{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"提出<span style=\"color:red\">碱性</span>NaOH体系分步<span style=\"color:red\">氧化</span><span style=\"color:red\">浸出</span>和盐酸<span style=\"color:red\">浸出</span>相结合的工艺预处理铅阳极泥,在<span style=\"color:red\">碱性</span>分步<span style=\"color:red\">氧化</span><span style=\"color:red\">浸出</span>过程中,实现As的<span style=\"color:red\">氧化</span>溶解和Bi等金属的<span style=\"color:red\">氧化</span>沉淀,然后用盐酸溶解<span style=\"color:red\">碱性</span><span style=\"color:red\">浸出</span>渣中的Bi,使贵金属富集在盐酸<span style=\"color:red\">浸出</span>渣中.结果表明:无论<span style=\"color:red\">碱性</span>直接<span style=\"color:red\">浸出</span>或酸性直接<span style=\"color:red\">浸出</span>都不能有效分离铅阳极泥中的有价金属;改变烘烤温度、延长空气<span style=\"color:red\">氧化</span>时间和改变<span style=\"color:red\">碱性</span>加压<span style=\"color:red\">氧化</span><span style=\"color:red\">浸出</span>温度都不能实现有价金属的分步分离.当双氧水用量大于0.2以后,<span style=\"color:red\">碱性</span><span style=\"color:red\">浸出</span>过程As的<span style=\"color:red\">浸出</span>率达到92%以上,<span style=\"color:red\">碱性</span><span style=\"color:red\">浸出</span>渣盐酸<span style=\"color:red\">浸出</span>时,Bi和Cu的<span style=\"color:red\">浸出</span>率分别达到99.0%和97.0%,且残余的As不溶解,实现铅阳极泥中有价金属分步分离的目的.","authors":[{"authorName":"刘伟锋","id":"77e22b0c-5bcf-4220-b654-07f25d48f67c","originalAuthorName":"刘伟锋"},{"authorName":"杨天足","id":"4980af87-6f2d-4f5f-915e-dc37e521ce0c","originalAuthorName":"杨天足"},{"authorName":"刘又年","id":"cf78ea99-39ea-43cf-9f1e-7c2a6debd876","originalAuthorName":"刘又年"},{"authorName":"陈霖","id":"eee1b398-3b32-4cf2-9e9e-eaf30af6bd3f","originalAuthorName":"陈霖"},{"authorName":"张杜超","id":"049bdd38-9250-4547-a18e-8697b5cb536c","originalAuthorName":"张杜超"},{"authorName":"唐谟堂","id":"e107d81a-882a-4610-8bce-c3e35446bfad","originalAuthorName":"唐谟堂"}],"doi":"","fpage":"549","id":"0c75d738-d3ef-4e88-8384-1e3174529d6c","issue":"2","journal":{"abbrevTitle":"ZGYSJSXB","coverImgSrc":"journal/img/cover/ZGYSJSXB.jpg","id":"88","issnPpub":"1004-0609","publisherId":"ZGYSJSXB","title":"中国有色金属学报"},"keywords":[{"id":"c8858148-9a17-4998-849f-b6cc5c351022","keyword":"铅阳极泥","originalKeyword":"铅阳极泥"},{"id":"bdb18a91-ef9f-48ba-a4d3-69fb62929b9d","keyword":"<span style=\"color:red\">碱性</span><span style=\"color:red\">氧化</span><span style=\"color:red\">浸出</span>","originalKeyword":"碱性氧化浸出"},{"id":"d7109b65-279c-4f2c-896e-7ed0f3bcf8ed","keyword":"盐酸<span style=\"color:red\">浸出</span>","originalKeyword":"盐酸浸出"},{"id":"15c816a1-52c0-4d72-b6d3-98df7f0f688c","keyword":"NaOH","originalKeyword":"NaOH"}],"language":"zh","publisherId":"zgysjsxb201302037","title":"脱除铅阳极泥中贱金属的预处理工艺选择","volume":"","year":"2013"},{"abstractinfo":"为阐明砷在铅阳极泥<span style=\"color:red\">碱性</span>加压<span style=\"color:red\">氧化</span><span style=\"color:red\">浸出</span>过程(NaNO3为<span style=\"color:red\">氧化</span>剂;NaOH为<span style=\"color:red\">碱性</span>试剂)中的热力学特性,通过热力学计算绘制体系离子质量浓度为0.1 mol/kg,温度为298、373、423和473 K条件下的As?Na?H2O、N?H2O和As?N?Na?H2O系的φ?pH图.