材料期刊网

Mechanically Driven Alloying and Structural Evolution of Nanocrystalline Fe_(60)Cu_(40) Powder

Yuanda DONG and Xueming MA(School of Materials Science and Engineering , Shanghai University , Shanghai 200072 , China)Yuanzheng YANG(Dept. of Mechanical Engineering(2) , South China University of Technology , Guangzhou 510641 , China)Fangxin LIU and Genmiao WA

材料科学技术（英文）

Highly supersaturated nanocrystalline fcc Fe60Cu40 alloy has been prepared by mechanical alloying of elemental powders. The phase transformation is monitored by X-ray diffraction (XRD),Mossbauer spectroscopy and extended X-ray absorption fine structure (EXAFS). The powder obtained after milling is of single fcc structure with grain size of nanometer order. The Mossbauer spectra of the milled powder can be fitted by two subspectra whose hyperfine magnetic fields are 16 MA/m and 20 MA/m while that of pure Fe disappeared. EXAFS results show that the radial structure function (RSF) of Fe K-edge changed drastically and finally became similar to that of reference Cu K-edge, while that of Cu K-edge nearly keeps unchanged in the process of milling. These imply that bcc Fe really transforms to fcc structure and alloying between Fe and Cu occurs truly on an atomic scale. EXAFS results indicate that iron atoms tend to segregate at the boundaries and Cu atoms are rich in the fcc lattice. Annealing experiments show that the Fe atoms at the interfaces are easy to cluster to α-Fe at a lower temperature, whereas the iron atoms in the lattice will form γ-Fe first at temperature above 350℃, and then transform to bcc Fe

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25Cr2Ni4WA钢裂纹分析

钱志明 , 谷砚魁

物理测试 doi:10.3969/j.issn.1001-0777.2001.03.010

采用金相检验、扫描电镜、超声探伤等方法，对25Cr2Ni4WA钢的不同形态的裂纹进行分析，结果表明，裂纹均是由组织应力、热应力引起的。

关键词: 裂纹 , 断口 , 应力

铝和稀土合金化25Cr2Ni4WA钢的高温特性

李风 , 刘江龙 , 丁培道

兵器材料科学与工程 doi:10.3969/j.issn.1004-244X.2001.01.008

研究了穿孔顶头常用钢25Cr2Ni4WA经铝和稀土合金化后的高温性能和氧化特征。试验结果与分析表明，铝和稀土合金化可明显提高穿孔顶头的高温硬度和强度及表面氧化膜抗剥落行为，从而可有效提高穿孔顶头的使用寿命。

关键词: 铝 , 稀土 , 合金钢 , 合金化

Introduction to atmospheric corrosion research in China

Science and Technology of Advanced Materials

In this paper, we introduce the research on atmospheric corrosion in China. We describe the climate characteristics and the classification of atmospheric corrosivity across the whole country. We also describe the rusting evolution under simulated wet/dry cyclic conditions. (C) 2007 NIMS and Elsevier Ltd. All rights reserved.

关键词: atmospheric corrosion;corrosivity;rusting evolution;weathering steels;rust;mechanism;so2;o-3;no2

Recent Advances of Laser Coating Technology in China

LIANG Yong LI Ruiguo Institute of Metal Research , Academia Sinica , Shenyang 110015 , ChinaInstitute of Corrosion and Protection of Metals , Aademia Sinica , Shenyang , 110015 , China

材料科学技术（英文）

Recent advances in laser coating technology including laser cladding,laser surface alloying and laser vapour deposition in China are reviewed in this paper.

关键词: laser , null , null , null , null

残余奥氏体对18Cr2Ni4WA钢接触疲劳抗力的影响

祝东 , 汪复兴 , 蔡其巩 , 郑明新 , 程荫芊

金属学报

在滚动接触疲劳试验机上,对不同残余奥氏体含量的18Cr2Nj4WA 钢制成的滚轮试样进行了试验.试验结果表明,残余奥氏体含量商的试样比含量低的试样具有较好的接触疲劳性能.认为奥氏体内超细团粒的出现,形成微观双相组织,可能是提高接触疲劳抗力很重要的因素.此外,形变诱发马氏体相变及残余应力的增加等对接触疲劳抗力的提高,也起一定的作用.

