{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"通过三步反应制备出一种端基含SH的叶酸衍生物.首先采用双氧水作为氧化剂制备一种含羟基的<span style=\"color:red\">二</span><span style=\"color:red\">硫</span><span style=\"color:red\">物</span>；然后以<span style=\"color:red\">二</span>甲基亚砜为溶剂、N,N-<span style=\"color:red\">二环己基碳二</span>亚胺为脱水剂、4-<span style=\"color:red\">二</span>甲氨基吡啶为催化剂,使叶酸与<span style=\"color:red\">二</span><span style=\"color:red\">硫</span><span style=\"color:red\">物</span>发生酯化反应；最后以<span style=\"color:red\">二硫</span>苏糖醇作为还原剂断裂S-S键,即得到目标产物.对中间产物以及最终产物分别采用傅里叶变换红外光谱仪、紫外-可见分光光度计和核磁共振仪进行测试表征,验证了该制备过程得到了目标产物.该叶酸衍生物可以直接用于修饰纳米金属粒子,在药物输送以及靶向治疗肿瘤方面具有潜在的应用价值.","authors":[{"authorName":"孙燕","id":"a4700480-f717-40ad-b329-3e2363f2291e","originalAuthorName":"孙燕"},{"authorName":"刘继宪","id":"9b98910f-5d39-46d2-8a5f-79bd62cb7489","originalAuthorName":"刘继宪"},{"authorName":"唐建国","id":"5b6e0d8c-66a0-4899-abef-ceaff456666c","originalAuthorName":"唐建国"},{"authorName":"王瑶","id":"a22be2b8-393a-4cde-8ba8-b2e2578c74f0","originalAuthorName":"王瑶"},{"authorName":"黄震","id":"df06f4be-974f-4f55-aa33-0ab865a147bf","originalAuthorName":"黄震"},{"authorName":"黄林军","id":"36d330de-e22e-4a3b-ab32-b7546e91bdd1","originalAuthorName":"黄林军"},{"authorName":"武鹏","id":"92910fbf-5c58-4fab-a16d-6013056bcb75","originalAuthorName":"武鹏"}],"doi":"","fpage":"74","id":"a8211720-fe52-4281-b0e5-672583c4868d","issue":"16","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"cd0b1ebe-e77a-4a07-9ff6-8c49b1674227","keyword":"叶酸","originalKeyword":"叶酸"},{"id":"1f989b2d-b1d2-4c58-b67d-bb6c2be7831b","keyword":"双氧水","originalKeyword":"双氧水"},{"id":"c9b48b87-c239-49e6-ada6-509bb965e639","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">硫</span><span style=\"color:red\">物</span>","originalKeyword":"二硫物"},{"id":"cce34ecb-cc1d-4a52-a15e-4b2fa6044f52","keyword":"酯化反应","originalKeyword":"酯化反应"},{"id":"b97e4f3f-4a98-46a6-8641-3fa12c1a6fb9","keyword":"<span style=\"color:red\">二硫</span>苏糖醇","originalKeyword":"二硫苏糖醇"}],"language":"zh","publisherId":"cldb201316020","title":"端基含SH的叶酸衍生物的合成与表征","volume":"27","year":"2013"},{"abstractinfo":"氨基<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代甲酸酯类化合<span style=\"color:red\">物</span>由于其独特的分子结构,使其具有明显的抗肿瘤、抗菌、抗氧化以及杀虫等多种生物活性,已经成为近年来药物化学领域研究的重点.本文评述了近年来文献报道的氨基<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代甲酸酯类化合<span