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Origin of Ordering Coupled Tweed Microstructures in Alloys with Large Atomic Size Factors

Xiaobing REN and Xiaotian WANG (College of Materials Science and Engineering , Xi'an Jiaotong University Xi'an 710049 , China)K.Shimizu and T.Tadaki (Institute of Scientific and Industrial Research , Osaka University , 8-1 , Mihoga-oka , Ibaraki , Osaka , 567 , Ja

材料科学技术(英文)

A theoretical study is developed on the evolution and mechanism of an ordering coupled phase separation, and on the origin of a resultant tweed microstructure. It is found that long-range elastic interaction among atoms with different atomic sizes plays a key role in the phase sep aration, and that the evolution of the phase separation is very similar to that Of conventional spinodal decomposition except that the separation is dependent on an elastic interaction order ing (EIO). This "EIO coupled spinodal decomposition" is shown to exhibit a periodical or tweed microstructure being accompanied by an EIO. It is also found that a large atomic size factor yields a large positive contribution of EIO to spinodal decomposition. Generally it is thermodynamically and kinetically favorable for the EIO to precede the onset of spinodal decomposition,though the former is not separable from the latter as a whole. We suggest that an initially disordered solid solution undergoes an EIO first, and then the partially ordered solid solution starts to decompose via a spinodal mechanism. Solute-enriched regions increase their degree of order along with an increase in solute content, and solute-depleted regions decrease their degree of order together with a decrease of solute content. The final microstructure is characterized by a periodical array of highly ordered solute-enriched regions and nearly disordered solute-depleted regions. The notion of EIO coupled spinodal decomposition is in general agreement with the transformation behaviour of a large number of alloy systems.

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Introduction to atmospheric corrosion research in China

Science and Technology of Advanced Materials

In this paper, we introduce the research on atmospheric corrosion in China. We describe the climate characteristics and the classification of atmospheric corrosivity across the whole country. We also describe the rusting evolution under simulated wet/dry cyclic conditions. (C) 2007 NIMS and Elsevier Ltd. All rights reserved.

关键词: atmospheric corrosion;corrosivity;rusting evolution;weathering steels;rust;mechanism;so2;o-3;no2

Recent developments in high temperature intermetallics research in China

Intermetallics

A comprehensive survey was made of various advances of intermetallics research in China. The investigation focussed on the fundamental research and materials development. Charge density distribution and site occupancy of alloying elements, environmental embrittlement and chemical reaction, interface structures and phase transformation at the atomic scale, nanocrystalline intermetallics and its thermal stability, superplastic behavior and anomalous yield strength peak are reviewed. Several Ti-Al and Ni-Al based alloys have been manufactured, and show good mechanical properties. Diverse components have been fabricated successfully. (C) 2000 Elsevier Science Ltd. All rights reserved.

关键词: aluminides, miscellaneous;hydrogen embrittlement;mechanical properties;at high temperatures;superplastic behavior;phase interfaces;grain-boundary fracture;in-situ composites;environmental;embrittlement;hydrogen embrittlement;ni3al;compression;alloys;co3ti;boron;feal

Industrial Research on Broadening of Slab in Continuous Casting Process

FU Jian-xun , LI Jing-she

钢铁研究学报(英文版)

The broadening of slab was investigated on the basis of several industrial manufactures of continuous casting. The results show that slab broadening commonly exists in the process of continuous casting. It is found that there are few reports on it until now. In order to find out the reasons of slab broadening, we checked the effect of change of mold size, excepting technological parameters, conditions of soft reduction, and contraction of roll gap on slab broadening. Our examinations exclude the possibility of change of mold size, excepting technological parameters to be the causes of broadening of slab. The broadening of slab probably results from the static pressure of molten steel and the force from driving rolls. At the same time, online observations on three kinds of steel in the process of continuous casting reveal that the average objective ratio of slab broadening ranges from 1.27 % to 3.00 %, and even arrives at 4.4 %. In addition, the width of mold and formulas of calculating the broadening of slab was deduced.

关键词: continuous casting;slab;broadening;industrial investigation

R&D STATUS ON INTERMETALLICS IN CHINA

CHEN Guoliang(State Key Laboratory for Advanced Metals and Materials University of Science and Technology Beijing Beijing 100083 , China)SHI Changxu (Academia Sinica , Beijing 100864 , China)

金属学报(英文版)

This paper briefiy introduces the R&D of intermetallics in China. R&D on intermetallics in a national scale in China began near ten years ago. The investigation in past years focused on the fundamental research and materials development. A significant progress has been made. Various components that made of Ti3Al Ni3Al, TiAl and Fe3Al have been successfully manufactured Some of them have been evaluted. It is expected that some intermetallic alloys will be produced in an industrial scale in the near future.

关键词: :intermetallic alloys , null , null , null

MICROSTRUCTURE AND PROPERTIES OF SiC_w/6061Al COMPOSITE The Author is now with Institute of Metal Research,Academia Sinica,China

MA Zongyi YAO Zhongkai Harbin Institute of Technology , Harbin , China

金属学报(英文版)

The SiC_w/Al composite prepared by squeeze casting has a combination of superior room temperature specific strength and modulus together with excellent thermal properties.The extrusion can make an improvement on the strength and ductility of the composite from 582 MPa as squeeze casted up to 639 MPa,and on the transformation from isotropic to the anisotropic structure.This seems to be explained by the orientation of whiskers and the densification of dislocations in matrix.TEM observation indicates that the stacking fault is the usual planar defect on the SiC_w surface. composite;;SiC whisker;;Al alloy;;microstructure

关键词: composite , null , null , null

Some Problems of Recycling Industrial Materials

CAI Jiuju , LU Zhongwu , YUE Qiang

钢铁研究学报(英文版)

The industrial system should learn from the natural ecosystem. The resource utilization efficiency should be increased and the environmental load should be decreased, depending on the materials recycled in the system. The classification of industrial materials from the viewpoint of largescale recycling was stated. Recycling of materials, on three different levels, was introduced in the industrial system. The metal flow diagram in the life cycle of products, in the case of no materials recycled, materials partially recycled, and materials completely recycled, was given. The natural resource conservation and the waste emission reduction were analyzed under the condition of materials completely recycled. The expressions for the relation between resource efficiency and material recycling rate, and the relation between ecoefficiency and material recycling rate were derived, and the curves describing the relationship between them were protracted. The diagram of iron flow in the life cycle of iron and steel products in China, in 2001, was given, and the iron resource efficiency, material recycling rate, and iron ecoefficiency were analyzed. The variation of iron resource efficiency with the material recycling rate was analyzed for two different production ratios.

关键词: recycling;industrial material;product life cycle;resource efficiency;ecoefficiency;material recycling rate

ANOMALIES AROUND T=270K OBSERVED IN POTASSIUM BLUE BRONZE

Physics Letters A

Except for a Peierls transition at T(p) = 180 K, a new transition around T = 270 K in K0.3MoO3 single crystals has been found as evidenced by the anomalies in electrical, magnetic and thermodynamic properties. This transition may be caused by the variation of carrier characteristics or of the charge transfer between cations and anions.

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