结果表明,砷的存在形态与pH值有关.当pH值较低时,砷主要以H3AsO4、24H AsO?、24HAsO?、22H AsO?及As2O3的形式存在;当pH>11.14时,砷主要以34AsO?形式存在,高碱浓度及高温对砷<span style=\"color:red\">浸出</span>有利.<span style=\"color:red\">碱性</span>加压<span style=\"color:red\">氧化</span><span style=\"color:red\">浸出</span>实验表明,砷<span style=\"color:red\">浸出</span>率变化趋势与As?N?Na?H2O系φ?pH图的热力学分析结果一致,在453 K时砷的最佳<span style=\"color:red\">浸出</span>率为95.85%.","authors":[{"authorName":"何云龙","id":"313f550e-f7ff-40a8-a35e-c5458be08f9e","originalAuthorName":"何云龙"},{"authorName":"徐瑞东","id":"451b92f7-8c4e-4926-8f10-c80fa962d016","originalAuthorName":"徐瑞东"},{"authorName":"何世伟","id":"dde7eadc-70f1-4da9-8329-e22305c92dde","originalAuthorName":"何世伟"},{"authorName":"陈汉森","id":"7de0f113-e29e-4862-97e1-768c8f1e862f","originalAuthorName":"陈汉森"},{"authorName":"李阔","id":"c08e0364-0e45-4721-9359-be55dcb62525","originalAuthorName":"李阔"},{"authorName":"朱云","id":"469585a4-563e-47a5-9f63-0d5665e1ba47","originalAuthorName":"朱云"},{"authorName":"沈庆峰","id":"4e74c8f7-0306-4393-8e08-6dcb91c44802","originalAuthorName":"沈庆峰"}],"doi":"10.1016/S1003-6326(17)60075-X","fpage":"676","id":"f65c913f-db7c-460c-87cc-fa4c342578af","issue":"3","journal":{"abbrevTitle":"ZGYSJSXBEN","coverImgSrc":"journal/img/cover/ZGYSJSXBEN.jpg","id":"757390d2-7d95-4517-96f1-e467ce1bff63","issnPpub":"1003-6326","publisherId":"ZGYSJSXBEN","title":"中国有色金属学报(英文版)"},"keywords":[{"id":"3723a517-f1b6-44a5-ab54-ff6818690bdd","keyword":"φ?pH图","originalKeyword":"φ?pH图"},{"id":"a6dc129b-4dbe-4fc4-b375-9df5561609da","keyword":"As?N?Na?H2O系","originalKeyword":"As?N?Na?H2O系"},{"id":"c929a1e8-780b-4f91-8ef1-0fd182e6e104","keyword":"铅阳极泥","originalKeyword":"铅阳极泥"},{"id":"4fdf1e7f-df36-4613-8ac6-1a3f77c44fe9","keyword":"<span style=\"color:red\">浸出</span>","originalKeyword":"浸出"},{"id":"01519675-de6a-4445-9f5a-6d841949539f","keyword":"脱砷","originalKeyword":"脱砷"}],"language":"zh","publisherId":"zgysjsxb-e201703021","title":"铅阳极泥<span style=\"color:red\">碱性</span>加压<span style=\"color:red\">氧化</span><span style=\"color:red\">浸出</span>脱砷过程中As?N?Na?H2O系的φ?pH图","volume":"27","year":"2017"},{"abstractinfo":"研究了从低品位铷矿中回收铷的工艺流程,试图提高铷回收率、降低生产成本.将经过焙烧处理的<span style=\"color:red\">氧化</span>铷熟矿用苛性碱溶液<span style=\"color:red\">浸出</span><span style=\"color:red\">氧化</span>铷,<span style=\"color:red\">浸出</span>液为铷盐溶液,在<span style=\"color:red\">浸出</span>过程中研究NaOH浓度、温度、<span style=\"color:red\">浸出</span>时间、液固比及碱液循环次数对<span style=\"color:red\">氧化</span>铷<span style=\"color:red\">浸出</span>率的影响.