{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"综述了最近几年来在改进<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>二次电池方面进行的研究.主要论述通过加入各种不同的添加剂如HF、CO2、无机离子、碘化物、有机物和表面活性剂来改善<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>的表面和/或表面膜的结构,从而提高<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>二次电池的电化学行为.同时对固态电解质和合金负极今后的研究方向进行了展望.","authors":[{"authorName":"吴宇平","id":"e8d38947-ee6d-429f-9911-c5b26f91ed40","originalAuthorName":"吴宇平"},{"authorName":"万春荣","id":"54c14dfc-12bb-45f6-80f7-91fae7a3c080","originalAuthorName":"万春荣"},{"authorName":"姜长印","id":"1ecbc0e6-8aeb-4574-b34b-e2251fb1f06a","originalAuthorName":"姜长印"},{"authorName":"李建军","id":"a0352ce7-2e4b-4470-af11-e65caba1ceac","originalAuthorName":"李建军"},{"authorName":"李阳兴","id":"98563005-48da-4d39-adb0-82fd5ff8b1cd","originalAuthorName":"李阳兴"}],"doi":"","fpage":"449","id":"1f41ec68-31b2-413f-b442-deb7fc0bca2c","issue":"5","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"540a86f2-cfd1-42ed-bdde-5463175021d2","keyword":"<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>","originalKeyword":"金属锂"},{"id":"c6899e59-6a03-4571-bfcc-b48168d23e1b","keyword":"二次电池","originalKeyword":"二次电池"},{"id":"a324b3d0-535c-4bb3-9987-8ba5a46b5be0","keyword":"添加剂","originalKeyword":"添加剂"},{"id":"357a5f4b-8b6c-4d06-8f6b-87728cdc3d0d","keyword":"改进","originalKeyword":"改进"}],"language":"zh","publisherId":"gncl200005001","title":"<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>二次电池的研究进展","volume":"31","year":"2000"},{"abstractinfo":"953 K下,在LiCl-LiF-Li2CO3纯<span style=\"color:red\">锂</span>盐体系中,采用电化学手段(循环伏安法,计时电流法)研究了熔盐电解碳酸<span style=\"color:red\">锂</span>制备<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>的电极过程,重点分析了<span style=\"color:red\">锂</span>的还原机制和碳酸根离子的放电行为.研究表明,<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>在钨电极上的还原是锂离子一步得电子的可逆反应过程,在氯气析出峰前的氧化峰为碳酸<span style=\"color:red\">锂</span>在电场作用下分解为二氧化碳和氧化锂,氧化锂中的氧离子放电生成氧气所致,电场的作用促进了碳酸<span style=\"color:red\">锂</span>的分解.计时电流表明锂离子的沉积速率受扩散控制,经计算锂离子在熔盐中扩散系数为1.35×10-8 cm2·s-1,成核过程是半球形三维瞬时成核.碳酸<span style=\"color:red\">锂</span>的加入比传统的以LiCl为原料熔盐电解法制备<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>或者合金实际分解电压低0.5V,从而降低了电解过程电压,较少了能源消耗;使用碳酸<span style=\"color:red\">锂</span>作原料熔盐电解法制备<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>不仅减少了环境污染还降低了<span