P. He
,
J. H. Zhang
,
J. C. Feng and Y. Y. Qian (National Key Laboratory of Advanced Welding Production Technology
,
HIT
,
Harbin 150001
,
China)
金属学报(英文版)
TiAl was diffusion bonded to Ti and TC4 alloy in vacuum furnace. Results showed,at the TiAl-Ti interface,the reaction layer of stratification Ti3Al was formed closest to TiAl base,and the a phase and the α + βphase arised closest to Ti base at 1173K and 1573K respectively. The phase structure of TiAl/ and the phase structure of TiAlwere observed be- tween AiAl and TC4 under respetive bonding temperature.The fiacture at tensile testing occurred in the bond - line, producing very flat fracture surfaces with some pull-out of the TiAl materials.The ultimate tensile strengths of the joint were approximate to γ-TiAl base marterial.
关键词:
diffusion bonding
,
null
,
null
Journal of Materials Research
Based on the best bulk metallic glass (BMG) forming alloy in the Mg-Cu-Y ternary system, we introduced Ag (or Ni) to partially substitute for Cu to improve the glass-forming ability (GFA). The objective of this paper is twofold. First, we illustrate in detail a recently developed search strategy, which was proposed but only briefly outlined in our previous publication [H. Ma, L.L. Shi, J. Xu, Y. Li, and E. Ma: Discovering inch-diameter metallic glasses in three-dimensional composition space. Appl. Phys. Lett. 87, 181915 (2005)]. The protocol to navigate in three-dimensional composition space to land large BMGs is spelled out step-by-step using the pseudo-ternary Mg-(Cu,Ag)-Y as the model system. Second, our ability to locate the best BMG former in the composition tetrahedron allows us to systematically examine, and conclude on, the effects of a given alloying element. The large improvement in glass-forming ability in the Mg-(Cu,Ag)-Y system relative to the based ternary will be contrasted with the reduced glass-forming ability in the Mg-(Cu,Ni)-Y pseudo ternary system. It is demonstrated that the improvement of glass-forming ability requires judicious choice of substitutional alloying elements and concentrations, rather than simple additions of multiple elements assuming the "confusion principle."
关键词:
bulk metallic-glass;shaped copper mold;amorphous-alloys;thermal-stability;ternary-system;casting method;p system;diameter;zr;mm
材料科学技术（英文）
The corrosion of an Fe-based alloy containing 15 wt pet Y in H-2-H2S mixtures under 10(-3) Pa S-2 was studied at 600 similar to 800 degrees C in an attempt to find materials with improved sulphidation resistance with respect to pure Fe. The presence of Y has been shown to be beneficial, but not sufficient to the level expected. In fact, the alloy is able to form at all tested temperatures an external FeS layer, beneath which a zone containing a mixture of the two sulphides is also present. Thus, Fe can still diffuse through this region to form the outer FeS layer with non-negligible rate. The corrosion rate of Fe is considerably reduced by the Y addition, but the alloy corrodes still much more rapidly than Y. The sulphidation kinetics is generally rather irregular for both the pure metals, while the corrosion rate of the alloy decreases with time and tends to become parabolic after an initial period of 12 similar to 17 h. The sulphidation behaviour of the alloys is discussed by taking into account the presence of an intermetallic compound Fe17Y2 and the limited solubility of Y in Fe.
关键词:
high-temperature sulfidation;most-reactive component;ni-nb alloys;h2-h2s mixtures;behavior;600-degrees-c-800-degrees-c;oxidation
Transactions of Nonferrous Metals Society of China
The influence of Zr and Y on the cast microstructure of a nickel-based superalloy was investigated by optical microscopy (OM), scanning electron microscopy(SEM), electron probe micro-analysis (EPMA) and X-ray diffraction (XRD). The gamma+gamma' eutectic volume in the superalloy rises notably with the increase of Zr or Y content. Meanwhile, the morphologies of primary MC carbides change from needle and platelet-like to blocky shape with increasing Zr and Y doped. The XRD results show that the primary MC carbide lattice constant increases with Zr and Y additions, and EPMA investigation shows that the platelet-like MC carbides contain primarily Nb and C, while those carbides in blocky shape have 39.2% Zr and 39.6% Nb in average,. These influences on the cast microstructure can be attributed to the atomic size effects of Zr and Y.