style=\"color:red\">物</span>以及它们的主要生物活性,并对其今后的发展方向、应用前景做出展望.","authors":[{"authorName":"王晓娟","id":"adb737f0-50a6-430e-a723-3b5ac2d85452","originalAuthorName":"王晓娟"},{"authorName":"李高伟","id":"c6c20b9a-1eb2-4e8e-9e57-43a434e2a5c4","originalAuthorName":"李高伟"},{"authorName":"孟团结","id":"955c5a62-8340-4c39-9ba3-d0b957544331","originalAuthorName":"孟团结"},{"authorName":"刘澜涛","id":"7e22020f-7416-451e-a399-414c9c7003c8","originalAuthorName":"刘澜涛"},{"authorName":"赵文献","id":"245c135f-7463-40db-a08f-a456a15b5ad4","originalAuthorName":"赵文献"}],"doi":"10.11944/j.issn.1000-0518.2015.02.140187","fpage":"123","id":"0463f8f8-2240-4a50-90a3-ca9c0e82751c","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"eb08f2c2-67d1-4b5a-a0b3-5b12f16ac7dc","keyword":"氨基<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代甲酸酯","originalKeyword":"氨基二硫代甲酸酯"},{"id":"cb44646b-84ff-4b29-8f93-a993325ab1cd","keyword":"生物活性","originalKeyword":"生物活性"}],"language":"zh","publisherId":"yyhx201502001","title":"氨基<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代甲酸酯类化合<span style=\"color:red\">物</span>生物活性研究进展","volume":"32","year":"2015"},{"abstractinfo":"将2-巯基-5-取代基-1,3,4-噻<span style=\"color:red\">二</span>唑经与β-氯苯丙酮取代、盐酸羟胺肟化和氯甲基(口恶)<span style=\"color:red\">二</span>唑醚化,合成了6种3-(5-取代基-1,3,4-噻<span style=\"color:red\">二</span>唑-2-<span style=\"color:red\">硫</span>代基)-1-苯基丙酮-O-(5-苯基-1,3,4-(口恶)<span style=\"color:red\">二</span>唑-2-甲基)肟醚化合<span style=\"color:red\">物</span>(4a～4f),用1 H NMR、IR、MS和元素分析表征了其结构.用MTT法测试了6种目标化合<span style=\"color:red\">物</span>对人黑色素瘤细胞株B16、人白血病细胞株HL60和人肝癌细胞株SMMC-7721的体外细胞毒活性.测试结果表明,部分化合<span style=\"color:red\">物</span>对3种癌细胞具有潜在的体外生长抑制活性.","authors":[{"authorName":"张耀洲","id":"ab4c77b9-4773-4adc-b2cb-e1ad5a8ec6ba","originalAuthorName":"张耀洲"},{"authorName":"肖颖","id":"2ac64980-6e63-42ad-8e30-194291bfccbd","originalAuthorName":"肖颖"},{"authorName":"杨俊杰","id":"1555ecaf-5de8-435b-831c-afebe6f9cef8","originalAuthorName":"杨俊杰"},{"authorName":"胡国强","id":"d4c25027-c87a-4451-a428-33e87130e72a","originalAuthorName":"胡国强"}],"doi":"10.3724/SP.J.1095.2013.20259","fpage":"383","id":"8b57d618-2884-4f84-906c-cc1565aa6363","issue":"4","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"30532710-9893-4fb9-add5-0e19d821a2d8","keyword":"噻<span style=\"color:red\">二</span>唑","originalKeyword":"噻二唑"},{"id":"ba41d2c4-fbb6-4f68-afb0-2170f3bf448d","keyword":"(口恶)<span style=\"color:red\">二</span>唑","originalKeyword":"(口恶)二唑"},{"id":"c6be7536-f0a0-4658-99c7-2aa3bb2e3729","keyword":"肟醚","originalKeyword":"肟醚"},{"id":"00fb2bd3-eba4-46ed-99ff-e1c09b1d1141","keyword":"抗肿瘤活性","originalKeyword":"抗肿瘤活性"}],"language":"zh","publisherId":"yyhx201304004","title":"肟醚噻<span style=\"color:red\">二</span>唑<span style=\"color:red\">硫</span>醚化合<span style=\"color:red\">物</span>的合成及其抗肿瘤活性","volume":"30","year":"2013"},{"abstractinfo":"于空气中一步合成出<span style=\"color:red\">二</span>乙基<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代氨基甲酸稀土(镧、钕、铕和混合稀土)共四种配合<span style=\"color:red\">物</span>,产率达90%以上,本文首次报道了该系列稀土配合<span style=\"color:red\">物</span>促进橡胶硫化性能和应用于胶鞋大底生产的配方试验,结果表明,除混合稀土配合物外,镧、钕、铕配合<span style=\"color:red\">物</span>均具有对橡胶硫化促进作用.