{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以丙烯酸甲酯和二亚乙基三胺为原料,通过缩聚反应制备了一种水溶性端氨基超支化聚合物(HBP-NH2);并以2,3-环氧丙基三甲基氯化铵(EPTAC)为改性剂,在水溶液中继续与船HBP-NH2反应,制备了端氨基超支化聚合物季铵盐(HBP-HTC).分别采用红外光谱(FT-IR)、核磁共振(1H-NMR)和凝胶色谱(GPC)分析表征了产物的结构及分子量,同时研究了HBP-NH2和HBP-HTC的溶解性能、抗菌性能、紫外吸收性能及热性能等,为其在纺织加工中的应用提供依据.结果表明,HBP-NH2和HBP-HTC具有良好的抗菌性能和紫外吸收性能,同时在H2O,二甲基亚砜(DMSO),C2H5OH和CH3OH等极性溶剂中具有优异的溶解性能.","authors":[{"authorName":"张峰","id":"3f6a34b3-73cc-4b1b-9cb7-2de5ae168fc4","originalAuthorName":"张峰"},{"authorName":"陈宇岳","id":"4a56b2ed-a89f-4d5e-8144-bec34f81c812","originalAuthorName":"陈宇岳"},{"authorName":"张德锁","id":"8e2bda82-9386-4c20-9424-92c52a6a33e8","originalAuthorName":"张德锁"},{"authorName":"华琰蓉","id":"fb6e018f-b690-4e20-89ad-60522d6f69b1","originalAuthorName":"华琰蓉"},{"authorName":"赵兵","id":"0fa16e47-4ffa-4ddc-a1da-6b334e9158be","originalAuthorName":"赵兵"}],"doi":"","fpage":"141","id":"20c534a4-92c6-44b4-9af4-42c205dcda39","issue":"8","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"7fca4b90-caf3-4dff-b4b0-b537f2b9f936","keyword":"端氨基超支化聚合物","originalKeyword":"端氨基超支化聚合物"},{"id":"7db70196-5694-460b-83e8-0fd4f5c2cff9","keyword":"季铵盐","originalKeyword":"季铵盐"},{"id":"10f40f21-8cc8-4895-bc69-8b1035657232","keyword":"合成","originalKeyword":"合成"},{"id":"5f796338-5a35-4428-b6de-6afa734a64c2","keyword":"表征","originalKeyword":"表征"}],"language":"zh","publisherId":"gfzclkxygc200908039","title":"端氨基超支化聚合物及其季铵盐的制备与性能","volume":"25","year":"2009"},{"abstractinfo":"根据《吴仲华奖励基金章程》(吴奖[2008]01号),经各高等院校、中国工程热物理学会和中国科学院工程热物理研究所认真评选和推荐,吴仲华奖励基金理事会评审并确定授予青年学者戴巍、罗坤、唐桂华“吴仲华优秀青年学者奖”,授予程雪涛等10位同学“吴仲华优秀学生奖”。","authors":[],"doi":"","fpage":"0003","id":"6f0ba2a8-05d9-4d8a-8139-230c2fa7e582","issue":"2","journal":{"abbrevTitle":"GCRWLXB","coverImgSrc":"journal/img/cover/GCRWLXB.jpg","id":"32","issnPpub":"0253-231X","publisherId":"GCRWLXB","title":"工程热物理学报 "},"keywords":[{"id":"1d50df37-d3bd-4afd-b0bc-96fcef367f18","keyword":"基金","originalKeyword":"基金"},{"id":"96f9e366-8b92-4e45-a8dd-4cf57f7c7890","keyword":"奖励","originalKeyword":"奖励"},{"id":"ddda9152-b951-4a3a-a74b-df9c31c71fdd","keyword":"评选","originalKeyword":"评选"},{"id":"b457f4f4-07c3-4491-8696-b0fe00c86d52","keyword":"获奖者","originalKeyword":"获奖者"},{"id":"ba4efb8c-78da-4883-9ae3-5a4a6746f396","keyword":"中国科学院","originalKeyword":"中国科学院"},{"id":"5