研究结果表明:Rb2O<span style=\"color:red\">浸出</span>率随着碱浓度增加而增大,当碱液浓度达到0.125 mol·L-1时,Rb2O<span style=\"color:red\">浸出</span>率达到80％以上;温度从20℃升高到80℃时,Rb2O<span style=\"color:red\">浸出</span>率从62％增加到90％,但温度从40℃升高到80 ℃时,Rb2O<span style=\"color:red\">浸出</span>率维持在91％左右;随着<span style=\"color:red\">浸出</span>时间、液固比的增加,Rb2O<span style=\"color:red\">浸出</span>率也不断增大,当<span style=\"color:red\">浸出</span>时间超过5 min及液固比大于4时,Rb2O<span style=\"color:red\">浸出</span>率低于92％;碱液循环<span style=\"color:red\">浸出</span>熟矿4次以内时,Rb20<span style=\"color:red\">浸出</span>率不变,大于4次<span style=\"color:red\">浸出</span>率逐渐下降.在NaOH浓度为0.125 mol·L-1、<span style=\"color:red\">浸出</span>温度为40℃、液固比为4∶1、<span style=\"color:red\">浸出</span>时间为5min、碱液循环<span style=\"color:red\">浸出</span><span style=\"color:red\">氧化</span>铷熟矿4次的条件下,<span style=\"color:red\">氧化</span>铷<span style=\"color:red\">浸出</span>率达90％.该工艺为工业化生产提供基础理论依据.","authors":[{"authorName":"杨少华","id":"6ebd7c6a-b323-4b84-82ba-556d3be0bbcd","originalAuthorName":"杨少华"},{"authorName":"谢宝如","id":"eaa694a1-57cf-4b31-a791-b6aee47caa35","originalAuthorName":"谢宝如"},{"authorName":"王君","id":"0d83d276-2d89-4975-a607-d30c571a786b","originalAuthorName":"王君"},{"authorName":"赖晓晖","id":"58c44384-abee-4b1b-800a-716b66350c2d","originalAuthorName":"赖晓晖"},{"authorName":"王浩然","id":"d7e0d85a-3daa-4ba5-a6fc-3cfeea946392","originalAuthorName":"王浩然"},{"authorName":"房孟钊","id":"76f112ff-9687-4f4c-8731-e9733939aebd","originalAuthorName":"房孟钊"}],"doi":"10.13373/j.cnki.cjrm.2015.09.015","fpage":"861","id":"4bcac65a-c0e8-48e1-a5fa-ec956e223a08","issue":"9","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"1c809137-0a2a-43a5-82aa-65b1f4d011e7","keyword":"<span style=\"color:red\">氧化</span>铷熟矿","originalKeyword":"氧化铷熟矿"},{"id":"b77f3b45-4d9b-4221-a003-fb5943aa1e1a","keyword":"铷盐","originalKeyword":"铷盐"},{"id":"aed45195-2bdf-4027-8288-0992d9b4cdcd","keyword":"碱<span style=\"color:red\">浸出</span>","originalKeyword":"碱浸出"},{"id":"a169e641-a8fd-479e-bc75-6fb62f7ed518","keyword":"<span style=\"color:red\">浸出</span>率","originalKeyword":"浸出率"}],"language":"zh","publisherId":"xyjs201509015","title":"<span style=\"color:red\">氧化</span>铷熟矿的碱<span style=\"color:red\">浸出</span>","volume":"39","year":"2015"},{"abstractinfo":"研究Me(Ⅱ)-NH4Cl-NH3-H2O(MACA)体系处理兰坪低品位<span style=\"color:red\">氧化</span>锌矿的<span style=\"color:red\">浸出</span>过程,提出用循环<span style=\"color:red\">浸出</span>方法富集<span style=\"color:red\">浸出</span>液中锌浓度的工艺技术方案.