HUANG Qizhong
,
YANG Qzaoqin and WU Lijun(Powder Metallurgy Research institute
,
Central Sonth University of Technology
,
Changsha 410083
,
China Materials Research and Test Center
,
Hnnan University
,
Changsha 410082
,
ChinaLab. of Atomic Imaging of Solids
,
Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang110015
,
ChinaState Key Laboratory for Corrosion and Protection
,
Institute of Corrosion and Protection of Metals
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)Manuscript received 4 August 1995
,
in revised form 6 April 1996
金属学报(英文版)
A Preliminary study of the effect of silicon additive on the structure and properites of C-B_4C-SiC composite was conducted. A liquid Phase has formed and the liquid Si reacts with C to form SiC at the grain boundary when sintering, which accelerates the sintering process and retards the grain growth. Consequently, the density and strength of the composite increase markedly. And the increase in the density increases the oxidation resistance and decreases the specific resistance of the composite. Furthermore,the C-B_4 C-SiC composite has good heat-shock resistance. The phenomena may be dueto the strengthening and toughening of microcracks.
关键词:
:Si additive
,
null
,
null
Q.R. Zhang
,
Y.G. Li and Z. Fang (Department of Chemistry
,
Central South University of Technology
,
Changsha 410083
,
China)(Department of Chemistry
,
Central South University of Technology
,
Changsha 410083
,
China)(Department of Chemistry
,
Central South University of Technology
,
Changsha 410083
,
China)
金属学报(英文版)
In orber to calculate the activity coefficients of water in the aqueous solution systems of double electrolytes, HCl and MCln (M=Ni, Cu,Na and Fe), a simplified regular solution model has been derived based on the assumption that the electrolytes in the aqueous solution are treated as independent particles instead of their ion forms, and that the interaction of the component pair HCl-MCln in the aqueous solution is very weak as compared with the component pairs HCl-H2O and H2 O-MCln. The interchange energies of the component pairs in the discussed systems, ωWCl-H2o, ωH2o-NiCl2,ωH2o-CuCl2, ωH2o-NaCl and ωH2O-FeCl3, have been evaluated from the experimental data to be-69800, -212600, -90550, -42450 and -198310J·mol-1.
关键词:
solution model; interchange energy; electrolyte solution
HUANG Kelong
,
SHU Wanyin
,
DING Dunhuang
,
LIU Guogen
,
DONG Ping
,
Central South University of Technology
,
Changsha
,
China HUANG Kelong
,
Lecturer
,
Department of Chemistry
,
Central South University of Technology
,
Changsha 410083
,
China
金属学报(英文版)
In order to clarify the mechanism and the complex formed in the extraction of divalent Mn by alkylphosphonic acid monoester, the solid complex has been prepared by mono (2-ethylhexyl)-2-ethylhexyl phosphate, HEH(EH)P, HA with divalent Mn. The elemental analysis, magnetic susceptibility and thermogravimetry have been determined for the solid complex of HEH(EH)P-Mn(II) and the infrared spectrum has been carried out in comparison to the extractant HEH(EH)P. The extracted compound has also been studied by electronic and electron spin resonance spectroscopy in octane solvent and solid state at room temperature. On the basis of the measurements, it is concluded that the structure of the solid polymeric species MnA_2 is in a tetrahedral arrangement.
关键词:
solvent extraction mono (2-ethylhexyl)-2-ethylhexyl phosphate
,
null
,
null
C.M. Yang
,
Q.R. Zhang and Z. Fang(Department of Chemistry
,
Central South University of TecHnology
,
Changsha 410083
,
China)
金属学报(英文版)
Polyaniline doped with rare earth chloride was synthcsized in organic solvent and identified by clemental analysis and ithered spectroscopy. The experimental results show that there exist both doping and complexation at the same time in the resulting product. When pH<4, prototnic acid doping is predominating, whereas rare earth ion complexation is predominating when pH>1. Moreover, polyanitine doped wih rare earth chloride exhibits better thermal stability than that doped with hydrochloric acid.
关键词:
dope
,
null
,
null
,
null
M.W. Li
,
R.Z. Tang and W.X. Li (Department of Materials Science and Engineering
,
Central South University of Technology
,
Changsha 410083
,
China)
金属学报(英文版)
Starting from elemental powders, complete MoSi2 powder forms abruptly between 3.5and 4 h during mechanical alloying (MA) of the Mo-66 at.% Si powders. Continuous milling of this MoSi2 Phase leads to a nanocrystalline powder and amorphizationtransformation takes place after 100 h milling. Howeven MA of the Mo-37.5 at.%Si powders does not result in the formation of the Mo5Si3 crystalline phase, but the formation of a Mo(Si) supersaturated solid solution (SSS) and a completely amorphots phase after 5 h and 70 h milling, respectively. The free energy of the Mo-Sisystem has been calculated and it has been found that there is no driving force for the amorphization reaction under normal conditions. The amorphization by MA of the Mo-Si system is attributed to a solid-state amorphization reaction in which defects and a very fine grain size induced during milling process may raise the free energy of the crystalline intermetallic phase (for MoSi2) or the Mo(Si) supersaturated solid solution (for Mo5Si3) above that of the amorphous phase.
关键词:
mechanical alloying
,
null
,
null
L. X. Li and D. S. Peng (Department of Materials Science and Engineering
,
Central SouthUniversity of Technology
,
Changsha 410083
,
China)
金属学报(英文版)
The deformaton behavior of Ti - 6Al - 4V alloy under hot - working condition has been studied by compression testing in the temperature range 750 - 950℃ and strain rate range 0.05 - 15s -1. The flow stress decreases with the increase of temperature and with the decrease of strain rate. After a steep initial strain hardening, a flow softening occurs. This softening is mainly ascribed to the temperature rise and dynamic recmptallisation.By a simple extension, a classical sinushyperbolic constitutive equation can be used to describe the flow behavior of Ti - 6Al - 4V alloy. flow stress is described as a function of strain, strain rate and temperature. The parameters Q, n andaare the same at differ- ent deformation conditions, and A is a funciton of strain.
关键词:
Ti-6Al-4V alloy
,
null
,
null
H. Zhang
,
Y. Y. Liu
,
D. S. Peng and C. K. Wang (Department of Materials Science and Engineering
,
Central South University of Technology
,
Changsha 410083
,
China)
金属学报(英文版)
Continuous thermo-mechanical processing (CTMP) of 6201 aluminum alloy was simulated on Gleeble-1500. The deformed specimens were analyzed by the observation of TEM and the measurement of hardness. It was shown that rapid solid solution and aging treatment can be effectively combined in one procedure by the strain induced during CTMP. The deformation temperature is ranging from 540* C to 300* C, the hardness increases directly before the 6th pass followed by a slight drop, the amount of precipitates increases with the holding time after deformation. Uniformly distributed and stabilized Mg2Si precipitates, as well as dislocation substructure can be observed on deformed specimens which have been subsequently held at 300℃ for 60 seconds.
关键词:
6201 aluminum alloy
,
null
,
null
,
null
,
null
Y.H. He
,
B. Y. Huang
,
Y. Liu and Y.X. Liu (Powder Metallurgy Research Institute
,
Central South University of Technology
,
Changsha 410083
,
China)
金属学报(英文版)
The effects of a new technology, multi-step thermo-mechanical treatment, on the microstructure, deformation substructure and mechanical properties at ambient and elevated tempemture of can-forged Ti-33 Al-3 Cr-0.5Mo (wt%) Alloy were investigated.The results show that, after multi-step thermo-mechanical treatment of can-forged specimens, homogeneous, fine microstructures can be obtained in the whole TiAl-based alloy specimens. Furthermore, the specimen with homogeneous and fine full lamellae microstructure demonstrutes excellent comprehensive mechanical properties at ambient and elevated temperature.
关键词:
TiAl-based alloy
,
null
,
null
