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Preparation of Sodium Borosilicate Transparent Bulk Gel

Weidong XIANG , Zhongcai WANG , Quanzhu YANG and Wenxing ZHAO(Changchun Institute of Optics and Fine Mechanics , Chinese Academy of Sciences , Changchun 130022 , China)Chengyu WANG(Institute of Glass and Inorganic Materials , Dalian Institute of Light Industry

材料科学技术(英文)

A transparent bulk sodium borosilicate gel with the composition of 72SiO2·23B2O3·5Na2O (wt pct) was prepared by using tetraethyl orthosilicate, boric acid, sodium methoxide, sodium alkoxide, sodium acetate as precursor, methanol, ethanol and glycolic methyl ether as precursor solvent and hydrochloric acid as catalyst. Properties of gel, varied principle and related mechanism of conversion for sol to gel are discussed. Ideal composition and dry process are given in this work

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Development of Glass Ceramics Made From Ferrous Tailings and Slag in China

LIU Chengjun , SHI Peiyang , ZHANG Dayong , JIANG Maofa

钢铁研究学报(英文版)

A great amount of ferrous tailings and slag cause severe damage to the ecological environment, which must be reclaimed and utilized. The composition, type, and characteristics of ferrous tailings and slag in China were introduced. The research status and the application outlook of glass ceramics made from ferrous tailings and slag were discussed. Glass ceramics made from ferrous tailings and slag can be applied to various fields, and it will be environmentally conscious materials in the 21st century.

关键词: glass ceramics;ferrous tailings;slag

Development of rapidly quenched soft magnetic materials in China

Shaoxiong ZHOU

材料科学技术(英文)

The discovery of the first Fe-based ferromagnetic amorphous alloy in 1966 had made an impact on conventional magnetic materials because of its unique properties. Since then, a number of amorphous magnetic materials have been successfully developed and used in a wide variety of applications. A brief review of R & D activities on amorphous soft magnetic materials in China is given from the beginning to the present in a somewhat chronological order, followed by a brief introduction to their applications on electric and electronic industries. An analysis and a prospect of Chinese market of such amorphous materials are also presented.

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Mechanical properties, damage and fracture mechanisms of bulk metallic glass materials

材料科学技术(英文)

The deformation, damage, fracture, plasticity and melting phenomenon induced by shear fracture were investigated and summarized for Zr-, Cu-, Ti- and Mg-based bulk metallic glasses (BMGs) and their composites. The shear fracture angles of these BMG materials often display obvious differences under compression and tension, and follow either the Mohr-Coulomb criterion or the unified tensile fracture criterion. The compressive plasticity of the composites is always higher than the tensile plasticity, leading to a significant inconsistency. The enhanced plasticity of BMG composites containing ductile dendrites compared to monolithic glasses strongly depends on the details of the microstructure of the composites. A deformation and damage mechanism of pseudo-plasticity, related to local cracking, is proposed to explain the inconsistency of plastic deformation under tension and compression. Besides, significant melting on the shear fracture surfaces was observed. It is suggested that melting is a common phenomenon in these materials with high strength and high elastic energy, as it is typical for BMGs and their composites failing under shear fracture. The melting mechanism can be explained by a combined effect of a significant temperature rise in the shear bands and the instantaneous release of the large amount of elastic energy stored in the material.

关键词: bulk metallic glasses (BMGs);mechanical properties;shear fracture;failure criterion;plastic deformation;melting phenomenon;supercooled liquid region;fatigue-crack-propagation;nanostructure-dendrite composite;soft-magnetic properties;serrated;plastic-flow;ni amorphous-alloys;ti-based composites;in-situ;formation;cu-be alloy;high-strength

Guangzhou Institute of Energy Conversion,The Chinese Academy of Sciences,Guangzhou 510070,China

B.W. Wang , H. Shen

金属学报(英文版)

Ni-Cr System solar selective thin solid films were prepared by d.c. magnetron reactivesputtering under the atmosphere of O2 and N2. Ni-Cr alloy was chosen as targetmaterial and copper sheets as substrate. Using SEM, Spectrophotometer and Talystepto analyze the relations between the selective characteristic and the structure, theformation and the thickness of the thin films. The aim is to obtain good solar selectivethin films with high absorptance and low emittance, which is applied to flat plate solarheat collectors.

关键词: solar selective thin film , null , null , null

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

High tensile strength reliability in a bulk metallic glass

Applied Physics Letters

We report high strength reliability under tension of a bulk metallic glass (BMG), demonstrated by its high uniformity in strength found over a statistically significant number of specimens, despite the fact that the samples all showed no macroscopic plasticity. Weibull statistical analysis showed that the Weibull modulus of the material is 36.5, which is much higher than the values of more typical brittle materials, further confirming BMGs' high reliability [Appl. Mech. Rev. 5, 449 (1952)]. (c) 2008 American Institute of Physics.

关键词: plasticity;alloys;temperature;brittleness;estimators;fracture;stress

Developing carbon materials targeted for applications-A summary on the annual world conference on carbon, Carbon2011

新型炭材料

The 2011 Annual World Conference on Carbon (Carbon 2011) was held in Shanghai, China, during 24-29 July, 2011. This conference was hosted jointly by East China University of Science and Technology, University of Shanghai for Science and Technology, and Institute of Coal Chemistry Chinese Academy of Sciences. About 800 attendees from 42 countries/regions participated in this conference, and 797 papers were accepted for presentation, including 5 plenary lectures, 42 keynote lectures, 280 oral presentations, and 470 posters, involving 10 topics: graphene; nanocarbon, carbon for energy storage and conversion, porous carbon and adsorption, carbon fiber and composites, precursor/carbonization and graphitization, computation and modeling, bio-carbon and safety, novel experimental techniques and characterization, bulk carbon and industrial applications. Research and development of nanocarbons are quite active and in particular, graphene received tremendous interest. Rapid progress has also been made on the electrochemical properties, energy conversion and energy storage applications of carbon materials.

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