结果表明:循环<span style=\"color:red\">浸出</span>的优化条件为液固比4:1、常温、搅拌速度300 r/min、<span style=\"color:red\">浸出</span>时间3 h;通过循环次数分别为14、15及10的3个阶段的循环<span style=\"color:red\">浸出</span>试验,获得渣计锌<span style=\"color:red\">浸出</span>率≥69%、<span style=\"color:red\">浸出</span>液锌浓度≥33 g/L的较好结果.该工艺具有流程简短、能耗低、净化容易、环境友好等优点,对低品位高<span style=\"color:red\">碱性</span>脉石难选<span style=\"color:red\">氧化</span>锌矿的开发利用具有重要意义.","authors":[{"authorName":"唐谟堂","id":"c588f8fa-b7cd-4571-9824-dbb32a2a31db","originalAuthorName":"唐谟堂"},{"authorName":"张家靓","id":"dd97ed59-3967-421f-995e-09c1945456d2","originalAuthorName":"张家靓"},{"authorName":"王博","id":"dc9c8294-1ef3-4025-9cc0-3f3383cc6ba5","originalAuthorName":"王博"},{"authorName":"杨声海","id":"c7dadb9a-27c8-458c-892e-c68f27a91186","originalAuthorName":"杨声海"},{"authorName":"何静","id":"f51cf958-e542-4c9c-b05d-301a22961cac","originalAuthorName":"何静"},{"authorName":"唐朝波","id":"063fbeb3-33ae-4f2d-97df-ef2d7fc65569","originalAuthorName":"唐朝波"},{"authorName":"杨建广","id":"c144c708-b9e8-45ca-8257-6d0b81033c72","originalAuthorName":"杨建广"}],"doi":"","fpage":"214","id":"dd73b23d-8b3e-4f2a-b3e3-ca3643b2a5a3","issue":"1","journal":{"abbrevTitle":"ZGYSJSXB","coverImgSrc":"journal/img/cover/ZGYSJSXB.jpg","id":"88","issnPpub":"1004-0609","publisherId":"ZGYSJSXB","title":"中国有色金属学报"},"keywords":[{"id":"7dc812de-67a1-4f29-ac4e-6d4c15a53810","keyword":"锌冶金","originalKeyword":"锌冶金"},{"id":"cb234c53-ade8-4236-ab83-c1a2c7fb1dd1","keyword":"低品位<span style=\"color:red\">氧化</span>锌矿","originalKeyword":"低品位氧化锌矿"},{"id":"9908e469-b71b-4b87-885b-323dda79cdc0","keyword":"MACA体系","originalKeyword":"MACA体系"},{"id":"5ee50078-7ae5-4357-8b4c-e8c815ee7e9f","keyword":"循环<span style=\"color:red\">浸出</span>","originalKeyword":"循环浸出"}],"language":"zh","publisherId":"zgysjsxb201101027","title":"低品位<span style=\"color:red\">氧化</span>锌矿在MACA体系中的循环<span style=\"color:red\">浸出</span>","volume":"21","year":"2011"},{"abstractinfo":"在100 g钴矿加入39 mL浓硫酸、<span style=\"color:red\">浸出</span>温度80 ℃、<span style=\"color:red\">浸出</span>时间2 h、液固比2-1时,采用常规的硫酸<span style=\"color:red\">浸出</span>,钴<span style=\"color:red\">浸出</span>率仅为16.86%;当100 g钴矿中加入42.5 mL浓硫酸、在焙烧温度630 ℃、焙烧时间1.5 h的焙烧条件下,采用硫酸化焙烧后硫酸<span style=\"color:red\">浸出</span>,钴<span style=\"color:red\">浸出</span>率达到67.48%;在100 g钴矿中加入39 mL浓硫酸和56 mL浓硝酸、<span style=\"color:red\">浸出</span>温度60 ℃、<span style=\"color:red\">浸出</span>时间4 h、液固比为3-1时,采用硝酸<span style=\"color:red\">氧化</span>下硫酸<span style=\"color:red\">浸出</span>,钴<span