选择镧配合<span style=\"color:red\">物</span>在胶鞋大底生产上试用,生产的胶鞋物理机械性能均达国家一级品标准.","authors":[{"authorName":"江涛","id":"33b6ec43-91af-4bb0-a5bd-f5e3aaf5d63e","originalAuthorName":"江涛"},{"authorName":"章伟光","id":"7f65f911-7423-4726-85d3-e881218344b8","originalAuthorName":"章伟光"},{"authorName":"申俊英","id":"bbfa78fb-85f7-4d81-a252-44cfda71533d","originalAuthorName":"申俊英"}],"doi":"10.3969/j.issn.1004-0277.2000.03.011","fpage":"39","id":"93bbc62b-a8e6-4cb9-8bc4-1d36dfe537ab","issue":"3","journal":{"abbrevTitle":"XT","coverImgSrc":"journal/img/cover/XT.jpg","id":"65","issnPpub":"1004-0277","publisherId":"XT","title":"稀土"},"keywords":[{"id":"6b351299-17a8-41c8-9566-d5c22bdd1ab4","keyword":"<span style=\"color:red\">二</span>乙基<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代氨基甲酸","originalKeyword":"二乙基二硫代氨基甲酸"},{"id":"5a17612a-2a1a-4971-87bb-f69e49c224f9","keyword":"稀土配合<span style=\"color:red\">物</span>","originalKeyword":"稀土配合物"},{"id":"0c2f59ff-6d35-468c-a0a4-a7e48d80e557","keyword":"橡胶","originalKeyword":"橡胶"},{"id":"2ef73c29-c35b-42c6-8ee7-1f72fa66393b","keyword":"硫化促进剂","originalKeyword":"硫化促进剂"}],"language":"zh","publisherId":"xitu200003011","title":"<span style=\"color:red\">二</span>乙基<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代氨基甲酸稀土配合<span style=\"color:red\">物</span>的合成及促进橡胶硫化性能研究","volume":"21","year":"2000"},{"abstractinfo":"由<span style=\"color:red\">二</span>硫化碳、<span style=\"color:red\">二</span>甲基甲酰胺(DMF)、金属钠、3-溴丙腈和三氟甲基磺酸银等合成了4,5-<span style=\"color:red\">二</span>腈基乙<span style=\"color:red\">硫</span>基-1,3-<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代环戊烯-2-<span style=\"color:red\">硫</span>酮(bcdt)(1)及其Ag(Ⅰ)配位聚合<span style=\"color:red\">物</span>[Ag4(bcdt)4(CF3SO3)2]·(CF3SO3)2·acetone(2),并使用溶剂扩散法得到了它们的单晶.通过元素分析、红外光谱和X射线单晶衍射分析等对配体和配合<span style=\"color:red\">物</span>的组成和结构进行了表征.X射线单晶衍射分析表明:配体1通过S…S相互作用形成了一维的链状结构;配位聚合<span style=\"color:red\">物</span>2则借助配位键构建出一个新颖的三维网络结构,分子内存在着广泛的面对面和肩并肩的S…S相互作用.配体1是绝缘体,而配合<span style=\"color:red\">物</span>2室温电导率σRT＝6.46×10-8S·cm-1.","authors":[{"authorName":"杜世海","id":"123b1182-b260-464f-8f1f-26136fd08b6f","originalAuthorName":"杜世海"},{"authorName":"仲剑初","id":"695673d3-bda1-49c4-8865-c421aff947c4","originalAuthorName":"仲剑初"},{"authorName":"丁一","id":"fe433d19-e977-4c15-afd9-ddaf28c50fb1","originalAuthorName":"丁一"},{"authorName":"王洪志","id":"be3f1121-1ee9-4e62-a9a9-fdb22af38db4","originalAuthorName":"王洪志"}],"doi":"","fpage":"39","id":"6c320170-5c40-451b-ad95-0dabf89ac7ca","issue":"1","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"333d8737-ea12-4e30-a86a-e8f242b8976c","keyword":"晶体结构","originalKeyword":"晶体结构"},{"id":"606c79ba-1898-4ff0-8b19-6d97049d8b96","keyword":"四<span