d901c8f-96a3-4df7-bc14-2bcd72c081a4","keyword":"青年学者","originalKeyword":"青年学者"},{"id":"8a8e4fab-befc-419f-acb8-1abf6556d4ea","keyword":"物理研究所","originalKeyword":"物理研究所"},{"id":"d399f276-b272-4e7a-b3e7-28290b5ba79d","keyword":"高等院校","originalKeyword":"高等院校"}],"language":"zh","publisherId":"gcrwlxb201202047","title":"第四届“吴仲华奖励基金”评选出获奖者","volume":"33","year":"2012"},{"abstractinfo":"根据《吴仲华奖励基金章程》(吴奖[2010]01号),经各高校、中国工程热物理学会和中国科学院工程热物理研究所遴选和推荐,以及吴仲华奖励基金理事会评审,决定授子钟文琪、张鹏、张明明、徐纲4位青年学者“吴仲华优秀青年学者奖”,授予顾超等13位同学“吴仲华优秀学生奖”。","authors":[],"doi":"","fpage":"0003","id":"d70b96d7-3c44-4fde-a109-b1112f1278e4","issue":"11","journal":{"abbrevTitle":"GCRWLXB","coverImgSrc":"journal/img/cover/GCRWLXB.jpg","id":"32","issnPpub":"0253-231X","publisherId":"GCRWLXB","title":"工程热物理学报 "},"keywords":[{"id":"5a64f2f4-38be-401a-a83f-adef9ef224ed","keyword":"基金","originalKeyword":"基金"},{"id":"f05f7ec3-a6e8-4e71-ac22-e8a10fe82e5e","keyword":"奖励","originalKeyword":"奖励"},{"id":"c026f7a6-59c8-49e9-b2f1-5ceb65037ec2","keyword":"获奖者","originalKeyword":"获奖者"},{"id":"d8a77205-3a8b-4c09-a791-931274af58b5","keyword":"中国科学院","originalKeyword":"中国科学院"},{"id":"5f463d1c-52c8-4e1a-8c66-8da518a48b2c","keyword":"评选","originalKeyword":"评选"},{"id":"f5330498-d48a-472b-97ce-585f7fa55608","keyword":"青年学者","originalKeyword":"青年学者"},{"id":"7ff61d48-2aef-42b7-a260-329b6a7e98db","keyword":"物理研究所","originalKeyword":"物理研究所"},{"id":"031540a3-091d-4fd9-b967-5cfa8b33e754","keyword":"物理学会","originalKeyword":"物理学会"}],"language":"zh","publisherId":"gcrwlxb201211045","title":"第五届“吴仲华奖励基金”评选出获奖者","volume":"33","year":"2012"},{"abstractinfo":"2012年2月22日是两院院士邵象华先生百岁华诞的大喜日子,2月21日上午,中国钢研科技集团有限公司为邵象华院士百岁华诞举办了隆重的座谈会。","authors":[],"doi":"","fpage":"16","id":"b91bfe95-42b7-41e4-8ed9-e5773f29f027","issue":"3","journal":{"abbrevTitle":"GTYJXB","coverImgSrc":"journal/img/cover/GTYJXB.jpg","id":"30","issnPpub":"1001-0963","publisherId":"GTYJXB","title":"钢铁研究学报"},"keywords":[{"id":"d2105c24-f208-4b24-8b19-bf467d2b0a85","keyword":""庆祝邵象华院士百岁华诞座谈会"","originalKeyword":""庆祝邵象华院士百岁华诞座谈会""},{"id":"df4761b4-1374-4fcd-8cf4-327714600128","keyword":"钢铁工业","originalKeyword":"钢铁工业"},{"id":"8a2fcb21-b70e-4106-96cc-c707c039244c","keyword":"科技工作者","originalKeyword":"科技工作者"},{"id":"f5805ea9-8437-439d-84c2-6d0f81500ac2","keyword":"学术作风","originalKeyword":"学术作风"}],"language":"zh","publisherId":"gtyjxb201203004","title":"“庆祝邵象华院士百岁华诞座谈会”隆重召开","volume":"24","year":"2012"},{"abstractinfo":"2012年2月22日是两院院士邵象华先生百岁华诞的大喜日子,2月21日上午,中国钢研科技集团有限公司为邵象华院士百岁华诞举办了隆重的座谈会。