style=\"color:red\">锂</span>的生产成本.","authors":[{"authorName":"张保国","id":"dd0ab41d-4653-4128-ac13-0265ddd3dd6d","originalAuthorName":"张保国"},{"authorName":"李继东","id":"fa09ee3a-7708-4fd1-93e4-088552609111","originalAuthorName":"李继东"},{"authorName":"赫婷婷","id":"921887a3-49f4-44bb-9df1-8e668a43dd6b","originalAuthorName":"赫婷婷"},{"authorName":"王一雍","id":"3dafc875-1623-42f5-8e6e-171802475a19","originalAuthorName":"王一雍"}],"doi":"10.13373/j.cnki.cjrm.2016.05.011","fpage":"473","id":"c81f0627-a2ef-433c-aa72-ea9a5e18dc6b","issue":"5","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"a75a879e-f619-4cd3-b32a-e23f7068cfa7","keyword":"Li2CO3","originalKeyword":"Li2CO3"},{"id":"8f185464-2eea-4941-8bf5-5caf114d1983","keyword":"<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>","originalKeyword":"金属锂"},{"id":"c8815eb7-ba8c-4450-bb3e-395589abbd66","keyword":"还原机制","originalKeyword":"还原机制"},{"id":"57e8b50b-feda-459b-8849-2b718504833c","keyword":"电沉积","originalKeyword":"电沉积"},{"id":"371db60f-a54f-42a3-b01d-2615a332b4ad","keyword":"熔盐电解","originalKeyword":"熔盐电解"}],"language":"zh","publisherId":"xyjs201605011","title":"以Li2CO3为原料制备<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>过程的电化学还原机制","volume":"40","year":"2016"},{"abstractinfo":"着重介绍了高纯<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>工业试验流程、真空蒸馏法提纯<span style=\"color:red\">锂</span>的原理和连续式<span style=\"color:red\">锂</span>真空蒸馏炉的特点,并根据工业试验结果讨论了<span style=\"color:red\">锂</span>的蒸发速度和设备产能、工业试验产品高纯<span style=\"color:red\">锂</span>的质量以及<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>回收率等问题.试验结果表明,设备能耗低, 750℃时蒸馏<span style=\"color:red\">锂</span>纯度99.9%以上,产能达15 t/a.","authors":[{"authorName":"兰海苍","id":"8e2e32c1-1766-4414-8019-df85ee84a681","originalAuthorName":"兰海苍"},{"authorName":"赵炜","id":"eeaa0e8c-7001-4f46-aa43-172db55f4588","originalAuthorName":"赵炜"},{"authorName":"胡初潜","id":"5b352bb8-ff43-4709-ac0b-0e73dbbb640e","originalAuthorName":"胡初潜"},{"authorName":"贾玉兰","id":"9a96cad3-d51f-4cd4-92d2-d6b66fbdf514","originalAuthorName":"贾玉兰"},{"authorName":"胡洪波","id":"c64989a8-593a-41f5-9f37-f4dd3633a0f8","originalAuthorName":"胡洪波"}],"doi":"10.3969/j.issn.0258-7076.1998.04.011","fpage":"286","id":"91eeffd2-a30c-476a-b965-cc91f533eaf0","issue":"4","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"a13fc17e-e46f-44be-a9fe-72944f3c32db","keyword":"蒸馏","originalKeyword":"蒸馏"},{"id":"63f1cc09-8e20-43a0-93ae-efa5cc5571bb","keyword":"高纯<span style=\"color:red\">锂</span>","originalKeyword":"高纯锂"},{"id":"9ff884ff-1d9b-4af9-9c00-5833b20e40ea","keyword":"工业试验","originalKeyword":"工业试验"}],"language":"zh","publisherId":"xyjs199804011","title":"真空蒸馏法制取高纯<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>工业试验","volume":"22","year":"1998"},{"abstractinfo":"在分析工艺原理的基础上, 