style=\"color:red\">硫</span>富瓦烯","originalKeyword":"四硫富瓦烯"},{"id":"bb3481e1-d718-4cc0-9c3f-348f0aceb131","keyword":"配位聚合<span style=\"color:red\">物</span>","originalKeyword":"配位聚合物"},{"id":"69aa0d7b-2aa8-45bf-b80e-19be0c67dd31","keyword":"电导率","originalKeyword":"电导率"}],"language":"zh","publisherId":"rgjtxb98200901008","title":"4,5-<span style=\"color:red\">二</span>腈基乙<span style=\"color:red\">硫</span>基-1,3-<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代环戊烯-2-<span style=\"color:red\">硫</span>酮及其Ag(Ⅰ)配合<span style=\"color:red\">物</span>的合成和晶体结构","volume":"38","year":"2009"},{"abstractinfo":"过渡金属<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>族化合<span style=\"color:red\">物</span>(Transition-metal dichalcogenides,TMDs)作为一组<span style=\"color:red\">二</span>维材料具有丰富的物理特性,近几年因其半导特性在半导体器件上具有重要的应用前景而引其了学界的普遍关注.总结了TMDs材料的制备方法及其在场效应管(FET)上的应用研究进展,并对存在的问题以及潜在的研究方向做了展望.","authors":[{"authorName":"张禹","id":"247ff66a-dad6-410b-aee5-ca84777fe4f1","originalAuthorName":"张禹"},{"authorName":"韦习成","id":"46847413-d461-4f01-b3b7-dd90513bf1ef","originalAuthorName":"韦习成"},{"authorName":"余运龙","id":"54aef689-c536-43a9-8979-5e9f571943bb","originalAuthorName":"余运龙"},{"authorName":"张浩","id":"048284dd-665e-45e4-a81c-6ea76c9f0f01","originalAuthorName":"张浩"}],"doi":"","fpage":"867","id":"53ffcdbc-a50c-4ed7-8d4f-55b6950428f5","issue":"5","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"579f8d1a-f498-421a-8663-8dc37dc097b5","keyword":"过渡金属<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>族化合<span style=\"color:red\">物</span>","originalKeyword":"过渡金属二硫族化合物"},{"id":"99365a8b-ae0f-4343-80fe-bf5261604157","keyword":"FET","originalKeyword":"FET"},{"id":"1e653253-8bf2-4be8-8531-f68bc72f4635","keyword":"器件","originalKeyword":"器件"}],"language":"zh","publisherId":"rgjtxb98201705022","title":"过渡金属<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>族化合<span style=\"color:red\">物</span>在FET中的应用研究进展","volume":"46","year":"2017"},{"abstractinfo":"以1,3-<span style=\"color:red\">二</span>苯基丙酮为原料,经干燥的H2S和HCl气体反应得<span style=\"color:red\">二</span>苄基<span style=\"color:red\">二</span>巯基甲烷(1),在微波辐射条件下,经酯化、肼解,得l,1-<span style=\"color:red\">二</span>苄基-1,1-<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>乙酰肼(3),再与芳香醛反应,方便地合成了酰腙类新化合<span style=\"color:red\">物</span>(4a～4n).其结构经IR、1H NMR、MS和元素分析确证.","authors":[{"authorName":"冯驸","id":"f3f66f8b-e771-4afa-9ca1-e841593c1c41","originalAuthorName":"冯驸"},{"authorName":"崔治财","id":"4e52153d-3d3d-4fdd-9b1a-2e2fd46462fa","originalAuthorName":"崔治财"},{"authorName":"段正超","id":"9dc9d4dc-129d-4316-a3a2-1dc01ac04084","originalAuthorName":"段正超"},{"authorName":"胡卫兵","id":"135c6ab3-86a5-4914-b20d-db487a2ef582","originalAuthorName":"胡卫兵"}],"doi":"10.3724/SP.J.1095.2012.00547","fpage":"1251","id":"604f4ef1-2606-4c6f-9104-ad4357657504","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"8781ac6b-8bcf-41e7-9253-076c9a921387","keyword":"微波辐射","originalKeyword":"微波辐射"},{"id":"9be99a99-95eb-49a7-b9f7-32d0c6ece35a","keyword":"乙酰腙","originalKeyword":"乙酰腙"},{"id":"c8cf401b-922d-46ac-ad09-e312ec1df22b","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"yyhx201211005","title":"1,1-<span style=\"color:red\">二</span>苄基-1,1-<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>乙酰腙甲烷类化合<span style=\"color:red\">物</span>的微波辐射法合成","volume":"29","year":"2012"},{"abstractinfo":"以<span style=\"color:red\">二环己基碳二</span>亚胺为脱水荆,4-<span style=\"color:red\">二</span>甲氨基吡啶为催化剂,合成了含有中心<span style=\"color:red\">硫</span>醚键聚乳酸/聚乙<span style=\"color:red\">二</span>醇嵌段共聚<span style=\"color:red\">物</span>(PBG-S-PLA).动态光散射和扫描电子显微镜结果表明此嵌段共聚<span style=\"color:red\">物</span>能自组装形成纳米球形胶束,并且可在高强度聚焦超声刺激下导致自组装结构破坏,通过粒径和形貌变化证实了结构的破坏.进一步用紫外吸收光谱研究高强度聚焦超声控制释放行为,结果表明,此新型刺激响应胶束体系对疏水药物的控制释放具有重要意义.","authors":[{"authorName":"李永文","id":"709181eb-8859-4513-b369-a9c7ddaff124","originalAuthorName":"李永文"},{"authorName":"佟锐","id":"5eecfd1a-5ca5-4537-82e4-d3d060d5bae1","originalAuthorName":"佟锐"},{"authorName":"宣隽","id":"bd78b5ff-a71c-432f-83d5-e335f636ed36","originalAuthorName":"宣隽"},{"authorName":"张洪吉","id":"4b04fafa-8960-425b-bfda-ec850219bbfe","originalAuthorName":"张洪吉"},{"authorName":"夏和生","id":"23802287-9d0a-4bab-b48e-89bb85ad2bee","originalAuthorName":"夏和生"}],"doi":"","fpage":"148","id":"15348b02-3ebb-4631-b014-916f5d3243ef","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"fb96e187-c990-43af-bccd-89a2cd9fcb98","keyword":"胶束","originalKeyword":"胶束"},{"id":"9c1d209a-263b-4ba0-8d09-54fa78431443","keyword":"<span style=\"color:red\">硫</span>醚键聚乳酸/聚乙<span style=\"color:red\">二</span>醇嵌段共聚<span style=\"color:red\">物</span>","originalKeyword":"硫醚键聚乳酸/聚乙二醇嵌段共聚物"},{"id":"f0c4e1e7-d5cb-4e46-ac5a-b166f56f8f70","keyword":"高强度聚焦超声","originalKeyword":"高强度聚焦超声"}],"language":"zh","publisherId":"gfzclkxygc201006041","title":"单<span style=\"color:red\">硫</span>键聚乳酸/聚乙<span style=\"color:red\">二</span>醇共聚<span style=\"color:red\">物</span>胶束的制备及超声响应行为","volume":"26","year":"2010"},{"abstractinfo":"以配体Ia、Ib和Ni(dbbpy)Cl2(dbbpy=4,4′-<span style=\"color:red\">二</span>-叔丁基-2,2′-联吡啶)反应,合成了两种新型冠醚环化<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>纶配体的Ni(Ⅱ)配合<span style=\"color:red\">物</span>1和2.经1H NMR、IR、MS和元素分析表征了<span style=\"color:red\">二</span>者的结构,并解析了其晶体结构,初步测定了其光电响应性质.结果表明,配合<span style=\"color:red\">物</span>2对Li+有较明显的响应,ΔE1/21=35 mV(30倍Li+),对碱金属离子Na+和K+均无明显响应.