座谈会会场一幅以长城和中国钢铁工业为背景的巨型彩色喷绘画卷蕴喻了邵象华院士的成长经历和学术贡献。座谈会高朋满座,群贤毕集。中国材料界学术泰斗,国家最高科学技术奖获得者师昌绪院士、中国工程院名誉院长徐匡迪院士、中国科学院副院长李静海院士、","authors":[],"doi":"","fpage":"75","id":"90f1fcfb-cc62-4b18-b287-ba2d3d459b74","issue":"3","journal":{"abbrevTitle":"GT","coverImgSrc":"journal/img/cover/GT.jpg","id":"27","issnPpub":"0449-749X","publisherId":"GT","title":"钢铁"},"keywords":[{"id":"e830a8e9-3b92-458b-8ecc-4192704ffee5","keyword":"师昌绪院士","originalKeyword":"师昌绪院士"},{"id":"cf99cc15-ae16-4654-a7c2-007b2e85fa03","keyword":"国家最高科学技术奖","originalKeyword":"国家最高科学技术奖"},{"id":"820407b1-47c6-4c07-b8b3-ebce8bc4934f","keyword":"中国工程院","originalKeyword":"中国工程院"},{"id":"17200f26-910f-4bce-af83-beea7ccf79a0","keyword":"学术贡献","originalKeyword":"学术贡献"},{"id":"6982139f-7d3d-4126-b3af-06e5e7ef8525","keyword":"钢铁工业","originalKeyword":"钢铁工业"},{"id":"7416ace7-3590-450e-95df-94de60ab2d99","keyword":"中国科学院","originalKeyword":"中国科学院"},{"id":"c3552b08-e8da-4b85-965f-db3b43777054","keyword":"成长经历","originalKeyword":"成长经历"},{"id":"8c26f9db-5cc3-445f-8333-6f6089c2b1ca","keyword":"副院长","originalKeyword":"副院长"}],"language":"zh","publisherId":"gt201203017","title":"“庆祝邵象华院士百岁华诞座谈会”隆重召开","volume":"47","year":"2012"},{"abstractinfo":"西安华钊电子油科技有限公司是专业从事电接触表面的三防、润滑、保护材料研制和销售的高新技术企业。同时代销荏原优吉莱特(上海)贸易有限公司的电镀添加剂。","authors":[],"doi":"","fpage":"30","id":"07bec302-c435-4941-9498-55d4562697bd","issue":"8","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"c4639ad7-f463-4d10-b46f-b78330389843","keyword":"保护材料","originalKeyword":"保护材料"},{"id":"bc785b58-5c01-42ea-bd62-228aff8c668e","keyword":"表面润滑","originalKeyword":"表面润滑"},{"id":"30f1966b-c07b-4f18-86c0-ba4b3bb9484e","keyword":"科技","originalKeyword":"科技"},{"id":"59e9de6f-0566-4a29-9905-2bb4030adb41","keyword":"电子","originalKeyword":"电子"},{"id":"c86e97b8-1bcb-4f36-a812-77e943226829","keyword":"西安","originalKeyword":"西安"},{"id":"945205db-6d84-47d6-acd6-7acb02f195ec","keyword":"电接触","originalKeyword":"电接触"},{"id":"d850407f-8992-49a4-b63b-65ff2de10323","keyword":"环保","originalKeyword":"环保"},{"id":"dc7b7205-681f-4c28-8a2b-ece7d8b19d67","keyword":"高新技术企业","originalKeyword":"高新技术企业"}],"language":"zh","publisherId":"clbh201208011","title":"西安华钊电子油科技有限公司——新型环保电接触表面润滑保护材料","volume":"45","year":"2012"},{"abstractinfo":"比较了5种不同商品化脂肪酶和自制的华根霉CCTCC M201021全细胞脂肪酶(RCL)催化油脂合成生物柴油的转化效果,结果表明, RCL能有效应用于无溶剂体系催化合成生物柴油. 在无溶剂体系中对该酶催化生物柴油的转酯化反应工艺进行优化,考察了甲醇用量、体系含水量、酶的添加量和反应温度对生物柴油收率的影响,使生物柴油最终收率大于86.0%. 在有机溶剂体系中选择不同有机溶剂作为助溶剂进行转酯化反应,发现log P值在4.0~4.5的有机溶剂具有较好的转化效果. 其中以正庚烷为助溶剂的转酯化反应具有最高的生物柴油收率86.7%. 在无溶剂体系中RCL催化转化油酸和模拟高酸价油脂合成脂肪酸甲酯的研究表明,该酶具有很好的催化合成生物柴油的潜力.","authors":[{"authorName":"贺芹","id":"aa1dc494-2ae6-4cee-a60c-73b3e7f8bf39","originalAuthorName":"贺芹"},{"authorName":"徐岩","id":"124f3a2f-5486-4cfa-bd8e-440f015d230d","originalAuthorName":"徐岩"},{"authorName":"滕云","id":"46927df5-d869-41fc-a4b3-58afa0bef982","originalAuthorName":"滕云"},{"authorName":"王栋","id":"169b8702-4102-4811-a00f-67ae26ff8a0e","originalAuthorName":"王栋"}],"doi":"","fpage":"41","id":"15f616ac-4c57-47b0-bdbe-0c43f373bb92","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"8ecabbd5-5148-4309-897c-f2728132cb61","keyword":"华根霉","originalKeyword":"华根霉"},{"id":"ce7fb2d1-c66a-407f-b5ce-24ad10187fba","keyword":"全细胞脂肪酶","originalKeyword":"全细胞脂肪酶"},{"id":"8a3e40d7-70e4-465c-98ac-6583cb6365da","keyword":"转酯化反应","originalKeyword":"转酯化反应"},{"id":"2ef6b8d6-7ca8-432e-98f4-a468e459cc32","keyword":"生物柴油","originalKeyword":"生物柴油"},{"id":"6f0665f4-e6be-44a8-9252-f6769f5a385d","keyword":"脂肪酸甲酯","originalKeyword":"脂肪酸甲酯"},{"id":"65a996a2-eccf-48d6-ada1-aa707ba646de","keyword":"无溶剂体系","originalKeyword":"无溶剂体系"},{"id":"a729b645-540c-4cd8-a332-8aaf2f5f37e5","keyword":"高酸价油脂","originalKeyword":"高酸价油脂"}],"language":"zh","publisherId":"cuihuaxb200801010","title":"华根霉全细胞脂肪酶催化合成生物柴油","volume":"29","year":"2008"},{"abstractinfo":"研究了华根霉CCTCC M201021菌丝体结合脂肪酶(RCL)在非水相中催化酯合成动力学拆分外消旋2-辛醇的能力.发现RCL对该反应具有较好的光学选择性(E>100),辛酸和异辛烷分别是最佳的酰基供体和反应溶剂,体系水活度的减少对反应的光学选择性没有明显影响,但能显著提高反应初速度.在相同转化率下,通过添加 3A 分子筛降低体系水含量可使反应初始速度提高7.3倍.当底物浓度提高到0.230 mol/L,反应 40 h 时转化率达44.4%,产物酯的ee值为94.7%.