直接利用青海察尔汗别勒滩地区盐湖晶间卤水提取制备的粗品碳酸<span style=\"color:red\">锂</span>为原料, 选用复合助剂, 采用真空热还原-蒸馏技术, 以CaO和Al2O3的混合物为助剂, 在1000 ℃, 0.13～1.33 Pa真空下反应5h, 制备了纯度≥99.95%的高纯<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>, 其纯度可满足一般锂电池和<span style=\"color:red\">锂</span>合金对<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>的纯度要求, 而且生产过程能耗低、无污染、产品纯度高、收率高、工艺流程短、设备简单, 具有明显的成本竞争优势.","authors":[{"authorName":"周园","id":"0804cd7f-fc30-410d-a4f3-e2a7f714162c","originalAuthorName":"周园"},{"authorName":"韩金铎","id":"4a9c35fa-03d5-4a3c-96b4-38fd1c8e9f07","originalAuthorName":"韩金铎"},{"authorName":"贾永忠","id":"a9dbb3b6-6d0e-44dd-81af-3593f48214b9","originalAuthorName":"贾永忠"},{"authorName":"马培华","id":"a53afdf8-fb0d-49d5-8d9a-2ee5992cc459","originalAuthorName":"马培华"},{"authorName":"景燕","id":"28c00186-e176-481d-99cc-e648fc90bb1a","originalAuthorName":"景燕"}],"doi":"10.3969/j.issn.0258-7076.2004.02.013","fpage":"343","id":"bcaf5ff9-1c6d-49e8-ad6a-036d01f9c1a1","issue":"2","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"5e4dd734-a121-4bdc-ba9f-ef142460d553","keyword":"真空冶金","originalKeyword":"真空冶金"},{"id":"696690bc-923e-42f0-8739-ef0bb35dfca1","keyword":"高纯<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>","originalKeyword":"高纯金属锂"},{"id":"497ad5f7-ff4a-4280-b782-991d49d448cf","keyword":"热还原-真空蒸馏法","originalKeyword":"热还原-真空蒸馏法"},{"id":"ef546f4c-8c63-4725-a49b-075a27b86f12","keyword":"碳酸<span style=\"color:red\">锂</span>","originalKeyword":"碳酸锂"},{"id":"020c2a72-ec45-4a6c-924a-5a39b4d5ad69","keyword":"盐湖","originalKeyword":"盐湖"}],"language":"zh","publisherId":"xyjs200402013","title":"青海盐湖初级碳酸<span style=\"color:red\">锂</span>产品制备高纯<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>研究","volume":"28","year":"2004"},{"abstractinfo":"采用等离子体接枝的方法在聚丙烯(PP)隔膜表面接枝<span style=\"color:red\">锂</span>磺酸根(SO3Li)基团以及甲基丙烯酸甲酯(MMA)基团.将隔膜与<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>组装成对称电池采用恒流长时间放电、恒流充放电循环以及交流阻抗方法研究接枝的表面官能团对<span style=\"color:red\">金属</span>锂电极上<span style=\"color:red\">锂</span>沉积/溶解过程的影响.实验结果证实,表面接枝MMA和SO3Li官能团可有效促进<span style=\"color:red\">锂</span>的沉积/溶解动力学,降低界面电阻,抑制<span style=\"color:red\">金属</span><span style=\"color:red\">锂</span>在反复溶解/沉积循环中枝晶的形成.","authors":[{"authorName":"鞠兰","id":"2d90fbfe-32bc-4cdd-90a3-7d4e8075362a","originalAuthorName":"鞠兰"},{"authorName":"李志虎","id":"292ee2bb-693d-4a05-b025-aa61311c9b21","originalAuthorName":"李志虎"},{"authorName":"鞠华","id":"618a1552-1218-4fb4-8678-5803a6cfce6d","originalAuthorName":"鞠华"},{"authorName":"徐艳辉","id":"bb3c06ea-6dbe-40c6-859c-f43ca4bcb143","originalAuthorName":"徐艳辉"}],"doi":"","fpage":"1640","id":"9fd938b6-a227-4af6-9915-efe0062adc64","issue":"12","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"5d97041d-4fa0-4553-953f-64c06c8223e6","keyword":"<span