{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"概述了多壁富勒烯和新型纳米碳结构(纳米碳球)的表面修饰方法以及在催化中的应用研究现状,结果表明,化学氧化法对纳米碳颗粒进行表面修饰是有效的方法,可以改善其惰性表面,使其功能化.由于结构的独特性,纳米碳颗粒作为载体材料在电催化和某些脱氢反应中已经显示了较好的催化性能.预测了纳米碳在合成低碳烯烃中的潜在应用前景并为其在能源、化工领域中的应用提供了新的思路.","authors":[{"authorName":"杜建平","id":"d56fceb3-78eb-4bfb-af15-a6a25ff3b9c3","originalAuthorName":"杜建平"},{"authorName":"<span style=\"color:red\">赵</span><span style=\"color:red\">瑞</span><span style=\"color:red\">花</span>","id":"820390e9-e458-4f99-be33-5fc142c936cc","originalAuthorName":"赵瑞花"},{"authorName":"于峰","id":"658538a2-486a-4769-b5b9-4a662e1b2c70","originalAuthorName":"于峰"},{"authorName":"陈树伟","id":"a53e169d-d6df-482f-8c4b-d82bd104fb7e","originalAuthorName":"陈树伟"},{"authorName":"李<span style=\"color:red\">瑞</span>丰","id":"8890b74c-917c-47a3-a137-6277a58cf4c3","originalAuthorName":"李瑞丰"}],"doi":"","fpage":"49","id":"ff85b4ba-fa80-4e91-ab4f-428d5154d875","issue":"17","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"c82df0a4-9756-4cd6-bdc0-ef7bc8a35052","keyword":"纳米碳颗粒","originalKeyword":"纳米碳颗粒"},{"id":"552c5f35-3e28-4dc3-ba6b-99e8e15d41b5","keyword":"表面修饰","originalKeyword":"表面修饰"},{"id":"4b0df880-e047-4afd-9527-125570f4f408","keyword":"催化","originalKeyword":"催化"},{"id":"48faddbc-fb5d-4323-8db4-17bbc0045f2f","keyword":"应用","originalKeyword":"应用"}],"language":"zh","publisherId":"cldb201017010","title":"纳米碳颗粒在催化中的应用及前景","volume":"24","year":"2010"},{"abstractinfo":"本研究采用静电喷雾法,以壳聚糖为基质材料,康普<span style=\"color:red\">瑞</span>丁为模型药物制备微球.实验中采用AcOH/H2O和AcOH/H2O/EtOH两种溶剂,分析了微球形貌和粒径分布的影响因素,并且对CS-CA4微球的缓释性能进行了测定.结果表明,壳聚糖浓度、溶剂配比及乙醇和康普<span style=\"color:red\">瑞</span>丁的加入会使壳聚糖微球呈球状、中间塌陷的类球状、棒状等不同形貌,微球粒径存在较大差异;通过AcOH/H2O/EtOH复合溶剂将疏水性药物康普<span style=\"color:red\">瑞</span>丁载入壳聚糖微球,制备出的壳聚糖/康普<span style=\"color:red\">瑞</span>丁载药微球分散性好,粒径分布均匀,平均粒径仅为0.27μm;使用戊二醛蒸汽交联48h的微球缓释效果明显.","authors":[{"authorName":"马骊娜","id":"1199ac48-a9e3-4a3e-bb00-419a65ff9d7c","originalAuthorName":"马骊娜"},{"authorName":"方大为","id":"75d9368e-192b-4a88-9bec-9695b9fa8044","originalAuthorName":"方大为"},{"authorName":"王克敏","id":"c738f1c1-d104-410d-9f54-55b3dca5dc2e","originalAuthorName":"王克敏"},{"authorName":"聂俊","id":"a11a1f53-3fd7-45b4-9dec-4aff409c0f7b","originalAuthorName":"聂俊"},{"authorName":"马贵平","id":"ccd2cd48-646b-4ffd-95c6-9d59f1efb92a","originalAuthorName":"马贵平"}],"doi":"10.14136/j.cnki.issn 1673-2812.2015.06.023","fpage":"889","id":"e2dd295a-8366-4fe2-816d-1bd9aea9ed57","issue":"6","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"c0915753-d339-4bb7-84b4-fb27eec6936d","keyword":"静电喷雾","originalKeyword":"静电喷雾"},{"id":"84fb1809-9c50-47b3-b2b4-73df58a6cf63","keyword":"壳聚糖","originalKeyword":"壳聚糖"},{"id":"242c9cf4-d5d8-4798-86a4-712f75491661","keyword":"康普<span style=\"color:red\">瑞</span>丁","originalKeyword":"康普瑞丁"},{"id":"7bcabc05-f355-4742-9b0c-d0599dbafa0a","keyword":"微球","originalKeyword":"微球"}],"language":"zh","publisherId":"clkxygc201506023","title":"静电喷雾法制备壳聚糖/康普<span style=\"color:red\">瑞</span>丁载药微球","volume":"33","year":"2015"},{"abstractinfo":"在模拟人体生理条件下(pH=7.40),采用荧光光谱法研究双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白的相互作用.