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ANALYSIS OF THE GROWTH MECHANISM OF TiAl_3 WHISKERS PREPARED BY IN SITU REACTION IN MOLTEN ALUMINUM

B. Yang , YQ. Wang , J. Zhang and B.L. Zhou (Institute of Metal Research , Chinese Academy of Sciellces , Shenyang 110015 , China Nanchang University , Nanchang 330029 , China International Center for Materials Physics , Chinese Academy of Sciences , Shenyang 110015 , China)

金属学报(英文版)

Some TiAl3 whiskers are found to be produced simultaneously during the formation process of TiB2 Particulates fabricated by in situ reaction in molten aluminum. The thec t of temperature of molten aluminum on the morphologies of the TiAl3 whiskers and the growth mechanism of the whiskers are studied in this paper. The results show that the aspect rutio of the TiAl3 whiskers decreases with the increase of the temperoture. The growth of the whiskers is proved to be controlled by a Vapor-LiquidSoltd (VLS) mechanism. The titanium and aluminum atoms in the catalytic droplet,however, have been coofrmed to react with each othen which is dtherent from other whlskcrs growing by a VLS mcchanism where the compostion in the catalytic droplet is a constant.

关键词: in situ reaction , null , null , null

Surface Degradation of Bulk AlN+Al Nano-composites

Xiangcheng SUN , Feng YE , Xaoping SONG , Mngchuan YANG and Xiukui SUN (State Key Lab. for RSA , Institute of Metal Research , Chinese Academy of Sciellces , Shenyang 110015 , China)

材料科学技术(英文)

Bulk AlN + Al nanocomposite materials were Synthesized by sintering the compacts of AlN and Al nanoparticles, which were produced by an active plasma-metal reaction method. The sudeces of as-prepared nanocomposite was investigated by X-ray photoelectron spectroscopy (XPS).Results show the surfaces are much degraded and the degradation products are alumina(Al2O3),boehmite(AIOOH), bayerite(AI(OH)3) layer. The mechanism of degradation behaviour in moist environment was also discussed

关键词:

Guangzhou Institute of Energy Conversion,The Chinese Academy of Sciences,Guangzhou 510070,China

B.W. Wang , H. Shen

金属学报(英文版)

Ni-Cr System solar selective thin solid films were prepared by d.c. magnetron reactivesputtering under the atmosphere of O2 and N2. Ni-Cr alloy was chosen as targetmaterial and copper sheets as substrate. Using SEM, Spectrophotometer and Talystepto analyze the relations between the selective characteristic and the structure, theformation and the thickness of the thin films. The aim is to obtain good solar selectivethin films with high absorptance and low emittance, which is applied to flat plate solarheat collectors.

关键词: solar selective thin film , null , null , null

Nickel-free stainless steel for medical applications

材料科学技术(英文)

BIOSS4 steel is essentially a nickel-free austenitic stainless steel developed by the Institute of Metal Research, Chinese Academy of Sciences, in response to nickel allergy problems associated with nickel-containing stainless steels that are widely used in medical applications. The high nitrogen content of this steel effectively maintains the austenitic stability and also contributes to the high levels of corrosion resistance and strength. BIOSS4 steel possesses a good combination of high strength and toughness, better corrosion resistance, and better blood compatibility, in comparison with the medical 316L stainless steel. Potential applications of BIOSS4 steel can include medical implantation material and orthodontic or orthopedic devices, as well as jewelries and other decorations.

关键词: medical stainless steel;nitrogen;nickel-free;nickel-allergy;blood;compatibility;austenitic steels;high-nitrogen;corrosion;cells

Nickel-free Stainless Steel for Medical Applications

Yibin REN , Ke YANG , Bingchun ZHANG , Yaqing WANG , Yong LIANG

材料科学技术(英文)

BIOSS4 steel is essentially a nickel-free austenitic stainless steel developed by the Institute of Metal Research, Chinese Academy of Sciences, in response to nickel allergy problems associated with nickel-containing stainless steels that are widely used in medical applications. The high nitrogen content of this steel effectively maintains the austenitic stability and also contributes to the high levels of corrosion resistance and strength. BIOSS4 steel possesses a good combination of high strength and toughness, better corrosion resistance, and better blood compatibility, in comparison with the medical 316L stainless steel. Potential applications of BIOSS4 steel can include medical implantation material and orthodontic or orthopedic devices, as well as jewelries and other decorations.

关键词: Medical stainless steel , null , null , null , null

THERMODYNAMIC STUDY OF CHROMITE CAUSTICFUSION PROCESS

S.L. Zheng , Y. Zhang

金属学报(英文版)

A new method for chromate cleaning production named chromite caustic fusion pro-cess, is advanced by Institute of Chemical Metallurgy, the Chinese Academy of Sci-ences. With sodium hydroxide as reaction medium, the new process is composed ofthree procedures: liquid phase oxidation of chromite - metastable phase separation -carbonation ammonium transition. Generally illustrating the new process and its fea-tures, this paper mainly studies the thermodynamics of chromite oxidation. The newprocess has much better practical results than the conventional chromate productionprocess in which sodium carbonate is used as reaction medium. The superiority is alsoshown through thermodynamic studies.``

关键词: chromite , null , null , null , null

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