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18Cr2Ni4WA钢过热和石状断口的观察

叶里

金属学报

比较了三种不同冶炼工艺(平炉与电炉混合炼钢经RH真空循环脱气处理、碱性电炉冶炼及电炉冶炼加电渣重熔)和两种不同脱氧方法(并用铝、钛或仅用铝脱氧)生产的五炉18Cr2Ni4WA钢的过热敏感性并观察了断口.实验表明,这种钢产生严重过热井出现石状断口的条件是:(1)钢在高温加热时原始奥氏体晶粒充分长大;(2)钢中含有MnS夹杂物以细小的颗粒沉淀在原始奥氏体晶界上,并用铝、钛脱氧使钢中含有微量残留钛可以在高温加热过程中阻止奥氏体晶粒长大同时改善MnS夹杂物的形态和分布状况,从而有效地降低了这种钢的过热敏感性。最后,讨论了这种钢形成石状断口的机构。

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18Cr2Ni4WA钢氮化层强化机理的研究

郑经纮 , 王育烽 , 沈甫法 , 俞德刚 , 毛树楷

金属学报

本文应用薄膜透射电镜方法对经不同温度一段及二段氮化后的18Cr2Ni4WA钢的内氮化层显微组织及其强化本质进行了研究.结果表明,该钢内氮化层形成过程可分为二个阶段:1.合金元素及氮原子在铁素体基体{100}α面上形成有序化的混合偏聚区;2.由偏聚区转变成平衡沉淀相CrN,它与基体的位相关系符合Baker-Nutting关系:(001)_(CrN)∥(001)α;[110]CrN∥[100]α在较低温度氮化时,CrN还可由碳化物转变而成.造成内氮化层高硬度的主要原因是铁素体基体内形成弥散的有序化混合偏聚区.在420—500℃氮化的条件下,内氮化层强度达最高值.随氮化温度升高,其硬度逐渐下降.采用低温+高温二段氮化时,由于低温形成的有序化偏聚区相当稳定,从而使氮化层的高硬度能保持到较高的温度,所以二段氮化在保持内氮化层高硬度的同时可以加速氮化过程,缩短氮化时间.

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25Cr2Ni4WA合金钢高温锰系磷化工艺

谢良波 , 方亮 , 李赟 , 胡釜 , 胡佳

材料保护

高温锰系磷化对部分高合金钢处理效果不佳.为此,对25Cr2Ni4WA合金钢黑色锰系磷化工艺进行了研究,通过正交试验,分析了磷化过程中总酸、酸比、Fe2+浓度、表调时间、磷化时间等因素对磷化膜耐蚀性能和膜重的影响.结果表明,适当的总酸、酸比、磷化时间以及降低Fe2+浓度和表调时间有利于提高耐蚀性能;适当的表调时间及增加总酸、酸比、Fe2+浓度和磷化时间有利于增加膜重.结果表明,为提高耐蚀性能,应尽量使磷化膜晶粒细小均匀、致密;获得较佳磷化膜耐蚀性能的工艺参数为:总酸110点,酸比6.0,0.6g/L Fe2+,表调时间20s,磷化时间20min;膜重较佳的工艺参数为:总酸130点,酸比7.0,1.8g/L Fe2+,表调时间40s,磷化时间20min.

关键词: 高温锰系磷化 , 磷化膜 , 25Cr2Ni4WA合金钢 , 耐蚀性能 , 膜重

Development of Cast Superalloys for Gas Turbines in China

CHEN Rongzhang CHEN Wanhua Institute of Aeronautic Materials , Beijing 100095 , China.

材料科学技术（英文）

As in other countries,significant achievements in the research of cast superalloys for many years have also been obtained in China.These results are important contribu- tion to the development of aero and land-based gas tur- bine engines.

关键词: cast superalloy , null