采用2种方法计算不同温度下其结合常数K<,A>、结合位点数n,同时对2种计算方法进行了比较;并根据热力学参数确定了双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白之间的作用力类型.根据Forster非辐射能量转移原理,确定了双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白相互结合时供能体-受能体间的作用距离和能量转移效率,并用同步荧光光谱研究了双醋<span style=\"color:red\">瑞</span>因对人血清白蛋白构象的影响.结果表明,双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白之间主要是以静态猝灭为主;结合距离r=2.88 nm,能量转移效率E=0.273 8,二者主要凭借氢键和范德华力进行结合.","authors":[{"authorName":"吕茜茜","id":"f12bfcef-2194-44f2-af18-bffaf338c1f1","originalAuthorName":"吕茜茜"},{"authorName":"高苏亚","id":"a30644da-e49a-4d36-afc7-e716115ce091","originalAuthorName":"高苏亚"},{"authorName":"夏冬辉","id":"d73ff043-6fa7-4f8d-a484-08e90b5cb087","originalAuthorName":"夏冬辉"},{"authorName":"李华","id":"64609acd-7353-4cf0-9b35-d68a7b42f516","originalAuthorName":"李华"}],"doi":"10.3724/SP.J.1095.2011.00497","fpage":"836","id":"c91df298-e5b8-4f97-a2e9-feb360f7f935","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"28c96fc8-c4c6-4273-a94a-5ba9464e0eba","keyword":"双醋<span style=\"color:red\">瑞</span>因","originalKeyword":"双醋瑞因"},{"id":"f2d384ae-ff9a-425a-840a-8f406b7729eb","keyword":"人血清白蛋白","originalKeyword":"人血清白蛋白"},{"id":"316e2743-ed10-4b2a-8872-69ab0668a364","keyword":"荧光光谱法","originalKeyword":"荧光光谱法"},{"id":"5a82aeaa-fe8e-49cc-972a-8fca5dd7381e","keyword":"相互作用","originalKeyword":"相互作用"}],"language":"zh","publisherId":"yyhx201107018","title":"荧光光谱法研究双醋<span style=\"color:red\">瑞</span>因与人血清白蛋白的相互作用","volume":"28","year":"2011"},{"abstractinfo":"以具有22个不同种类手性中心的新型大环抗生素伊<span style=\"color:red\">瑞</span>霉素为手性选择器,基于环氧基团高反应活性的特征,将伊<span style=\"color:red\">瑞</span>霉素用一步法键合到甲基丙烯酸酯整体柱表面制备伊<span style=\"color:red\">瑞</span>霉素键合手性毛细管整体柱.通过对制备条件进行优化,证实该制备方法可在较宽的pH范围(6.0～9.0)内进行,方法简单易行,反应条件温和.应用制备的手性毛细管整体柱在毛细管电色谱模式下,对5种手性氨基酸对映体和手性药物罗格列酮对映体进行拆分,均得到了基线分离,说明伊<span style=\"color:red\">瑞</span>霉素手性固定相具有较强的手性拆分能力.在优化的色谱条件下,6种对映体的分析时间均小于4 min,分析速度快.通过对有机调节剂、缓冲液pH值和缓冲盐浓度等分离条件进行系统考察,初步探讨了该手性毛细管整体柱对不同溶质的手性识别机理.","authors":[{"authorName":"雷雯","id":"f3112f13-31b3-48d4-8a3d-24941a9b5feb","originalAuthorName":"雷雯"},{"authorName":"张凌怡","id":"e0071825-4b94-4a3f-ba04-ba62050f2187","originalAuthorName":"张凌怡"},{"authorName":"万莉","id":"75b5c03d-49e1-4f6e-a59e-e4904e4e2b5f","originalAuthorName":"万莉"},{"authorName":"朱亚仙","id":"4f006e92-817c-4597-842f-7f801bd9dcb9","originalAuthorName":"朱亚仙"},{"authorName":"覃飒飒","id":"954f8ad8-ce48-40e5-bda6-e494c7fc375b","originalAuthorName":"覃飒飒"},{"authorName":"张维冰","id":"62dc267b-d4f0-467d-81ef-ecdbb1d66fda","originalAuthorName":"张维冰"}],"doi":"10.3724/SP.J.1123.2010.00977","fpage":"977","id":"8b0818de-0a05-43be-89a8-9aae5bf1adf3","issue":"10","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"ebde9186-14bb-48bb-a7b9-c54bb9bbfd44","keyword":"伊<span