同时配合<span style=\"color:red\">物</span>1和2在室温下均有明显的溶剂变色现象.","authors":[{"authorName":"张睿","id":"c91b93aa-2368-4ed7-a990-161555c22afd","originalAuthorName":"张睿"},{"authorName":"顾晓龙","id":"d882bbe1-78b1-40ff-9cd9-2a815c382ff0","originalAuthorName":"顾晓龙"},{"authorName":"庞欢","id":"960f16d8-9eda-4ec1-b107-4ca31250a516","originalAuthorName":"庞欢"}],"doi":"10.11896/j.issn.1005-023X.2017.08.003","fpage":"11","id":"56dd1b01-e150-41b0-8d5c-562a50d89c93","issue":"8","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"f8eece66-d3f0-438f-bce7-c1eec9fc2196","keyword":"<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>纶镍(Ⅱ)配合<span style=\"color:red\">物</span>","originalKeyword":"二硫纶镍(Ⅱ)配合物"},{"id":"1ca3d536-4d4b-4256-998d-45e1c1e5b739","keyword":"冠醚衍生物","originalKeyword":"冠醚衍生物"},{"id":"4fa33429-f1f6-4831-ae2b-e2e2a4ba0f47","keyword":"合成","originalKeyword":"合成"},{"id":"e1975909-2cae-4221-8274-7b36c8a9826a","keyword":"单晶衍射","originalKeyword":"单晶衍射"},{"id":"64952dd5-f816-4239-abf1-f44ed67ac3cd","keyword":"光电性能","originalKeyword":"光电性能"}],"language":"zh","publisherId":"cldb201708003","title":"两种冠醚环化<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>纶配体的Ni配合<span style=\"color:red\">物</span>的合成、结构及光电性质研究","volume":"31","year":"2017"},{"abstractinfo":"采用低温固相反应合成了1,4-双-(<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代羧基)哌嗪乙基聚合<span style=\"color:red\">物</span>,用它作为吸附剂对废水中的重金属离子和苯胺进行了吸附和解吸性能测试. 结果表明,聚合<span style=\"color:red\">物</span>能够定量的吸附重金属离子,对Ag+、Pd2+有较高的吸附容量,吸附率分别达到98.2%和95.4%;对初始质量浓度为500 mg/L的苯胺废水进行一次性处理,苯胺质量浓度降低为10 mg/L左右,吸附剂具有优良的再生性能,可以反复使用.","authors":[{"authorName":"崔元臣","id":"3b36f5d7-48b4-4de9-b4e2-5fdcc566f330","originalAuthorName":"崔元臣"},{"authorName":"陈权","id":"fbbb9cc2-d230-4b52-a97b-0d467118b9a2","originalAuthorName":"陈权"},{"authorName":"马跃东","id":"544885a6-67c8-4d37-be18-86553952da4d","originalAuthorName":"马跃东"}],"doi":"10.3969/j.issn.1000-0518.2002.10.012","fpage":"968","id":"84fb2acb-56a3-46df-92ab-d82d8dc8805f","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"ced937eb-4595-4a52-95d2-3776e5758705","keyword":"双-(<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代羧基)哌嗪乙基聚合<span style=\"color:red\">物</span>","originalKeyword":"双-(二硫代羧基)哌嗪乙基聚合物"},{"id":"9bc5134a-760a-441c-b182-58535a6a8195","keyword":"固相合成","originalKeyword":"固相合成"},{"id":"ec9ab063-0bb9-4eff-907b-e65cb839e929","keyword":"吸附性能","originalKeyword":"吸附性能"}],"language":"zh","publisherId":"yyhx200210012","title":"1,4-双-(<span style=\"color:red\">二</span><span style=\"color:red\">硫</span>代羧基)哌嗪乙基聚合<span style=\"color:red\">物</span>的合成及其吸附性能","volume":"19","year":"2002"}],"totalpage":6136,"totalrecord":61357}