style=\"color:red\">锂</span><span style=\"color:red\">金属</span>电极","originalKeyword":"锂金属电极"},{"id":"22b2520f-c99c-4d91-b653-983f282af074","keyword":"枝晶","originalKeyword":"枝晶"},{"id":"f060f994-acda-4b96-829f-d0646b2df931","keyword":"等离子体","originalKeyword":"等离子体"},{"id":"e58c61b9-bb80-4b6f-992e-82dc1f8f96bf","keyword":"接枝","originalKeyword":"接枝"}],"language":"zh","publisherId":"gncl201212032","title":"隔膜表面改性法改进<span style=\"color:red\">锂</span><span style=\"color:red\">金属</span>电极循环性能","volume":"43","year":"2012"},{"abstractinfo":"以1 ～3μm<span style=\"color:red\">金属</span>铁粉和磷酸二氢<span style=\"color:red\">锂</span>为原料,采用高温固相法合成了无碳磷酸铁<span style=\"color:red\">锂</span>.通过X射线衍射(XRD),扫描电镜(SEM)和电化学测试等方法对合成的磷酸铁<span style=\"color:red\">锂</span>材料的结构、形貌和电化学性能进行了表征.研究结果表明,采用1 ～3 μm的<span style=\"color:red\">金属</span>铁粉和磷酸二氢<span style=\"color:red\">锂</span>为原料,高温固相法合成了具有橄榄石晶体结构的磷酸铁<span style=\"color:red\">锂</span>材料,粉末近似球形,振实密度较高,一次颗粒200 ～ 300 nm.600℃合成的磷酸铁<span style=\"color:red\">锂</span>存在杂质相,650～750℃下合成的磷酸铁<span style=\"color:red\">锂</span>具有完整的橄榄石晶体结构,产物为纯相.无碳的磷酸铁<span style=\"color:red\">锂</span>呈浅灰色,600～ 750℃下合成的磷酸铁<span style=\"color:red\">锂</span>材料0.1C充放电存在平台,显示两相充放电特性,比容量均在100 mAh·g-1左右,且极化较大.用蔗糖对其进行包覆改性得到碳包磷酸铁<span style=\"color:red\">锂</span>,其颜色呈黑色,改性后的磷酸铁锂电化学性能有了较大的提高,0.1C比容量达到了154 mAh·g-,充电平台和放电平台之间的极化明显降低,具有较好的循环稳定性.","authors":[{"authorName":"阚素荣","id":"34b5df53-f05f-482f-a366-518adbfbc0c6","originalAuthorName":"阚素荣"},{"authorName":"卢世刚","id":"e31923e4-6975-4bc6-9c84-c6f3f9f59085","originalAuthorName":"卢世刚"},{"authorName":"金维华","id":"98de2a99-b281-43a5-9f81-c10fced43916","originalAuthorName":"金维华"}],"doi":"10.13373/j.cnki.cjrm.2014.03.015","fpage":"441","id":"dd35b5d6-c32d-4435-ae2a-4ba491ae34cc","issue":"3","journal":{"abbrevTitle":"XYJS","coverImgSrc":"journal/img/cover/XYJS.jpg","id":"67","issnPpub":"0258-7076","publisherId":"XYJS","title":"稀有金属"},"keywords":[{"id":"0f00691b-1995-4d31-af47-7dc5af8e84f9","keyword":"<span style=\"color:red\">金属</span>铁粉","originalKeyword":"金属铁粉"},{"id":"05d11435-e3c9-4096-8b90-e8584b80149d","keyword":"磷酸铁<span style=\"color:red\">锂</span>","originalKeyword":"磷酸铁锂"},{"id":"d744531a-cea7-45ce-9a48-891f0d0b3e12","keyword":"固相法","originalKeyword":"固相法"},{"id":"8e90e3e5-8685-41fb-8319-72dd43f1cf7b","keyword":"包覆","originalKeyword":"包覆"},{"id":"fdb87582-f085-44b2-9f33-3dc2802aff28","keyword":"性能","originalKeyword":"性能"}],"language":"zh","publisherId":"xyjs201403015","title":"以<span