style=\"color:red\">浸出</span>率为96.35%.","authors":[{"authorName":"郑雅杰","id":"55f49d13-3e57-43ed-b51c-8db668a3e3b8","originalAuthorName":"郑雅杰"},{"authorName":"滕浩","id":"9540ed59-f52d-48b0-8188-4dcedc61cc9f","originalAuthorName":"滕浩"},{"authorName":"闫海泉","id":"9c54cdfc-1024-4a50-8d04-0f4eb95bc715","originalAuthorName":"闫海泉"}],"doi":"","fpage":"1418","id":"5c485669-ab69-46f3-a6b9-f7b0e07a738d","issue":"7","journal":{"abbrevTitle":"ZGYSJSXB","coverImgSrc":"journal/img/cover/ZGYSJSXB.jpg","id":"88","issnPpub":"1004-0609","publisherId":"ZGYSJSXB","title":"中国有色金属学报"},"keywords":[{"id":"97d0380f-8068-4c31-a1b5-5ecf37c57d1d","keyword":"高砷钴矿","originalKeyword":"高砷钴矿"},{"id":"a19d7cce-c150-4fe2-9e07-8f133d406052","keyword":"<span style=\"color:red\">氧化</span><span style=\"color:red\">浸出</span>","originalKeyword":"氧化浸出"},{"id":"cb17e9c1-8e8a-426f-8bdc-a7a719f8c247","keyword":"硫酸","originalKeyword":"硫酸"},{"id":"3a1ea23e-9038-4158-ad0e-a3d9cd3313eb","keyword":"硝酸","originalKeyword":"硝酸"}],"language":"zh","publisherId":"zgysjsxb201007027","title":"硝酸<span style=\"color:red\">氧化</span><span style=\"color:red\">浸出</span>难冶炼高砷钴矿","volume":"20","year":"2010"},{"abstractinfo":"研究了紫金山铜矿中主要目的矿物之一的蓝辉铜矿细菌<span style=\"color:red\">浸出</span>的过程和影响因素, 考察了蓝辉铜矿纯矿物的<span style=\"color:red\">浸出</span>特性. 实验室条件下细菌<span style=\"color:red\">浸出</span>蓝辉铜矿纯矿物的适宜参数为: 接种量50%; 培养基中Fe2+<span style=\"color:red\">氧化</span>量为60%. 20 d<span style=\"color:red\">浸出</span>周期内蓝辉铜矿<span style=\"color:red\">浸出</span>率可达80%以上. 通过向纯矿物<span style=\"color:red\">浸出</span>体系中添加黄铁矿探讨其强化<span style=\"color:red\">浸出</span>效果. 结果表明: 以1∶2或1∶1重量比添加黄铁矿能明显加快蓝辉铜矿的细菌<span style=\"color:red\">浸出</span>速率. 通过对蓝辉铜矿和黄铁矿在<span style=\"color:red\">浸出</span>介质中静电位的测定表明, 添加黄铁矿后能在<span style=\"color:red\">浸出</span>体系中形成较强的原电池效应, 促进目的矿物的溶解.","authors":[{"authorName":"温建康","id":"331fb4a3-5f33-4d29-b35c-2fe767e06477","originalAuthorName":"温建康"},{"authorName":"阮仁满","id":"fb8ac544-206c-4e74-ba2e-d08edeeee77a","originalAuthorName":"阮仁满"},{"authorName":"周峨","id":"b5887db2-e809-44e5-a01d-9b06deadde11","originalAuthorName":"周峨"},{"authorName":"张明明","id":"e2a10a0d-86e4-45ed-bbee-0f5c660313a2","originalAuthorName":"张明明"},{"authorName":"王淀佐","id":"a1217b91-1dc0-41df-9b6b-6fb02d7f947d","originalAuthorName":"王淀佐"}],"doi":"10.3969/j.issn.0258-7076.2007.06.020","fpage":"818","id":"3e3c03ee-0954-4fb3-add1-2a28ce125024","issue":"6","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"867f8060-8b69-440c-a433-72dbec4b5b84","keyword":"硫化铜矿","originalKeyword":"硫化铜矿"},{"id":"8abfcac9-ea94-40df-9f58-a57beaac1b57","keyword":"细菌<span style=\"color:red\">浸出</span>","originalKeyword":"细菌浸出"},{"id":"dd091449-93ff-4c7a-b80e-3c38417ee719","keyword":"蓝辉铜矿","originalKeyword":"蓝辉铜矿"},{"id":"f10de66e-e942-47c4-b674-6f0c7d9dfa25","keyword":"紫金山铜矿","originalKeyword":"紫金山铜矿"}],"language":"zh","publisherId":"xyjs200706020","title":"蓝辉铜矿的细菌<span style=\"color:red\">氧化</span><span style=\"color:red\">浸出</span>研究","volume":"31","year":"2007"},{"abstractinfo":"以硝酸镁为<span style=\"color:red\">氧化</span>剂系统研究了硝酸根存在下红土镍矿在硫酸体系中的高压<span style=\"color:red\">浸出</span>情况.