style=\"color:red\">瑞</span>霉素","originalKeyword":"伊瑞霉素"},{"id":"1f065bbb-c191-4889-88ec-8826a836e5d8","keyword":"大环抗生素","originalKeyword":"大环抗生素"},{"id":"f6bb8cb7-1144-4376-85ef-a81fdb8986f4","keyword":"手性整体固定相","originalKeyword":"手性整体固定相"},{"id":"303d37f9-7cd6-4218-8d88-b02ce6b5b5d8","keyword":"毛细管电色谱","originalKeyword":"毛细管电色谱"},{"id":"b90b4039-836a-4782-8b57-34e66b7c89e1","keyword":"对映体","originalKeyword":"对映体"}],"language":"zh","publisherId":"sp201010013","title":"伊<span style=\"color:red\">瑞</span>霉素键合手性毛细管整体柱的制备与对映体分离","volume":"28","year":"2010"},{"abstractinfo":"","authors":[],"doi":"","fpage":"15994","id":"fb0c4a31-34af-4c4b-a011-a9f5ab71392d","issue":"16","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"4cb87af0-a615-404f-80f3-5f05e3a08879","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"gncl201516001","title":"<span style=\"color:red\">赵</span>连城院士简介","volume":"","year":"2015"},{"abstractinfo":"在无表面活性剂的条件下,通过水热法在3种不同的基底上制备了由纳米棒组成的<span style=\"color:red\">花</span>状氧化锌微结构,其纳米棒沿c轴方向生长.通过X线衍射仪(XRD)、扫描电子显微镜(SEM)对<span style=\"color:red\">花</span>状氧化锌微结构进行了表征.XRD测试结果表明ZnO为纤锌矿结构,扫描电镜照片表明ZnO微结构具有<span style=\"color:red\">花</span>状形貌.简单讨论了反应物浓度对<span style=\"color:red\">花</span>状ZnO纳米棒形成的影响及生长机理.","authors":[{"authorName":"曹志峰","id":"c23912fa-dbbf-4084-a982-22bd3eb8a71a","originalAuthorName":"曹志峰"},{"authorName":"段好伟","id":"e0e9f4bb-b75c-4215-8445-6782507c2f8d","originalAuthorName":"段好伟"},{"authorName":"徐宝龙","id":"787bca16-4987-4638-9dc9-a5760a6056af","originalAuthorName":"徐宝龙"},{"authorName":"张娟","id":"0399355e-4358-44b4-9cb2-005f7db82091","originalAuthorName":"张娟"},{"authorName":"李剑平","id":"e5f34032-510d-44c4-83dc-9acc692f7307","originalAuthorName":"李剑平"}],"doi":"","fpage":"130","id":"dfa0e329-d309-4041-8364-ea8c61098295","issue":"9","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"6ed56f14-d245-44aa-b13c-bb0410f50062","keyword":"氧化锌","originalKeyword":"氧化锌"},{"id":"b61db621-c9fa-4144-a55e-c327ff39c7f4","keyword":"<span style=\"color:red\">花</span>状微结构","originalKeyword":"花状微结构"},{"id":"07088c6e-7550-40f0-a34f-e9a90b366e20","keyword":"水热法","originalKeyword":"水热法"}],"language":"zh","publisherId":"cldb200709034","title":"ZnO<span style=\"color:red\">花</span>状微结构合成研究","volume":"21","year":"2007"},{"abstractinfo":"以十八水合硫酸铝和尿素为原料,十六烷基三甲基溴化铵(CTAB)和酒石酸钠为表面活性剂,在165℃水热条件下反应3 h,制备<span style=\"color:red\">花</span>状γ-AlOOH 结构。采用扫描电镜(SEM )、热重分析和 X 射线衍射(XRD)对样品进行表征。