style=\"color:red\">金属</span>铁粉为原料磷酸铁<span style=\"color:red\">锂</span>的制备和性能研究","volume":"38","year":"2014"},{"abstractinfo":"采用高能球磨法制备了锂离子电池负极材料<span style=\"color:red\">锂</span><span style=\"color:red\">金属</span>氮化物Li<SUB>3-<EM>x</EM></SUB><EM>M</EM><SUB><EM>x</EM></SUB>N(<EM>M</EM>=Co,Cu等)。制备的<span style=\"color:red\">锂</span><span style=\"color:red\">金属</span>氮化物具有较高的电化学活性和充放电可逆性,可以用作锂离子电池的高容量负极材料。所制备的Li<SUB>2.6</SUB>Co<SUB>0.4</SUB>N前10次循环的脱嵌<span style=\"color:red\">锂</span>容量高达880mAh·g<SUP>-1</SUP>。Li<SUB>2.6</SUB>Co<SUB>0.2</SUB>Cu<SUB>0.2</SUB>N最初几个循环的脱嵌<span style=\"color:red\">锂</span>容量为750mAh·g<SUP>-1</SUP>,45次充放电循环后的容量保持率为80％。Li<SUB>2.6</SUB>Co<SUB>0.2</SUB>Fe<SUB>0.2</SUB>N是含有Li<SUB>2.6</SUB>Co<SUB>0.4</SUB>N的两相或多相混合物,40次充放电循环后脱<span style=\"color:red\">锂</span>容量为560mAh·g<SUP>-1</SUP>,相对第二次脱<span style=\"color:red\">锂</span>容量的保持率为82％。","authors":[{"authorName":"王可","id":"a8670a74-ea6a-49e3-b862-34ea49eb2078","originalAuthorName":"王可"},{"authorName":"杨军","id":"3b9e0130-8206-4b09-9911-36c3cdbab88b","originalAuthorName":"杨军"},{"authorName":"解晶莹","id":"6e7d4b28-f70e-4f8a-bff7-b779a16f6dce","originalAuthorName":"解晶莹"},{"authorName":"刘宇","id":"e150e806-f1f5-4fd6-aced-52c49dc28544","originalAuthorName":"刘宇"},{"authorName":"王保峰","id":"34e6d912-4c74-456f-aebc-38d51b2c3b5d","originalAuthorName":"王保峰"}],"categoryName":"|","doi":"","fpage":"843","id":"c299140d-cc43-400c-b034-bb45d352afc3","issue":"4","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"91c2c3fc-105c-4d46-97f2-241e8adb56ca","keyword":"球磨","originalKeyword":"球磨"},{"id":"7938e3c4-522b-42e8-8f23-9834d3eba1ef","keyword":" lithium metal nitride","originalKeyword":" lithium metal nitride"},{"id":"14508e5d-b65c-4d9c-acab-307363551b51","keyword":" anode material","originalKeyword":" anode material"},{"id":"2deef787-7607-4e8c-85c3-3e143884762b","keyword":" lithium-ion batteries","originalKeyword":" lithium-ion batteries"}],"language":"zh","publisherId":"1000-324X_2003_4_25","title":"球磨法制备<span style=\"color:red\">锂</span><span style=\"color:red\">金属</span>氮化物及电化学性能研究","volume":"18","year":"2003"},{"abstractinfo":"采用高能球磨法制备了锂离子电池负极材料<span style=\"color:red\">锂</span><span style=\"color:red\">金属</span>氮化物Li3-xMxN(M＝Co,Cu等).制备的<span style=\"color:red\">锂</span><span style=\"color:red\">金属</span>氮化物具有较高的电化学活性和充放电可逆性,可以用作锂离子电池的高容量负极材料.