分离膜"}],"language":"zh","publisherId":"gncl201005010","title":"聚芳硫醚砜<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>酰胺酰胺的合成及表征","volume":"41","year":"2010"},{"abstractinfo":"用1′-丁基<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>基甲酰丙酮为配体与三价稀土氯化物反应合成了十四种配合物,并对所有配合物进行了元素分析、红外光谱、核磁共振氢谱、热分析表征.分析结果表明配合物的组成为:(C4H9C5H4FeC5H4COCHCOCH3)3·Ln·xH2O(Ln=La,Lu,x=3;Ln=Ce,Ho,Er,Yb,x=1/2; Ln=Pr,Nd,Sm,Eu,Gd,Tb,Dy,Tm,x=1).运用DTA-TG法核实了配合物中水分子的个数.IR表明1′-丁基<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>基甲酰丙酮通过两个氧原子与稀土金属配位,生成稳定的六元螯合环结构.核磁数据表明受羰基和羟基去屏蔽作用影响的基团,在形成配合物后,化学位移均向低场稍有移动,进一步证实了配体的配位方式.","authors":[{"authorName":"吴海霞","id":"ac1f36df-7348-435f-95fd-6dbae1a5b760","originalAuthorName":"吴海霞"},{"authorName":"边占喜","id":"23d30ddf-97f1-47e1-8a61-31bee169efcb","originalAuthorName":"边占喜"},{"authorName":"李树臣","id":"d91e6c44-fa15-439c-9148-c938c510cb71","originalAuthorName":"李树臣"},{"authorName":"任杰","id":"95c9b504-6137-4a55-83d7-1a9798171f67","originalAuthorName":"任杰"}],"doi":"10.3969/j.issn.1004-0277.2006.06.005","fpage":"19","id":"9958db19-5df6-4d01-9452-2bb11272b58c","issue":"6","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"6ba4a29f-1d12-473f-a85d-37ec79671f50","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>","originalKeyword":"二茂铁"},{"id":"0394d771-e12b-42af-85e5-d2232d6c4e92","keyword":"β-<span style=\"color:red\">二</span>酮","originalKeyword":"β-二酮"},{"id":"a4ec2ada-6209-4619-b1b1-6f5b932f95e8","keyword":"稀土","originalKeyword":"稀土"},{"id":"49a1a629-6d3e-44d1-b5df-fa4f67dfebb5","keyword":"配合物","originalKeyword":"配合物"}],"language":"zh","publisherId":"xitu200606005","title":"1′-丁基<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>β-<span style=\"color:red\">二</span>酮稀土配合物的合成与性质","volume":"27","year":"2006"},{"abstractinfo":"选取<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>为掺杂剂,采用溶胶-凝胶法制备了掺杂PbTiO3粉体.基于TG-DTA分析结果给出了掺杂PbTiO3干凝胶的热处理条件和PbTiO3陶瓷的烧结条件.并讨论了影响掺杂PbTiO3凝胶的不同因素,确定了制备凝胶的最佳工艺条件.利用XRD和SEM对掺杂PbTiO3陶瓷的结构参数进行了分析,并探讨了掺杂对PbTiO3陶瓷电性能的影响.研究发现,<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>掺杂在试验研究范围内均能得到较好的凝胶,形成凝胶的pH值范围和掺量对体系影响不大.通过XRD分析表明,<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>掺杂PbTiO3陶瓷中可以看到掺杂相衍射峰.通过SEM观察发现,掺杂PbTiO3陶瓷晶粒结晶良好完整,晶界间几乎没有气孔,致密度高,同时晶粒的大小均匀,尺寸较小,为1～3 μm.还对掺杂PbTiO3陶瓷的电性能进行了初步探索,研究发现<span style=\"color:red\">铁</span>掺杂可以有效地降低PbTiO3陶瓷的电阻率.","authors":[{"authorName":"张晓红","id":"0d93daef-2f63-414e-8010-66367327c5c1","originalAuthorName":"张晓红"},{"authorName":"方双全","id":"b7c1a1cf-315e-41a9-9c7c-ab525b804958","originalAuthorName":"方双全"},{"authorName":"强亮生","id":"69f05e7d-0e5e-48fd-bdee-438a0d0cad78","originalAuthorName":"强亮生"}],"doi":"","fpage":"471","id":"064de8c3-1bbb-4452-938a-7006a73a994e","issue":"z1","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"322b5116-58a6-4016-8191-766287cd121a","keyword":"钛酸铅陶瓷","originalKeyword":"钛酸铅陶瓷"},{"id":"51f4ef28-b4e4-4f78-8845-b37b5084087a","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>","originalKeyword":"二茂铁"},{"id":"5e5eab84-26e1-4fd6-a796-6836c73ff1f4","keyword":"XRD","originalKeyword":"XRD"},{"id":"01078c7f-767b-4da9-a35b-e64a650b4a26","keyword":"SEM","originalKeyword":"SEM"},{"id":"ae7aa67b-e07c-4e5e-99c7-02a6bc62f5d6","keyword":"电阻率","originalKeyword":"电阻率"}],"language":"zh","publisherId":"xyjsclygc2007z1136","title":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>掺杂钛酸铅陶瓷的制备与性能研究","volume":"36","year":"2007"},{"abstractinfo":"以甲苯-乙醇混合体系作溶剂,用循环伏安法和交流阻抗法研究了<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>在铂电极上的电化学行为,进而测试了H2O2存在时<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>的循环伏安曲线. 结果表明,混合溶剂中溶液电阻和<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>在铂电极上的电化学反应电阻均随甲苯含量的增加而增大,<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>正离子能与H2O2发生均相化学反应,其电极反应机理为包含随后转化步骤的催化反应过程,即EC历程.","authors":[{"authorName":"郁章玉","id":"4f937618-0bec-4e2a-962b-0d59212dbb51","originalAuthorName":"郁章玉"},{"authorName":"齐丽云","id":"1e438af5-27a5-4695-a970-7d3c7c548a34","originalAuthorName":"齐丽云"},{"authorName":"秦梅","id":"f7704adc-e816-4262-9fab-1d4df2c51e14","originalAuthorName":"秦梅"},{"authorName":"郭道军","id":"b233975e-1520-462c-8d10-e2e7e0c6847a","originalAuthorName":"郭道军"},{"authorName":"王慧云","id":"6ee7e82b-04bf-40d7-959e-4dcf4eb8bd62","originalAuthorName":"王慧云"}],"doi":"10.3969/j.issn.1000-0518.2004.01.010","fpage":"41","id":"c92e2fd4-0093-48e0-bbb3-b90b78337c15","issue":"1","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"54abcf28-eddc-475f-9c2b-00e0ea79980c","keyword":"甲苯-乙醇混合介质","originalKeyword":"甲苯-乙醇混合介质"},{"id":"0cb7ef8c-8e48-443b-a9df-c2e2aa434885","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>","originalKeyword":"二茂铁"},{"id":"581fb6d1-c2e1-47dc-ae95-a7f935789606","keyword":"过氧化氢","originalKeyword":"过氧化氢"},{"id":"4416828a-38ec-421a-b345-1413bdf00e27","keyword":"电子转移机理","originalKeyword":"电子转移机理"}],"language":"zh","publisherId":"yyhx200401010","title":"甲苯-乙醇介质中<span style=\"color:red\">二</span><span style=\"color:red\">茂</span><span style=\"color:red\">铁</span>催化分解过氧化氢机理的探讨","volume":"21","year":"2004"}],"totalpage":3880,"totalrecord":38800}