关键词:
yttrium;zirconium;carbides;nickel based superalloys;microstructure;solidification;carbide morphology;mechanical-properties;boron;ni3al;yttrium;sulfur
C.G.Shi
,
Y.H.Wang
,
L.G.Cai
,
C.H.Zhou
金属学报(英文版)
There are four new achievements of this work on the theory and technology of explosive welding.(1) It has been found and defined three kinds of bonding interfaces: big wavy, small wavy and micro wavy, and the micro wavy interface is the best. In a cladding plate,it is for the first time to find that the form of interface presents regular distribution.(2) Although the interface has the features of melt, diffusion and pressure welding in the mean time, the seam and "hole" brought by the melt weaken the bonding strength of interface greatly, and the effect of melt on interface must be eliminated in explosive welding, so explosive welding is not a melt weld. The diffusion welding is a kind of form of pressure welding, and the diffusion is not the reason of the bonding of interface but the result of interface high pressure. So the diffusion welding cannot also explain the bonding mechanism of it. The experiment and theory make clear that explosive welding is a special pressure one.(3) To get good interface of no melt, explosive charge must be selected on the low limit of welding windows. In explosive welding, the drive plate should be treated as the viscous and plastoelastic body, not incompressible fluid. The bending moment under the explosive welding loading must be greater than that under dynamic limit of drive plate. According to the condition, the lower limit of explosive welding is obtained. It is about 20 1.019373e-312ss than that obtained by tradition calculation, and suitable for engineering application.(3) It is for the first time to test and study on soil anvil characteristics and change regularity under explosive welding impact loading. Through soil anvil parameter optimization analysis, it is the best for explosive welding with sandy soil of water content 17.00and density 1.74g/cm^3.
关键词:
explosive welding
,
null
,
null
马宏
,
彭晓东
,
谢卫东
腐蚀学报（英文）
利用对掺法熔铸镁合金AJ61+xY, 研究了合金中相的组成和分布及其在3.5%NaCl溶液中的腐蚀行为. 结果表明, 添加稀土Y使AJ61镁合金的晶粒明显细化,Mg17Al12 相的数量明显减少且由连续网状变成弥散颗粒状分布,沿晶界处生成耐蚀稀土相Al2Y、Al3Y, AJ61镁合金的耐腐蚀性得到明显改善. 耐腐蚀性顺序为:AJ61+1.5%Y>AJ61+2.0%Y>AJ61+1.0%Y>AJ61+0.5%Y.
关键词:
Mg-6Al-1Sr 镁合金
,
yttrium
,
microstructure
,
corrosion resistance
马宏
,
彭晓东
,
谢卫东
腐蚀学报（英文）
利用对掺法熔铸镁合金AJ61++xY,研究了合金中相的组成和分布及其在3.5%NaCl溶液中的腐蚀行为.结果表明,添加稀土Y使AJ61镁合金的晶粒明显细化,Mg17Al12相的数量明显减少且由连续网状变成弥散颗粒状分布,沿晶界处生成耐蚀稀土相Al2Y、Al3Y,AJ61镁合金的耐腐蚀性得到明显改善.耐腐蚀性顺序为:AJ61+1.5%Y＞AJ61+2.0%Y＞AJ61+1.0%Y＞AJ61+0.5%Y.
关键词:
Mg-6Al-1Sr镁合金
,
钇
,
显微组织
,
耐腐蚀
Yan NIU
,
Weitao WU and Chaoliu ZENG (State Key Lab. for Corrosion and Protection
,
Institute of Corrosion and Protection of Metals
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)F. Gesmundo and F. Viani (Instituto di Chimica
,
Facolta di Ingegneria
,
Un
材料科学技术（英文）
The corrosion of an Fe-based alloy containing 15 wt pct Y in H2-H2S mixtures under 10-3 Pa S2 was studied at 600~800℃ in an attempt to find materials with improved sulphidation resistance with respect to pure Fe. The presence of Y has been shown to be beneflcial, but not sufficient to the level expected. In fact, the alloy is able to form at all tested temperatures an external FeS layer, beneath which a zone containing a mixture of the two sulphides is also present. Thus,Fe can still diffuse through this region to form the outer FeS layer with non-negligible rate. The corrosion rate of Fe is considerably reduced by the Y addition. but the alloy corrodes still much more rapidly than Y. The sulphidation kinetics is generally rather irregular for both the pure metals, while the corrosion rate of the alloy decreases with time and tends to become parabolic after an initial period of 12~17 h. The sulphidation behaviour of the alloys is discussed by taking into account the presence of an intermetallic compound Fe17Y2 and the limited solubility of Y in Fe
关键词:
Zhihua LIU
,
Qing ZHAO
,
Deqing LI
材料科学技术（英文）
In this paper, technology margin experiment of hollow cathode fusion are welding (FAW) and penetrating are welding (PAW) is presented in detail. The advantages of PAW, compared with FAW, are better weld formation, narrower welds, as well as a larger welding technology margin. Technological experiment and hydraulic test for the Ti alloy pressure vessels with PAW are described. Also, the weld formation control on Ti alloys is preliminarily analyzed. Finally, conclusions are addressed.
关键词:
Intermetallics
The cyclic oxidation behavior of a magnetron sputtered NiAl microcrystalline coating was investigated at 1000 degreesC in air by TGA, and SEM in comparison with cast NiAl and NiAlY alloys. Results indicate that, for the cast NiAl alloy, mass loss is observed at about 40 cycles, implying the serious spallation occurred, while no spallation is detected for NiAlY alloy and NiAl coating for the whole test period. It is evident that. the scale adhesion is improved by the microcrystallization and the addition of Y. (C) 2001 Elsevier Science Ltd. All rights reserved.
关键词:
nickel aluminides;based on NiAl;scale adhesion;al2o3 scales;oxide scale;segregation;alpha-al2o3;morphology;mechanism;growth