所制备的Li2.6Co0.4N前10次循环的脱嵌<span style=\"color:red\">锂</span>容量高达880mAh.g-1.Li2.6Co0.2Cu0.2N最初几个循环的脱嵌<span style=\"color:red\">锂</span>容量为750mAh@g-1,45次充放电循环后的容量保持率为80%.Li2.6Co0.2Fe0.2N是含有Li2.6Co0.4N的两相或多相混合物,40次充放电循环后脱<span style=\"color:red\">锂</span>容量为560mAh@g-1,相对第二次脱<span style=\"color:red\">锂</span>容量的保持率为82%.","authors":[{"authorName":"王可","id":"698d2cdf-8dbb-4d44-a9a4-7865a4e003a5","originalAuthorName":"王可"},{"authorName":"杨军","id":"28a79ec9-2611-4b91-929b-5cd81d1822a7","originalAuthorName":"杨军"},{"authorName":"解晶莹","id":"2962c6fa-5b6e-40dc-bde4-6d38dbe448fa","originalAuthorName":"解晶莹"},{"authorName":"刘宇","id":"1ce77ae2-f685-4044-a8fa-bdf4f82239d3","originalAuthorName":"刘宇"},{"authorName":"王保峰","id":"3ed40500-6d44-4b51-8c5f-a9c2fb82afc0","originalAuthorName":"王保峰"}],"doi":"10.3321/j.issn:1000-324X.2003.04.022","fpage":"843","id":"64b5f295-e772-424e-9dfb-6d113fcb6668","issue":"4","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"e8bd5e16-209c-46d9-848f-72f58b1d8c7f","keyword":"球磨","originalKeyword":"球磨"},{"id":"348ce448-30df-4ec8-bdfd-41f61ef7dcd6","keyword":"<span style=\"color:red\">锂</span><span style=\"color:red\">金属</span>氮化物","originalKeyword":"锂金属氮化物"},{"id":"6908e7b7-dcf8-4fa8-9c4f-826feacc00af","keyword":"负极材料","originalKeyword":"负极材料"},{"id":"2b1f031a-701e-4b26-8924-f4331cadd9d7","keyword":"锂离子电池","originalKeyword":"锂离子电池"}],"language":"zh","publisherId":"wjclxb200304022","title":"球磨法制备<span style=\"color:red\">锂</span><span style=\"color:red\">金属</span>氮化物及电化学性能研究","volume":"18","year":"2003"},{"abstractinfo":"探索了用机械合金化制备得到的<span style=\"color:red\">金属</span>锑与石墨复合材料(Sbx-C1-x,x=0.1～0.4)作为锂离子电池负极材料的电化学吸放<span style=\"color:red\">锂</span>特性,发现球磨得到的Sbx-C1-x是由微米级Sb颗粒和C所组成的复合物.Sb0.2-C0.8的吸放<span style=\"color:red\">锂</span>过程实际上是由石墨和<span style=\"color:red\">金属</span>锑的吸放<span style=\"color:red\">锂</span>反应组成,首次吸<span style=\"color:red\">锂</span>容量达705 mAh/g,首次不可逆容量约130 mAh/g.对Sb含量与Sbx-C1-x(x=0.1～0.4)电化学吸放<span style=\"color:red\">锂</span>性能的关系表明Sb02-C0.8具有最高的首次充放电容量,而碳含量对循环稳定性有较大的影响.","authors":[{"authorName":"曹高劭","id":"f0053c4a-9a85-4479-a7c0-9bed4f976234","originalAuthorName":"曹高劭"},{"authorName":"赵新兵","id":"beefab95-9c0b-4569-94ec-1d0bff1f112b","originalAuthorName":"赵新兵"}],"doi":"","fpage":"915","id":"216793b6-6c07-4816-bd14-276c302b9a97","issue":"11","journal":{"abbrevTitle":"XYJSCLYGC","coverImgSrc":"journal/img/cover/XYJSCLYGC.jpg","id":"69","issnPpub":"1002-185X","publisherId":"XYJSCLYGC","title":"稀有金属材料与工程"},"keywords":[{"id":"73c2dec3-6eda-4e19-9ce2-5c0e6fad16e3","keyword":"锂离子电池","