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SINTERING BEHAVIOR OF Cu-AI ALLOY POWDER

TIAN Sugui , SHAO Huimeng , ZHOU Longjiang , LI Tiefan , YANG Hongcai , HAO Shiming(Shenyang Polytechnic University , China) (State Key Laboratory of Corrosion and Protection. Institute of Corrosion and Protection of Metals. Chinese Academy of Sciences , Shenyang)(Northeastern University. Shenyang.China) Manuscript received 1 March 1995

金属学报(英文版)

The dynamic behaviour of transient liquid phase during sintering 5wt% Al-Cu alloy compacts with green density of 7.56g/cn~3 is observed by means of high temperature metallographic microscopy. The structures and precipitating order of the phases are identified by means of DTA, TEM and composion analysis at the definite point and phase diagram. The results show that little Al-rich liquid phase resulting from eutectic reaction flows into the capillaries in Cu powder, because the peritectic reactions exhausts the liquid in high density compact,the composition homogenization needs longer sintering time. The remainder γ2-phase is discovered at place of the neck of sintered Cu particle and has a crystallographic relationship of (111)_(Cu)∥(033)_γ_2 after alloy is sintered at 900 ℃for 3h.

关键词: :transient liquid phase sintering , null , null

The effect of environmental variables on atmospheric corrosion of carbon steel in Shenyang

Chinese Science Bulletin

A study was carried out in order to investigate the effect of contaminants and meteorological variables on the rust layer of carbon steel exposed in Shenyang urban atmosphere. Seven kinds of contaminants and twelve kinds of meteorological parameters were also registered in order to correlate the data with respect to corrosion rate and the stepwise multiple regression analysis was carried out in order to obtain the best regression model. The sum of rainfall time as well as sunshine time and the concentration of H(2)S could stimulate initial atmospheric corrosion of carbon steel. The initial atmospheric corrosion kinetics of carbon steel was observed to follow the cubic equation. The corrosion products were analyzed by XRD and the transformation of phases in different periods was discussed.

关键词: contaminants;meteorological parameters;carbon steel;urban atmospheric;corrosion;stepwise multiple regression;corrosion products;rust;pollution

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