实验结果表明,采用水热法可以得到长度、厚度均匀的γ-AlOOH 纳米片组装成的<span style=\"color:red\">花</span>状γ-AlOOH。","authors":[{"authorName":"朱振峰","id":"53371aa0-ce07-44cd-bafa-132b0ee00cac","originalAuthorName":"朱振峰"},{"authorName":"施洋","id":"4180c0c7-c20f-4203-8409-4ad7e6733f25","originalAuthorName":"施洋"},{"authorName":"刘辉","id":"f5ba72f0-cf0b-45b0-aee3-228ac68dcabc","originalAuthorName":"刘辉"},{"authorName":"程莎","id":"a2c6108b-dfd2-4f50-aeb3-56ac3931c525","originalAuthorName":"程莎"},{"authorName":"苏兴","id":"df60f580-a908-42c7-b8ff-2845221312e4","originalAuthorName":"苏兴"}],"doi":"10.3969/j.issn.1001-9731.2014.18.022","fpage":"18104","id":"2f92651c-3651-41e4-8d15-c17b10d535cc","issue":"18","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"7dc6c243-905a-4414-860a-4debcbf6b166","keyword":"γ-AlOOH","originalKeyword":"γ-AlOOH"},{"id":"3fea9256-c698-4802-856e-4f9fe4d87694","keyword":"水热合成法","originalKeyword":"水热合成法"},{"id":"1dc07cef-22f5-4825-a814-48672ee91feb","keyword":"<span style=\"color:red\">花</span>状","originalKeyword":"花状"},{"id":"3135fdff-18ca-4f31-8014-79435d0a7cc8","keyword":"制备","originalKeyword":"制备"}],"language":"zh","publisherId":"gncl201418022","title":"水热法制备<span style=\"color:red\">花</span>状γ-AlOOH?","volume":"","year":"2014"},{"abstractinfo":"由大晶粒组成的锌<span style=\"color:red\">花</span>是热浸锌镀层有别于其它镀层的显著特征,综述了热镀锌钢上锌<span style=\"color:red\">花</span>的研究现状,包括锌<span style=\"color:red\">花</span>的外观形貌、形貌与锌晶体学位向的关系、合金添加剂的作用以及锌<span style=\"color:red\">花</span>对热浸锌镀层腐蚀性能和力学性能的影响.从过冷度、晶体学位向和润湿作用3个方面论述了锌<span style=\"color:red\">花</span>的形成机制.","authors":[{"authorName":"卢锦堂","id":"033e721d-4288-48cb-a529-b4218d6b8750","originalAuthorName":"卢锦堂"},{"authorName":"王新华","id":"4bfd25ad-4672-421b-9257-b8598db0c7a1","originalAuthorName":"王新华"},{"authorName":"陈锦虹","id":"0f0f07bc-7ed6-415b-8bdb-9240cf6523b1","originalAuthorName":"陈锦虹"},{"authorName":"孔纲","id":"31c2eccd-4b07-40b7-8152-7d37f5d98fb1","originalAuthorName":"孔纲"},{"authorName":"车淳山","id":"d2967ee8-4f4f-40cb-9c2c-ea8b16dab08b","originalAuthorName":"车淳山"}],"doi":"","fpage":"72","id":"02cac3dc-226d-4105-ae27-66612783cc49","issue":"12","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"b4bd82a2-ed7c-48c2-907f-98f7678eb9a5","keyword":"锌<span style=\"color:red\">花</span>","originalKeyword":"锌花"},{"id":"980136f1-bf4c-4fc0-9032-d3a98d7d2be5","keyword":"热镀锌","originalKeyword":"热镀锌"},{"id":"2c95039c-00fb-4331-96da-7255a6ae25cb","keyword":"锌合金","originalKeyword":"锌合金"},{"id":"84416156-a842-49e3-a284-f4e230747e51","keyword":"凝固模型","originalKeyword":"凝固模型"}],"language":"zh","publisherId":"cldb200512020","title":"热镀锌钢上锌<span style=\"color:red\">花</span>的研究进展","volume":"19","year":"2005"},{"abstractinfo":"建立了<span style=\"color:red\">花</span>锚药材及其制剂中两种抗肝炎有效成分<span style=\"color:red\">花</span>锚甙和去甲氧基<span style=\"color:red\">花</span>锚甙的反相高效液相色谱测定方法.