originalKeyword":"锂离子电池"},{"id":"0fecc169-2e7d-43cd-af01-a0abb7fa5312","keyword":"负极材料","originalKeyword":"负极材料"},{"id":"72667813-e0bd-4cb0-9ed2-d8dfcba2f376","keyword":"锑","originalKeyword":"锑"},{"id":"5f4be624-83e4-4510-99f8-efc5972bcb92","keyword":"石墨","originalKeyword":"石墨"},{"id":"e3db4805-f974-4c37-8a47-e155bddb85f8","keyword":"复合材料","originalKeyword":"复合材料"}],"language":"zh","publisherId":"xyjsclygc200311011","title":"<span style=\"color:red\">金属</span>Sb与石墨复合材料的电化学吸放<span style=\"color:red\">锂</span>性质","volume":"32","year":"2003"},{"abstractinfo":"研究化学镀Ni、Cu和混合掺杂Zn处理后天然鳞片石墨的电化学嵌/脱<span style=\"color:red\">锂</span>性能.结果表明:<span style=\"color:red\">金属</span>微粒Ni、Cu与Zn的掺入可有效改善天然鳞片石墨的循环性能与大倍率充放电特性,<span style=\"color:red\">金属</span>微粒有效降低石墨电极内阻、保证石墨颗粒之间紧密的电接触是掺入<span style=\"color:red\">金属</span>微粒后石墨大倍率充放电性能得到改善的重要原因之一.Ni与Cu微粒改善石墨循环性能的机理与Zn的不同,Cu、Ni通过阻止溶剂化锂离子嵌入维持石墨结构稳定性,来达到提高材料循环性能的目的；<span style=\"color:red\">金属</span>Zn改善石墨循环性能的原因则可能是嵌<span style=\"color:red\">锂</span>过程中,Zn<span style=\"color:red\">锂</span>化所形成Li-Zn合金维持材料表面所形成SEI膜的稳定性.","authors":[{"authorName":"杨娟","id":"6726bff6-1b1e-4946-8509-3c4caf8cb16d","originalAuthorName":"杨娟"},{"authorName":"赖延清","id":"a90511e3-f390-4bb9-9f75-bf3f794584b0","originalAuthorName":"赖延清"},{"authorName":"李劼","id":"03f52275-cbb5-48f2-b27b-e67b0ce960ad","originalAuthorName":"李劼"},{"authorName":"邹幽兰","id":"af1ad2b5-5b9d-4a44-bec0-c1b33f62f35e","originalAuthorName":"邹幽兰"},{"authorName":"唐晶晶","id":"aeb8dd53-2695-4356-a7f9-f363aca561d6","originalAuthorName":"唐晶晶"},{"authorName":"周向阳","id":"c3e65d45-8a84-4607-87ec-abddf89af4b5","originalAuthorName":"周向阳"}],"doi":"","fpage":"1667","id":"fecd9389-abc7-4710-876d-20cdb255f234","issue":"6","journal":{"abbrevTitle":"ZGYSJSXB","coverImgSrc":"journal/img/cover/ZGYSJSXB.jpg","id":"88","issnPpub":"1004-0609","publisherId":"ZGYSJSXB","title":"中国有色金属学报"},"keywords":[{"id":"aea3a102-9b2d-4329-8add-8d2beef48a4d","keyword":"天然鳞片石墨","originalKeyword":"天然鳞片石墨"},{"id":"16b2c7b1-5571-43b4-af28-42914ffa611f","keyword":"<span style=\"color:red\">金属</span>微粒掺杂","originalKeyword":"金属微粒掺杂"},{"id":"a5e6e17c-d145-4a6b-89c6-ba064168258c","keyword":"锂离子二次电池","originalKeyword":"锂离子二次电池"},{"id":"64fd79c0-81f2-42c9-97eb-121e74b9fcd7","keyword":"嵌/脱<span style=\"color:red\">锂</span>性能","originalKeyword":"嵌/脱锂性能"}],"language":"zh","publisherId":"zgysjsxb201206017","title":"掺杂<span style=\"color:red\">金属</span>对天然鳞片石墨电化学嵌/脱<span style=\"color:red\">锂</span>性能的影响","volume":"22","year":"2012"}],"totalpage":2224,"totalrecord":22235}