通过单因素条件实验详细考察了硝酸镁添加量、初始硫酸酸度、反应温度、保温时间和液固比对<span style=\"color:red\">浸出</span>结果的影响,并得到最优<span style=\"color:red\">浸出</span>工艺条件:硝酸镁加入量0.06 g·g-1,初始酸度140 g·L-1,反应温度220℃,保温时间60 min,液固比2 ml·g-1.在上述最优工艺条件下进行综合试验,取得了良好的<span style=\"color:red\">浸出</span>结果,实现了镍、钴和铁的选择性<span style=\"color:red\">浸出</span>,镍、钴<span style=\"color:red\">浸出</span>率分别为90.9％和91.7％,而铁<span style=\"color:red\">浸出</span>率低至2.2％.最后借助X射线衍射(XRD)、反射显微镜及化学物相分析,对新体系下<span style=\"color:red\">浸出</span>过程机制进行了研究,该体系中<span style=\"color:red\">浸出</span>过程为溶解—<span style=\"color:red\">氧化</span>—沉淀机制.添加硝酸根较传统硫酸高压<span style=\"color:red\">浸出</span>省酸,经计算利用该技术处理11红土矿可节省H2SO4大约160 kg.","authors":[{"authorName":"马保中","id":"97faf2e7-b7f1-4c30-a8cd-4a8522353b6e","originalAuthorName":"马保中"},{"authorName":"杨玮娇","id":"e27a8488-7f63-410a-8fa7-676188183a16","originalAuthorName":"杨玮娇"},{"authorName":"王硕","id":"ee2c6ccf-8459-4fbe-ad87-fe4d657db3e5","originalAuthorName":"王硕"},{"authorName":"杨卜","id":"3fffa197-2467-45fd-80c8-6df3eb35f137","originalAuthorName":"杨卜"},{"authorName":"王成彦","id":"bf0faafb-3d8b-4475-a859-6d611bfa9bce","originalAuthorName":"王成彦"}],"doi":"10.13373/j.cnki.cjrm.2016.07.013","fpage":"715","id":"772789b3-2fcc-48a0-b022-29848badaf3e","issue":"7","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"ad9465ee-bd35-413b-8ad4-7bef6b183389","keyword":"红土矿","originalKeyword":"红土矿"},{"id":"0554bf58-fc79-4d11-973a-f75c44b4762b","keyword":"硝酸镁","originalKeyword":"硝酸镁"},{"id":"2889ac90-8250-4732-896c-ecf7d28ad736","keyword":"硫酸","originalKeyword":"硫酸"},{"id":"59a98fbd-065a-4288-86fe-6bf5878a5a1d","keyword":"混合体系","originalKeyword":"混合体系"},{"id":"cf3cc1fa-c963-4c04-9aa6-f95f4da38855","keyword":"高压<span style=\"color:red\">浸出</span>","originalKeyword":"高压浸出"}],"language":"zh","publisherId":"xyjs201607013","title":"硝酸根<span style=\"color:red\">氧化</span>高压硫酸<span style=\"color:red\">浸出</span>红土镍矿","volume":"40","year":"2016"},{"abstractinfo":"对含砷类型不同的金精矿和单矿物进行细菌<span style=\"color:red\">氧化</span>-氰化<span style=\"color:red\">浸出</span>研究,分析毒砂和雄黄对金精矿细菌<span style=\"color:red\">氧化</span>-氰化<span style=\"color:red\">浸出</span>效果的影响.