Hao GUO
,
Guangfu LI
,
Xun CAI
,
Jianjiang ZHOU
,
Wu YANG
材料科学技术（英文）
The stress corrosion cracking (SCC) behaviour of X-70 pipeline steel in near-neutral pH solutions was studied $via$ slow strain rate testing (SSRT). The results showed that the cracking mode of X-70 pipeline steel in near-neutral pH solutions was transgranular at different temperatures and applied potentials with the feature of quasi-cleavage. The pH value of the solution decreased with increasing the addition of CO¬2, which increased the susceptibility to SCC. SCC susceptibility increased as the applied potential moved towards the cathodic direction, suggesting that hydrogen induced cracking (HIC) dominated the cracking process at cathodic potentials. The slight decrease of pH values with decreasing temperature of the solution increased the susceptibility to SCC, which attributed to the change of solubility of CO¬2 in the solution at different temperatures. The propagating directions of SCC cracks were different at different potentials. At rather negative cathodic potentials, the cracks were almost perpendicular to the tensile axis, while at free corrosion potential and near anodic potentials, cracks were nearly at 45 degree, and in the range of moderate cathodic potentials both propagating directions could be observed.
关键词:
Pipeline steel
,
null
,
null
,
null
Hao GUO
,
Guangfu LI
,
Xun CAI
,
Ruipeng YANG
,
Wu YANG
材料科学技术（英文）
The cracking behaviour of X-70 pipeline steel in near-neutral pH solutions was studied under different modes of cyclic loading. The crack propagation process of X-70 pipeline steel under low frequency cyclic loading condition was controlled mainly by stress corrosion cracking (SCC) mechanism. Under mixed-mode cyclic loading, both higher tensile stress and shear stress made cracks easier to propagate. Applied cathodic potentials and high content of carbon dioxide in solutions also promoted the propagation of cracks. The propagation directions of cracks were different under different cyclic loading conditions. Under mode I (pure tensile stress) cyclic loading condition, cracks were straight and perpendicular to the tensile stress axis, while under mixed-mode I/III (tensile/shear stress) cyclic loading, cracks were sinuous and did not propagate in the direction perpendicular to the main tensile stress axis. Under the mixed-mode cyclic loading, cracks were much easier to propagate, suggesting that shear stress intensified the role of tensile stress. In addition, shear stress promoted the interaction between cracks, resulting in easier coalescence of cracks.
关键词:
Pipeline steel
,
null
,
null
,
null
李志宏
,
柳卫平
,
白希祥
,
郭冰
,
连钢
,
颜胜权
,
王宝祥
,
陆昀
,
曾晟
,
苏俊
原子核物理评论
doi:10.3969/j.issn.1007-4627.2005.01.006
利用8Li次级束测量了质心系能量7.8 MeV 2H(8Li, 9Li)1H反应的角分布, 导出了8Li(d, p)9Li反应的天体物理S因子及9Li→8Li+n虚衰变的渐近归一化系数.
关键词:
8Li(d,p)9Li反应
,
角分布
,
天体物理S因子
,
渐近归一化系数
HUANG Jianshun CHEN Junming Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai
,
China Research Associate
,
Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai 200050
,
China
金属学报(英文版)
Crystal structure of γ-Li_xFe_2O_3,inserted Li electrochemically,was studied by Moss- bauer spectroscopy together with X-ray diffraction,XPS and electrochemical method,On the insertion of Li at low current density,the crystal structure is keeping original spinel; while at higher current density or by thermal activation,owing to violent movement of Li~+ ions,part of crystal structure transforms into rock type similar to face-centered cubic structure of ferrous oxide.The transition channels during insertion of Li~+ ions and limitation of Li~+ ions inserted were discussed.
关键词:
null
,
null
,
null
Journal of Materials Research
The effect of Li(3)N additive on the Li-Mg-N-H system was examined with respect to the reversible dehydrogenation performance. Screening Study with varying Li(3)N additions (5, 10, 20, and 30 mol%) demonstrates that all are effective for improving the hydrogen desorption capacity. Optimally, incorporation of 10 mol% Li(3)N improves the practical capacity from 3.9 wt% to approximately 4.7 wt% hydrogen at 200 degrees C, which drives the dehydrogenation reaction toward completion. Moreover, the capacity enhancement persists well over 10 de-/rehydrogenation cycles. Systematic x-ray diffraction examinations indicate that Li(3)N additive transforms into LiNH(2) and LiH phases and remains during hydrogen cycling. Combined structure/property investigations suggest that the LiNH(2) "seeding" should be responsible for the capacity enhancement, which reduces the kinetic barrier associated with the nucleation of intermediate LiNH(2). In addition, the concurrent incorporation of LiH is effective for mitigating the ammonia release.
关键词:
complex hydrides;improvement;mixtures;imides;amide;h-2
MANG Weishi WANG Guozhi ZHANG Yongchang HU Zhuangqi SHI Changxu Institute of Metal Research
,
Academia Sinica
,
Shenyang
,
China Yongchang Associate Professor
,
Institute of Metal Research
,
Academia Sinica
,
Shenyang 110015
,
China
金属学报(英文版)
A rapidly solidified microcrystalline Al-Li-Cu-Mg-Zr alloy and its superplasicity have been investigated.An optimum tensile elongation of 585% was obtained at 540℃ and strain rate 1.67×10~(-2)s~(-1).The superplastic Al-Li alloy is manufaetured using thermomechanical pro- cessing:solution,overaging,warm rolling and recrystallization.Microstructural changes in thermomechanical processing and cavitation occurred during superplastic deformation have been observed.The superplastic failure of alloy may be caused mainly by nucleation and growth of cavities as well as the linkage around grains.
关键词:
superplasticity
,
null
,
null
,
null
Zhijian LIU
,
Zhiyou LI
,
Wei DUAN
,
Xuanhui QU
,
Baiyun HUANG
,
Siqi ZHANG
材料科学技术（英文）
A LI-B alloy has been prepared using a pretreated amorphous B powder and pure Li ingot as starting materials by continually slow addition of B powder and intensified stirring in the process of melting. The microstructure and the discharge characteristic of the materials have been investigated. Results show that the problem of temperature control in synthesis would be modified by means of continual addition of B powder, the Li7B6 would be more finery distributed in the metal Li by means of intensified stirring. The discharge characteristic of the Li-B alloy using amorphous B as starting materials is almost the same with that of using crystalline B.
关键词:
