{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"从炭黑微观结构和形态出发,综述了6种非离子表面活性剂在炭黑水性体系中的吸附性能.聚醚型表面活性剂在炭黑/水界面上的吸附等温曲线都符合Langrnuir型,而癸基甲基亚砜在炭黑/水界面上的吸附等温曲线呈双平台型.展望了制备稳定炭黑水性分散体系的发展方向.","authors":[{"authorName":"袁霞","id":"206852b9-4e7d-4ee2-a3b4-0a0f610ca35f","originalAuthorName":"袁霞"}],"doi":"","fpage":"64","id":"2eedabe1-459d-43a5-a90b-53dfa5beda93","issue":"23","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"9410ef22-bf5a-4a99-80ba-66a8aece1ac9","keyword":"炭黑","originalKeyword":"炭黑"},{"id":"cc298cfa-730a-465d-81ba-9e2c4beb1a15","keyword":"非离子表面活性荆","originalKeyword":"非离子表面活性荆"},{"id":"0d67b4c1-870a-49c0-86bc-9d99f4945755","keyword":"吸附","originalKeyword":"吸附"},{"id":"954a3cf9-6483-4089-808e-c490c2dc53c8","keyword":"水性体系","originalKeyword":"水性体系"}],"language":"zh","publisherId":"cldb201023013","title":"非离子表面活性剂在炭黑水性体系吸附的研究进展","volume":"24","year":"2010"},{"abstractinfo":"比较了乙酐-浓硫酸法和乙酐-吡啶法测定非离子表面活性剂羟值的效果,结果表明:选择合适的测定条件,可以用乙酐-浓硫酸法代替乙酐-吡淀法.","authors":[{"authorName":"宋开平","id":"2e6e1289-dcd2-4e3e-a386-55fce4459050","originalAuthorName":"宋开平"}],"doi":"10.3969/j.issn.1673-2812.2003.06.033","fpage":"901","id":"8eb0062c-091c-44ee-8bd6-f4f3cc224118","issue":"6","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"96ca8acc-700a-4b84-b61b-18d6fa018db8","keyword":"非离子表面活性剂","originalKeyword":"非离子表面活性剂"},{"id":"007bd424-5cf4-4267-b225-45398711dcb1","keyword":"酸值","originalKeyword":"酸值"},{"id":"b901b8db-dc61-49ee-a7d9-1886f9508c0f","keyword":"羟值","originalKeyword":"羟值"}],"language":"zh","publisherId":"clkxygc200306033","title":"非离子表面活性剂羟值的测定方法改进","volume":"21","year":"2003"},{"abstractinfo":"对氯化物镀锌溶液浊点的影响因素:非离子表面活性剂浓度、主盐浓度、辅助光亮剂含量、阴离子型表面活性剂、增溶剂成分及pH值等进行了研究。结果表明,溶液浊点随苄叉丙酮、辅助添加剂(苯甲酸钠、扩散剂等)含量的提高而降低,随溶液主盐的含量提高而下降(与氯化锌含量提高,浊点应提高这一理论相反);含有弱酸类辅助添加剂时,随pH值的降低浊点显著降低;随烷基苯或烷基醇聚乙二醇盐类型阴离子表面活性剂及增溶剂的加入而大幅度提高;随非离子表面活性剂浓度提高而略有提高。","authors":[{"authorName":"谢洪波","id":"c2d19b98-f0c0-4046-a2de-d6e07a176006","originalAuthorName":"谢洪波"},{"authorName":"张来祥","id":"294bb2c0-6633-4c85-9d16-f0bbee5c3234","originalAuthorName":"张来祥"}],"doi":"10.3969/j.issn.1001-1560.2001.03.006","fpage":"14","id":"a9c68dad-1d74-491d-85dd-8802d019e088","issue":"3","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"c84769e7-2a7b-421c-91a7-523c0d421c4a","keyword":"氯化物镀锌","originalKeyword":"氯化物镀锌"},{"id":"32e5abcf-e5b3-4aba-a245-f04843e3607f","keyword":"非离子表面活性剂","originalKeyword":"非离子表面活性剂"},{"id":"a27529a8-3be1-4e29-ac65-c705dd6bc251","keyword":"阴离子表面活性剂","originalKeyword":"阴离子表面活性剂"},{"id":"2cf930f0-8b2f-4bc3-948f-a90a9c6e5332","keyword":"浊点","originalKeyword":"浊点"},{"id":"29aa994d-78c0-4e2e-a0e3-0cd7c9c399c8","keyword":"镀锌光亮剂","originalKeyword":"镀锌光亮剂"},{"id":"bbf59a90-d52c-4cba-b536-5ffbf7995ed7","keyword":"增溶剂","originalKeyword":"增溶剂"},{"id":"eb545f35-969c-4643-bc14-3ecc64b26c1a","keyword":"辅助光亮剂","originalKeyword":"辅助光亮剂"}],"language":"zh","publisherId":"clbh200103006","title":"影响氯化物镀锌溶液非离子表面活性剂浊点的因素","volume":"34","year":"2001"},{"abstractinfo":"要 以烷基胺、1,3-二溴丙烷为主要原料,采用两步法合成了不同碳链长度(n=8、12、16)的N,N’-二烷基(8/12/16)-N,N’-二葡萄糖丙二酰胺非离子双子表面活性剂.通过FTIR与1HNMR对产物的结构进行了表征,用悬滴法对其表面张力进行了测定,用动态光散射对其粒度分布进行了测定,用改进Ross-Miles法对样品的泡沫性能进行了测定.结果表明:合成的葡萄耱酰胺非离子双子表面活性剂(8/12/16)的临界胶束浓度(cmc)及γcmc分别为5.627×10-3 mol/L、4.42×10-4 mol/L、2.96×10-3 mol/L和36.20 mN/m、30.22 mN/m、46.35mN/m;双子表面活性剂溶液粒径分布在130~1050nm;双子表面活性剂泡沫性能良好.","authors":[{"authorName":"杨宗锋","id":"96e2d6f5-6ac5-4248-a8a6-cd052752cafc","originalAuthorName":"杨宗锋"},{"authorName":"闫顺杰","id":"5554ee90-e0ff-4680-8bdc-545b81aa6d27","originalAuthorName":"闫顺杰"},{"authorName":"杜斌斌","id":"9eb9d2ea-920b-4063-8472-4a23da6f1937","originalAuthorName":"杜斌斌"},{"authorName":"辛志荣","id":"f60dc2ae-ae53-4003-86bf-5b3f2d97c6fe","originalAuthorName":"辛志荣"}],"doi":"","fpage":"61","id":"2ae04c49-ef5a-4bb1-8c5f-22d9745f84f5","issue":"18","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"743d0c14-05df-4f8b-b170-a3681132b5e9","keyword":"双子表面活性剂","originalKeyword":"双子表面活性剂"},{"id":"6caaab2c-14a4-4095-b9bd-de0ebe654aac","keyword":"葡萄糖酰胺","originalKeyword":"葡萄糖酰胺"},{"id":"88d51546-a49c-48ef-810a-61697ad72f6a","keyword":"表面活性","originalKeyword":"表面活性"}],"language":"zh","publisherId":"cldb201318016","title":"葡萄糖酰胺非离子双子表面活性剂的制备与表征","volume":"27","year":"2013"},{"abstractinfo":"制备了不同碳链长度的二元环氧化合物,并使其与聚合度为8~9的聚氧乙烯(PEO)或SPAN80反应,合成了含有不同长度间隔链的双亲水基表面活性剂. 用傅立叶红外光谱仪和核磁共振仪对其结构进行了表征. 实验结果表明,具有疏水性间隔链的双亲水基表面活性剂具有良好的表面活性,其表面活性不仅比单亲水基表面活性剂的大,且可随着疏水间隔链长度的增加而增大. ","authors":[{"authorName":"辛志荣","id":"e698f02f-83af-4a47-bc22-7378eb496b97","originalAuthorName":"辛志荣"},{"authorName":"丁永涛","id":"af99f9a9-f182-411b-8c74-ef132f5ac65e","originalAuthorName":"丁永涛"},{"authorName":"柯卓","id":"156e4639-7865-4d90-b48f-e38974482092","originalAuthorName":"柯卓"},{"authorName":"蔡传伦","id":"5466960a-10b8-4684-b546-7eddf4e28f7d","originalAuthorName":"蔡传伦"},{"authorName":"高瑛","id":"04793d17-aa7d-478f-8c5a-50a037d007e8","originalAuthorName":"高瑛"},{"authorName":"殷敬华","id":"dab1598c-827c-495e-9966-b7f7e05b90ae","originalAuthorName":"殷敬华"}],"doi":"10.3969/j.issn.1000-0518.2002.08.003","fpage":"723","id":"1a762d30-a0d8-47b8-8f2c-e9a4d07aaeed","issue":"8","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"9f13ce89-e716-4c9c-9fee-e7cd3be3c62c","keyword":"非离子表面活性剂","originalKeyword":"非离子表面活性剂"},{"id":"1ffc5c0b-bff6-4fd8-9b70-01fe6d6744ad","keyword":"环氧化合物","originalKeyword":"环氧化合物"},{"id":"c2fe652c-5aee-49a9-ae94-1bbed48343ab","keyword":"疏水间隔链","originalKeyword":"疏水间隔链"},{"id":"e911fd4f-9568-40c8-ab7d-b536d222a1ec","keyword":"聚氧乙烯","originalKeyword":"聚氧乙烯"},{"id":"b31012ae-b4fd-4f68-adb1-55165f86b3df","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"yyhx200208003","title":"新型非离子表面活性剂的合成与表征","volume":"19","year":"2002"},{"abstractinfo":"用非离子表面活性剂Triton X-100和NaCl盐溶液在一定温度下形成的浊点体系为萃取介质,重点研究了浊点萃取甘草酸过程中凝聚相及水相的谱学性质和微观结构. 结果表明,随着温度的升高,红外谱图中O-H的振动吸收峰和C-O骨架伸缩振动峰会向高波数移动,而在浊点温度时,波数变化明显. 浊点体系的主体相具有粒度性质特征,吸附溶质后的凝聚相胶团粒径增大. 随着甘草酸浓度的升高,胶团从7.7 nm增大至20 nm以上,有类似聚集的现象.","authors":[{"authorName":"孙晨","id":"bc6ec6ae-8509-46c1-af3c-2ce309cc76cb","originalAuthorName":"孙晨"},{"authorName":"赵培侠","id":"0c63d94f-c70f-4f90-8759-d83be8e83872","originalAuthorName":"赵培侠"}],"doi":"10.3724/SP.J.1095.2010.90882","fpage":"1351","id":"da9d03ac-a94a-4c9c-b92e-9e2d82bdcec8","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"1ea3ba95-f1f1-4157-a44a-59659a8b342a","keyword":"浊点萃取","originalKeyword":"浊点萃取"},{"id":"20a8d443-6486-47a8-9b1b-690e78229ecb","keyword":"Triton X-100","originalKeyword":"Triton X-100"},{"id":"fc0f68dd-f84b-45f0-84d0-e2de0f2e56a9","keyword":"甘草酸","originalKeyword":"甘草酸"},{"id":"8c2f7f28-150b-47a9-b31e-e45b0fe1cd7f","keyword":"红外光谱","originalKeyword":"红外光谱"}],"language":"zh","publisherId":"yyhx201011021","title":"非离子表面活性剂浊点萃取甘草酸体系的特性","volume":"27","year":"2010"},{"abstractinfo":"先通过一系列试验筛选得到用于环保无磷除油粉的表面活性剂组合:脂肪醇聚氧乙烯醚AEO-90.6%(均为质量分数),异构C13聚氧乙烯醚A91.0%,烷基糖苷APG08141.0%,异构C13聚氧乙烯醚TDA-701.4%.随后通过正交试验对除油粉的其他组分进行优化,最终得到用于金属表面清洗的环保无磷除油粉:氢氧化钠30%,碳酸钠20%,五水偏硅酸钠4.0%,助洗剂DG 25%,十二烷基硫酸钠2%,元明粉(硫酸钠)15%,非离子表面活性剂4%.最后对比研究了该配方除油粉、现有含磷除油粉BH-11和无磷除油粉BH-13的除油性能.结果表明,与无磷除油粉BH-13相比,在相同温度下,该配方的除油速率更快,除油效率更高,漂洗性能更好,综合性能可与含磷除油粉BH-11相媲美.","authors":[{"authorName":"何东敏","id":"c8fa6920-b541-4bf4-bba5-2ffc02994985","originalAuthorName":"何东敏"},{"authorName":"张晓明","id":"ff918781-6a28-4b98-a6ac-f6abe207bed2","originalAuthorName":"张晓明"},{"authorName":"何敏思","id":"7d3486b7-a302-43dd-b89f-e06a24ed62f8","originalAuthorName":"何敏思"},{"authorName":"温青","id":"815c388c-cf74-4154-9c4f-86cecaf8ec82","originalAuthorName":"温青"}],"doi":"","fpage":"1015","id":"855daf8b-ca21-4b0b-a335-865e6b9bc34f","issue":"19","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"3fc3a4a1-ee26-49fc-9bee-2819436de421","keyword":"金属","originalKeyword":"金属"},{"id":"78420158-faf9-4256-a033-fd78e791454d","keyword":"清洗","originalKeyword":"清洗"},{"id":"bf5896c6-1165-4d04-a593-17b91b96899b","keyword":"非离子表面活性剂","originalKeyword":"非离子表面活性剂"},{"id":"3e011365-8610-41ac-ae96-a1b99e10e49e","keyword":"无磷除油粉","originalKeyword":"无磷除油粉"},{"id":"2669ea61-c416-4c15-979c-befae72706a4","keyword":"化学耗氧量","originalKeyword":"化学耗氧量"}],"language":"zh","publisherId":"ddyts201619004","title":"环保型非离子表面活性剂组合及其在金属清洗中的应用","volume":"35","year":"2016"},{"abstractinfo":"用失重法和电化学法研究了稀土钇(Ⅲ)离子和非离子表面活性剂聚乙二醇辛基苯基醚(OP)在磷酸介质中对锌腐蚀速度的影响,发现在特定浓度范围内,钇离子和OP对锌有强烈的缓蚀协同作用,用金属表面吸附理论讨论了这种缓蚀协同作用的机理.","authors":[{"authorName":"木冠南","id":"d76a3604-10da-4025-8dad-2fba25483595","originalAuthorName":"木冠南"},{"authorName":"刘光恒","id":"0425c425-ca05-4d42-a5b1-83dcb5f08add","originalAuthorName":"刘光恒"}],"doi":"10.3969/j.issn.1005-748X.2002.02.002","fpage":"51","id":"1d339611-ad51-4f42-8874-99c3fc577d39","issue":"2","journal":{"abbrevTitle":"FSYFH","coverImgSrc":"journal/img/cover/FSYFH.jpg","id":"25","issnPpub":"1005-748X","publisherId":"FSYFH","title":"腐蚀与防护"},"keywords":[{"id":"3921ed6d-1402-490a-9ecc-bec3649717cd","keyword":"表面活性剂","originalKeyword":"表面活性剂"},{"id":"b2baebc7-a1fd-4ccb-a47d-5d074e509387","keyword":"钇(Ⅲ)离子","originalKeyword":"钇(Ⅲ)离子"},{"id":"2dac96fd-8e70-490a-bbd8-dd1f5e16a092","keyword":"锌","originalKeyword":"锌"},{"id":"ef069fd0-9c04-4b85-a58d-e7c459da616a","keyword":"磷酸","originalKeyword":"磷酸"},{"id":"3641f432-5603-4394-bfe2-8f963a36b62e","keyword":"缓蚀协同效应","originalKeyword":"缓蚀协同效应"}],"language":"zh","publisherId":"fsyfh200202002","title":"稀土钇(Ⅲ)离子和非离子表面活性剂对锌的缓蚀协同效应","volume":"23","year":"2002"},{"abstractinfo":"研究了Gemini阴离子表面活性剂的表面活性.结果表明,其表面活性远远高于相应的单基表面活性剂,其临界胶束浓度(CMC)比相应的单基表面活性剂降低了1个数量级,且随着联接基团长度的增加,CMC呈减小的趋势;测定了Gemim阴离子表面活性剂的表面张力,其C20比常用的单基表面活性剂降低了2个数量级,显示出突出的降低水表面张力的效率;油水界面张力的测定结果表明,在Gemini D质量分数为0.1%时,就可以使得油水界面张力达到超低,具有突出的降低油水界面张力的能力.","authors":[{"authorName":"朱森","id":"ccc8b59b-0cfd-41e9-b84a-eb2ca00f0da8","originalAuthorName":"朱森"},{"authorName":"程发","id":"aba9dd69-84c5-4bc0-b340-7e44b7843694","originalAuthorName":"程发"},{"authorName":"郑宝江","id":"02e52c95-8504-4010-901c-17d1444e8ca7","originalAuthorName":"郑宝江"},{"authorName":"于九皋","id":"32ffa083-5e90-4884-8ea8-6d12d98dce98","originalAuthorName":"于九皋"}],"doi":"10.3969/j.issn.1000-0518.2005.07.021","fpage":"792","id":"dbb4ce37-0fb1-4e33-b041-fd16ef63672d","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"30e7643f-c046-43d8-80aa-6760353acddb","keyword":"Gemini阴离子表面活性剂","originalKeyword":"Gemini阴离子表面活性剂"},{"id":"5ac432e5-fc96-4121-bc60-3e89ebe88074","keyword":"表面张力","originalKeyword":"表面张力"},{"id":"a75d1612-c614-4193-9453-f2a17d7efdaf","keyword":"CMC","originalKeyword":"CMC"},{"id":"acf91b8d-69d9-45d7-b7d6-d459ce2588a3","keyword":"C20","originalKeyword":"C20"},{"id":"0e0ff8c0-7bce-491d-aa0b-ffb3b886d9f8","keyword":"界面张力","originalKeyword":"界面张力"}],"language":"zh","publisherId":"yyhx200507021","title":"Gemini阴离子表面活性剂水溶液的界面活性","volume":"22","year":"2005"},{"abstractinfo":"以氢化苯基甲烷二异氰酸酯(H-MDI)、聚氧乙烯十二烷基胺(PAE)、聚乙二醇(PEG)为主要原料,合成了系列侧链含十二烷基、主链嵌入大量聚环氧乙烷(E0)结构的阳-非离子型聚氨酯表面活性剂(PUS).通过红外光谱(FT-IR)、表面张力、临界胶束浓度、乳化力测试等对其进行分析.结果表明:当以PAE为软段单体,以聚乙二醇(PEG-200)为扩链剂时,合成的聚氨酯高分子表面活性剂的综合性能优异,溶液的临界胶束浓度为53.10 mg/L,水溶液的表面张力最低可达38.12 mN/m.","authors":[{"authorName":"孙哲","id":"79935c05-0820-49fc-aaac-c41d1223bec8","originalAuthorName":"孙哲"},{"authorName":"强西怀","id":"a0467546-ca54-4a06-9e28-288c80fce503","originalAuthorName":"强西怀"},{"authorName":"陈渭","id":"ad8a9825-766b-43e8-8cfd-0ec51db31d5d","originalAuthorName":"陈渭"},{"authorName":"陈苗苗","id":"c176dbb2-aa93-4a62-a0d2-e76e91d569ed","originalAuthorName":"陈苗苗"},{"authorName":"黄启恒","id":"62ac03d3-8486-4306-9588-37523dae5b57","originalAuthorName":"黄启恒"}],"doi":"","fpage":"12","id":"dddd3eef-02fd-4399-9c63-35384a60be0e","issue":"10","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"c0b8e7d2-3185-4f38-a8ab-62ab01964518","keyword":"阳-非离子表面活性剂","originalKeyword":"阳-非离子表面活性剂"},{"id":"6bc85cff-ec60-4c4c-a38d-a4409b766e19","keyword":"聚氨酯","originalKeyword":"聚氨酯"},{"id":"f4e129b1-13cf-40b5-8fd0-145ebd2e2fd9","keyword":"聚氧乙烯十二烷基胺","originalKeyword":"聚氧乙烯十二烷基胺"},{"id":"b52e073f-40a4-417b-970d-7142bed86ed0","keyword":"表面张力","originalKeyword":"表面张力"}],"language":"zh","publisherId":"tlgy201510003","title":"新型阳-非离子型聚氨酯高分子表面活性剂的制备和性能研究","volume":"45","year":"2015"}],"totalpage":7294,"totalrecord":72933}