结果表明:在细菌<span style=\"color:red\">氧化</span>过程中,含砷金精矿中的毒砂易被<span style=\"color:red\">氧化</span>分解,经过192 h的细菌<span style=\"color:red\">氧化</span>后,脱砷率可达93.10%;而雄黄无法被细菌<span style=\"color:red\">氧化</span>分解,且影响细菌活性,延长浸矿的停滞期;在氰化<span style=\"color:red\">浸出</span>过程中,毒砂非常稳定,不参与任何副反应;而雄黄易与CN-及保护碱发生副反应,且产生的沉淀物质会在金粒表面形成薄膜,从而降低氰化<span style=\"color:red\">浸出</span>效率.","authors":[{"authorName":"崔日成","id":"6f214420-fb45-416d-b17e-09a116659ffe","originalAuthorName":"崔日成"},{"authorName":"杨洪英","id":"7b16e8cc-8e9e-4422-b4df-c3a15718a2e0","originalAuthorName":"杨洪英"},{"authorName":"富瑶","id":"b8868b15-02be-400f-8d93-3db2a76bc957","originalAuthorName":"富瑶"},{"authorName":"陈森","id":"9fae68ef-f284-427c-90c2-756d2d3bae9f","originalAuthorName":"陈森"},{"authorName":"张硕","id":"aaba5d35-64cd-4b1f-b2c2-7db069354004","originalAuthorName":"张硕"}],"doi":"","fpage":"694","id":"72be9ffe-8acc-4f92-a9bc-ca8136f45553","issue":"3","journal":{"abbrevTitle":"ZGYSJSXB","coverImgSrc":"journal/img/cover/ZGYSJSXB.jpg","id":"88","issnPpub":"1004-0609","publisherId":"ZGYSJSXB","title":"中国有色金属学报"},"keywords":[{"id":"bd5be8d4-f444-4a76-ad31-1dd8f5467fcf","keyword":"雄黄","originalKeyword":"雄黄"},{"id":"628703de-8c3a-40d1-a012-7ea31d29bb05","keyword":"毒砂","originalKeyword":"毒砂"},{"id":"8f0ba89c-bd42-4d99-ab1b-0f75661dcb71","keyword":"细菌<span style=\"color:red\">氧化</span>","originalKeyword":"细菌氧化"},{"id":"5cf1f24d-abd3-4154-b98e-921b6f528606","keyword":"氰化<span style=\"color:red\">浸出</span>","originalKeyword":"氰化浸出"}],"language":"zh","publisherId":"zgysjsxb201103031","title":"不同含砷类型金矿的细菌<span style=\"color:red\">氧化</span>-氰化<span style=\"color:red\">浸出</span>","volume":"21","year":"2011"},{"abstractinfo":"针对低品位铀尾矿因脉石含量高、物相赋存状态复杂而造成的铀<span style=\"color:red\">浸出</span>率低的问题,提出添加辅助<span style=\"color:red\">氧化</span>剂破坏脉石结构而实现强化<span style=\"color:red\">浸出</span>铀的思路.采用单因素实验法对比常规酸浸和3种<span style=\"color:red\">氧化</span>剂(H2O2、MnO2和Fe3+)强化酸浸对铀<span style=\"color:red\">浸出</span>率的影响.结果表明:当<span style=\"color:red\">浸出</span>温度、硫酸浓度和液固比分别为30℃、1 mo1/L和20∶1时,采用常规酸浸6h后铀的<span style=\"color:red\">浸出</span>率仅为78％,而在相同的<span style=\"color:red\">浸出</span>条件下,强化酸浸1.5 h铀的<span style=\"color:red\">浸出</span>率可达到95％.<span style=\"color:red\">浸出</span>渣的XRD及SEM-EDS分析结果表明,H2O2及MnO2均能破坏脉石晶体结构,减少颗粒团聚,但添加MnO2后生成新的硅酸锰盐晶体,Fe3+不能破坏脉石结构,但其<span style=\"color:red\">氧化</span>作用在一定程度上能加快铀的<span style=\"color:red\">浸出</span>.","authors":[{"authorName":"李密","id":"e43a178d-30b2-4acf-a966-68ba34314eb4","originalAuthorName":"李密"},{"authorName":"张彪","id":"88599969-6a6e-4674-8025-d9fa7740fe98","originalAuthorName":"张彪"},{"authorName":"张晓文","id":"685478ed-ea36-4c93-94ac-65403a0a75d5","originalAuthorName":"张晓文"},{"authorName":"黄婧","id":"c3c112e5-0fa8-4676-9f91-c7ec362d6b09","originalAuthorName":"黄婧"},{"authorName":"丁德馨","id":"bf1a81e1-ef52-45af-b7ef-5be97fd95108","originalAuthorName":"丁德馨"},{"authorName":"叶勇军","id":"b491d784-0d82-476c-9d42-b74ab3fb255f","originalAuthorName":"叶勇军"}],"doi":"","fpage":"145","id":"2ed3f743-686b-49e6-983d-a17f3c61c4d0","issue":"1","journal":{"abbrevTitle":"ZGYSJSXB","coverImgSrc":"journal/img/cover/ZGYSJSXB.jpg","id":"88","issnPpub":"1004-0609","publisherId":"ZGYSJSXB","title":"中国有色金属学报"},"keywords":[{"id":"61d58108-9e94-4399-9018-fa7b8b949aad","keyword":"铀尾矿","originalKeyword":"铀尾矿"},{"id":"b90c9bcd-3442-48ea-a673-80e8a5f4fc6b","keyword":"<span