M.D.Starostenkov
,
G.M.Poletayev
,
D.M.Starostenkov
材料科学技术（英文）
The structural transformation in thin films of bimetals in the dependence on temperature and concentration of vacancies was investigated. The system Ni-Al structural transformation was realized by computer design according to the mechanism of self-sustained high-temperature synthesis. Structural transformation is characterized by the presence of dislocations, clusters of point defects and germs of intermetallic phases near interphase boundaries.
关键词:
马敬翙
,
刘光明
,
曾潮流
,
杜楠
,
赵晴
表面技术
doi:10.3969/j.issn.1001-3660.2006.04.005
采用电化学方法、扫描电镜、能谱分析等技术,研究了常温下镍基高温合金M17和M38G在NaCl溶液和含S2O2-3的NaCl溶液中的腐蚀行为.结果表明,在含质量分数为3.5% NaCl的溶液中,M17和M38G均会遭受严重的点腐蚀;向NaCl溶液(NaCl质量分数为3.5%)添加Na2S2O3(Na2S2O3质量分数为1.5%)后,由于溶液中的S2O2-3在试样表面活性点与Cl-竞争吸附并与H+结合,使两种合金的点蚀均受到抑制;M38G中存在微量的Nb、Ta、Mo等元素使得M38G合金在NaCl溶液中的耐腐蚀性能明显优于M17合金.
关键词:
镍基
,
高温合金
,
点蚀
,
电化学方法
,
腐蚀行为
林水东
,
丁马太
功能材料
用示差扫描量热法(DSC)考察了聚丙烯(PP)、聚丙烯/云母(PP/M)和聚丙烯/聚(丙烯-g-甲基丙烯酸甲酯)/云母复合材料(PP/PP-g-MMA/M)的非等温结晶过程.用Avrami方程和Ozawa方程对上述过程进行分析,n、t1/2、F(T)、Tp等参数表明,M和PP-g-MMA,特别是PP-g-MMA的掺入改变了PP的结晶成核和生长机理.用Dobreva方法分析填料的成核活性,ε数值表明,M有较强的成核活性,PP-g-MMA的掺入又进一步增强其成核活性,从而使结晶温度明显提高.Kissinger方法的计算结果表明,添加M可使PP的结晶活化能减小,再添加PP-g-MMA又使PP/M复合体系的结晶活化能进一步减小.
关键词:
聚丙烯
,
聚(丙烯-g-甲基丙烯酸甲酯)
,
云母
,
复合材料
,
非等温结晶动力学
Intermetallics
The phase transformation of alumina formed during oxidation of beta-NiAl coating prepared on M38G alloy by pack cementation was investigated. Oxidation experiments were conducted at 950 degrees C for various times from 2 to 180 min. The phase composition and microstructure of the oxide scales were investigated by using glancing angle XRD, AFM and SEM. The results showed that at the initial oxidation stage needle-like theta-Al2O3 was formed and then it covered the sample surface rapidly. The formation of alpha-Al2O3 grains beneath the theta-Al2O3 layer was favored by depletion of Al in the beta-NiAl coating during oxidation. alpha-Al2O3 preferred growing on the top (ridge) of beta-NiAl grains, which resulted in the formation of net-like alpha-Al2O3 inner layer. With increasing time, theta-Al2O3 transformed to alpha-Al2O3 gradually. After 180 min oxidation, most of alpha-Al2O3 grains transformed into alpha-Al2O3. A mechanism of excessive voids' formation at the oxide/coating interface was also proposed in this paper. (c) 2007 Elsevier Ltd. All rights reserved.
关键词:
nickel aluminides, based on NiAl;oxidation;phase transformations;coatings, intermetallic and otherwise;high-temperature oxidation;theta-alpha-al2o3 transformation;behavior;coatings;superalloy;transition;layers
Journal of Magnetism and Magnetic Materials
The electron paramagnetic resonance g factors g(parallel to) and g(perpendicular to) for the trigonal Er3+-V-K centers (where V-K denotes K+ vacancy) in KMF3 (M = Mg and Zn) are theoretically investigated from the perturbation formulas of the g factors for a 4f(11) ion in trigonal symmetry. In these formulas, the contributions to the g factors from the second-order perturbation terms and the admixture of various energy levels are taken into account. In the above trigonal centers, the impurity Er3+ resides in the octahedral M2+ site of both crystals, associated with one V-K in the C-3-axis due to charge compensation. By analyzing their g factors, we find that the impurity Er3+ in both centers would move towards the V-K by an amount DeltaZ along the C-3-axis due to electrostatic attraction. The calculated g factors for the Er3+ centers based on the above displacements DeltaZ show good agreement with the observed values. The validity of the results is discussed. (C) 2004 Elsevier B.V. All rights reserved.
关键词:
electron paramagnetic resonance (EPR);defects and impurities;crystal-field and spin hamiltonians;Er3+;KMF3;(M = Mg and Zn);crystal-field;superposition-model;perovskite kmgf3;conversion;parameters;fluorides;kznf3
蒋彦龙
,
陈国邦
,
甘智华
,
低温物理学报
doi:10.3969/j.issn.1000-3258.2004.02.006
本文开展了高性能G-M型单级脉管制冷机直流抑制和制冷特性实验研究.考察了直流流动对制冷机性能的影响,采用并联布置的双阀逆向型进气结构对直流进行抑制,成功地解决了脉管制冷机的直流问题;此外,深入研究了不同工作模式下,回热器填料布置方式对制冷特性的影响;估算了不同温度位下制冷循环的需气量,对不同压缩机输入功下的双向进气脉管制冷性能进行了研究,采用2kW(RW2)和4kW(CP4000)压缩机驱动时分别获得了18.4K和14.7K的最低制冷温度,在30K的相应制冷量分别为11.5W和29.5W.
关键词:
高性能
,
脉冲制冷机
,
直流
田磊
,
敖青
,
刘玉爱
,
李胜利
材料热处理学报
通过控制热处理参数在G55SiMoV钢中获得了不同贝氏体含量的马氏体/贝氏体复相组织,研究了贝氏体含量对其韧性和回火脆性的影响.结果表明:随等温时间延长贝氏体含量增加,等温淬火5 min、15 min、30 min、60 min可分别获得17％、27％、29％、31％的贝氏体.当贝氏体量较多(大于27％)时,马氏体对贝氏体的应变强化效果降低,韧性提高更加显著.300℃以下回火时组织和硬度基本不变;300℃回火时存在回火脆性,该马氏体/贝氏体复合组织钢的回火脆性温度区间几乎不受贝氏体量的影响,但增加贝氏体量可以提高残留奥氏体稳定性,使韧性降幅减小.
关键词:
马氏体/贝氏体复相组织
,
贝氏体含量
,
回火脆性
,
残留奥氏体稳定性
,
韧性
李杰
,
曾潮流
腐蚀学报（英文）
采用电化学阻抗技术研究了涂有Na2SO4-K2SO4盐膜的纯Ni和Ni基高温合金M38G在900℃，空气气氛中的热腐蚀行为.结果表明，纯Ni发生快速腐蚀，其腐蚀电化学阻抗谱 呈典型的扩散控制反应的特征；M38G合金在热腐蚀过程中由于形成了具有较好保护性的腐蚀产物层，其腐蚀电化学阻抗谱呈双容抗弧特征.提出了等效电路来解析电化学阻抗谱，并探讨了材料的腐蚀过程.
关键词:
Ni基合金
,
null
,
null