与三种商品化脂肪酶进行了比较,发现在相同条件下RCL对 2-辛醇的拆分不但具有较好的光学选择性(E=103.1),而且也表现出较高的反应初速度和转化率.","authors":[{"authorName":"单天宇","id":"49c970a3-2f43-48af-a957-7df3c906d51e","originalAuthorName":"单天宇"},{"authorName":"王栋","id":"5f29b905-ac1a-40dc-8dda-ee775fd3689d","originalAuthorName":"王栋"},{"authorName":"徐岩","id":"c55b9626-1a4f-46e8-82ee-b7be05f5670d","originalAuthorName":"徐岩"},{"authorName":"何军邀","id":"ed950bbb-6761-48dd-a056-86afff8451e7","originalAuthorName":"何军邀"}],"doi":"","fpage":"403","id":"30aeca97-0af9-4d3b-bade-c9ca586e393e","issue":"4","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"b03cdb56-8e30-4723-9812-a0e864874ea4","keyword":"华根霉","originalKeyword":"华根霉"},{"id":"6103d445-6155-4e68-aae7-ba1977a6f293","keyword":"菌丝体结合脂肪酶","originalKeyword":"菌丝体结合脂肪酶"},{"id":"f01245a5-7bb1-495b-ba2f-c25f1feb0576","keyword":"选择性酯化","originalKeyword":"选择性酯化"},{"id":"f4815c23-3b31-42d8-9c76-c6f6413a6f7b","keyword":"动力学拆分","originalKeyword":"动力学拆分"},{"id":"0f0969fe-5012-45c1-95d8-214936e0e6c0","keyword":"2-辛醇","originalKeyword":"2-辛醇"}],"language":"zh","publisherId":"cuihuaxb200804018","title":"华根霉菌丝体结合脂肪酶催化酯合成动力学拆分2-辛醇","volume":"29","year":"2008"},{"abstractinfo":"沙钢华盛钢铁新建的1080 m3高炉三座热风炉为顶燃式(卡鲁金式),投产使用不到半年,炉底耐热基墩与炉壳之间出现窜气,且窜气面多,压力较高,窜气量大,不仅增加能耗,而且在热风炉的正常使用中造成—定的安全隐患.前期对热风炉炉底进行了多次灌浆、打抱箍、采用树脂材料封堵等修复处理,基本都没有效果.最后经中冶武建院相关专家对窜风原因分析,采取具有针对性的材料和施工工序,对该热风炉进了处理,效果较为显著,热风炉炉底的窜风现象基本得到了修复.","authors":[{"authorName":"赵士明","id":"306cfc6f-6662-4c1f-8f93-dbff4244e076","originalAuthorName":"赵士明"},{"authorName":"熊继全","id":"f6eb7b97-6380-4c05-a232-b164b98b6719","originalAuthorName":"熊继全"}],"doi":"","fpage":"1171","id":"16fda778-acd3-45ee-b18e-870f4611a68a","issue":"4","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 "},"keywords":[{"id":"ab0bf1d4-208f-4eee-b4c4-6adae84cba36","keyword":"高炉热风炉","originalKeyword":"高炉热风炉"},{"id":"0b92ab64-387e-4606-b992-dbdc94ca60c2","keyword":"炉底窜风","originalKeyword":"炉底窜风"},{"id":"30cce9be-2d9a-42f5-91d9-1fb6bc4a591b","keyword":"事故分析","originalKeyword":"事故分析"}],"language":"zh","publisherId":"gsytb201504051","title":"沙钢华盛1080 m3高炉热风炉炉底窜风事故分析及其修复处理","volume":"34","year":"2015"},{"abstractinfo":"","authors":[],"doi":"","fpage":"46","id":"7044d826-cf66-4990-886c-3ed6706c88ec","issue":"4","journal":{"abbrevTitle":"TGYJZ","coverImgSrc":"journal/img/cover/TGYJZ.jpg","id":"60","issnPpub":"1009-9964","publisherId":"TGYJZ","title":"钛工业进展"},"keywords":[{"id":"0904b156-0ef2-45db-b1a8-9624f5650fc9","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"tgyjz200104022","title":"Ludlum和华昌公司欲使钛价上扬","volume":"","year":"2001"}],"totalpage":8,"totalrecord":78}