style=\"color:red\">浸出</span>","originalKeyword":"浸出"},{"id":"e0246a1b-205d-4cb8-803f-5cb694b1492a","keyword":"<span style=\"color:red\">氧化</span>","originalKeyword":"氧化"},{"id":"5f44861f-2cfd-41cb-9d5c-ec31f87b986c","keyword":"脉石","originalKeyword":"脉石"}],"language":"zh","publisherId":"zgysjsxb201701019","title":"从低品位铀尾矿中<span style=\"color:red\">氧化</span><span style=\"color:red\">浸出</span>铀","volume":"27","year":"2017"},{"abstractinfo":"氨法<span style=\"color:red\">浸出</span>是基于目标金属与氨形成配合离子进入溶液,实现目标金属与部分杂质的分离,因此<span style=\"color:red\">浸出</span>过程具有选择性.对钴、铜与氨的配合机制及亚硫酸钠还原性能的影响因素进行了分析.结果表明:提高cNH3/cMe有利于形成稳定性高的钴、铜氨配合离子；降低cSO42 -/cSO32-,提高体系pH可降低还原剂还原电位.实验过程采用加压氨浸工艺,在NH3-NH4+ -H2O体系中<span style=\"color:red\">浸出</span>钴铜<span style=\"color:red\">氧化</span>矿中的钴和铜,研究了总氨浓度、氨铵比、液固比、<span style=\"color:red\">浸出</span>温度、还原剂用量对<span style=\"color:red\">氧化</span>矿中钴和铜<span style=\"color:red\">浸出</span>率的影响.结果表明,在总氨浓度7 mol·L-1、氨铵比2∶1、液固比6∶1、<span style=\"color:red\">浸出</span>温度100℃、还原剂亚硫酸钠用量为三价钴含量(摩尔比)4倍的最优条件下,钴<span style=\"color:red\">浸出</span>率可达到95.2％,铜<span style=\"color:red\">浸出</span>率可达到95.8％.<span style=\"color:red\">浸出</span>液后续处理工艺简单,氨及铵盐可实现闭路循环,对环境友好.","authors":[{"authorName":"刘建华","id":"065352ea-8bfa-4646-9210-e96f21564804","originalAuthorName":"刘建华"},{"authorName":"张焕然","id":"426eecec-695c-42d0-b51c-e6134313f608","originalAuthorName":"张焕然"},{"authorName":"王瑞祥","id":"fdd6f782-6472-454e-9bcc-219732a76b76","originalAuthorName":"王瑞祥"},{"authorName":"黄涛","id":"6a96dd07-697a-4a1c-a50b-2c503b5a80bd","originalAuthorName":"黄涛"}],"doi":"10.3969/j.issn.0258-7076.2012.01.026","fpage":"149","id":"a8bc662f-6a0c-41f9-837c-6780eee399b9","issue":"1","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"d7593393-7150-4471-a419-f1078ecbb4cd","keyword":"NH3-NH4+ -H2O体系","originalKeyword":"NH3-NH4+ -H2O体系"},{"id":"454fb7dd-1419-411f-bd64-74ec79c46626","keyword":"钴铜<span style=\"color:red\">氧化</span>矿","originalKeyword":"钴铜氧化矿"},{"id":"7d5a7d74-c876-4490-8ece-0d9e2c520977","keyword":"<span style=\"color:red\">浸出</span>率","originalKeyword":"浸出率"}],"language":"zh","publisherId":"xyjs201201026","title":"氨法加压<span style=\"color:red\">浸出</span>钴铜<span style=\"color:red\">氧化</span>矿工艺","volume":"","year":"2012"}],"totalpage":3176,"totalrecord":31759}