采用甲醇回流提取进行样品处理,在乙腈-磷酸水溶液为流动相作梯度洗脱、ODS柱、检测波长为254 nm条件下,<span style=\"color:red\">花</span>锚甙和去甲氧基<span style=\"color:red\">花</span>锚甙均可达到基线分离.两种成分在0.68～3.40 g/L,0.36～1.8 g/L时,其峰面积与浓度成良好的线性关系,加标回收率为95%～105%.该法适用于<span style=\"color:red\">花</span>锚药材及其制剂的质量分析检验.","authors":[{"authorName":"纪兰菊","id":"90f46e08-097e-4a74-9a0e-8d22d6b86495","originalAuthorName":"纪兰菊"},{"authorName":"丁晨旭","id":"2c8746df-d650-49bf-95dd-5f8e286188df","originalAuthorName":"丁晨旭"},{"authorName":"陈桂琛","id":"3352e965-fd5a-48ea-b75b-321a792eb223","originalAuthorName":"陈桂琛"},{"authorName":"代冬海","id":"3ec457f5-daa5-45ee-b97a-2da3012a8be4","originalAuthorName":"代冬海"},{"authorName":"杨艳蓉","id":"14875d44-a9b3-4769-8ce7-ddd34d70c613","originalAuthorName":"杨艳蓉"}],"doi":"10.3321/j.issn:1000-8713.2004.01.011","fpage":"38","id":"79461737-d0a8-4471-aab5-c3692c18d31b","issue":"1","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"eea396ec-c034-46fb-94c3-21140a045ac9","keyword":"高效液相色谱","originalKeyword":"高效液相色谱"},{"id":"8160d49b-9130-436f-8a7f-878f69755e22","keyword":"<span style=\"color:red\">花</span>锚甙","originalKeyword":"花锚甙"},{"id":"c97b8bdd-6244-4054-bd2f-4be5f48ca3b5","keyword":"去甲氧基<span style=\"color:red\">花</span>锚甙","originalKeyword":"去甲氧基花锚甙"},{"id":"155dbeba-fda4-4b67-884e-a59d6b99ec62","keyword":"<span style=\"color:red\">花</span>锚","originalKeyword":"花锚"},{"id":"a53b65f9-4880-4097-b9b3-6281cd742087","keyword":"乙肝健片","originalKeyword":"乙肝健片"}],"language":"zh","publisherId":"sp200401011","title":"反相高效液相色谱法测定野生与栽培<span style=\"color:red\">花</span>锚药材及其制剂中的<span style=\"color:red\">花</span>锚甙和去甲氧基<span style=\"color:red\">花</span>锚甙","volume":"22","year":"2004"},{"abstractinfo":"激光刻<span style=\"color:red\">花</span>技术是可以改善机械零件表面摩擦性能的一项新技术,与传统刻<span style=\"color:red\">花</span>加工方法相比,有其自身的优势.本文综述了激光刻<span style=\"color:red\">花</span>技术的国内外应用现状及该技术的发展前景,并结合我国具体情况,为该技术今后的发展提出了建议.","authors":[{"authorName":"宋全胜","id":"46c37958-6844-4855-b789-0c19872c9414","originalAuthorName":"宋全胜"},{"authorName":"曾晓雁","id":"300f3c74-fb9f-424d-9016-53c94eea0e2b","originalAuthorName":"曾晓雁"}],"doi":"10.3969/j.issn.1673-2812.2002.04.037","fpage":"609","id":"3776f0bf-8b90-4cb3-a510-93934e3292d1","issue":"4","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"1774473a-7450-4292-b86e-aa68dea67935","keyword":"激光刻<span style=\"color:red\">花</span>","originalKeyword":"激光刻花"},{"id":"5ca435f9-a471-4d0e-be1e-3df7e9d211a6","keyword":"摩擦学","originalKeyword":"摩擦学"},{"id":"6ed75675-49c7-44c0-b330-c708c2b6568a","keyword":"润滑","originalKeyword":"润滑"}],"language":"zh","publisherId":"clkxygc200204037","title":"激光刻<span style=\"color:red\">花</span>技术的应用现状和展望","volume":"20","year":"2002"}],"totalpage":50,"totalrecord":497}