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EVOLUTION OF THE ELECTROCHEMICAL CHARACTERISTICS DURING PITTING CORROSION OF PURE ALUMINUM IN SODIUM CHLORIDE SOLUTION

Z. Zhang , C. Cai , F.H. Cao , Z.N. Gao , J.Q. Zhang , C.N. Cao

金属学报(英文版)

The corrosion behavior of pure aluminum in neutral 3.0% (mass fraction) sodium chloride (NaCl) solution has been studied using electrochemical impedance spectroscopy (EIS) measurement in conjunction with the scanning electron microscopy (SEM) technique. EIS information on the evolution of pitting corrosion over a period of 15 days has been obtained and analyzed with equivalent circuit technique. The results shown that, during the ensemble constant immersion time, two time constants involved, the high frequency one originated from the protective layer on the corroding surface while the low frequency one from the diffusion process or the corrosion reaction and so on. And there existed a period for oxide film to growth and thickening prior to the commencement of the attacking of chloride ions to the substrate. Meanwhile, good relationship between EIS and the material corrosion type / severity has been obtained, which has been interpreted according to the characteristics of corrosion process such as auto acceleration of pitting corrosion and the protection of local anodic reaction to the area around them.

关键词: pure aluminum , null , null

J积分法测定Q345断裂韧性及失效评定曲线

李亚宁 , 董保胜 , 赵新伟 , 罗金恒 , 周根树 , 郑茂盛

钢铁研究 doi:10.3969/j.issn.1001-1447.2006.03.010

Q345是广泛使用的一种普通低合金钢,其断裂韧性是工程中进行裂纹检测的重要参数.应用J积分法测定了Q345的断裂韧性,并采用R6方法中的选择3曲线和通用曲线绘制了其失效评定曲线.研究发现:所有试样断口均有充分张开的大分层现象,它的存在阻碍了断口沿厚度方向的收缩,从而增加了材料的断裂韧性值.给出了适合Q345特性的失效评定曲线,以便为工程应用提供依据.

关键词: Q345 , J积分 , 断裂韧性 , 失效评估曲线

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

Spin waves in a four-sublattice Heisenberg ferrimagnet or ferromagnet with different exchange constants (J(ab)=J(cd)not equal J(bc)=J(da))

Physical Review B

The Hamiltonian for a four-sublattice Heisenberg ferrimagnet or ferromagnet with different exchange constants (J(ab) = J(cd) not equal J(bc) = J(da)) was established. An extended Bogoliubov transformation was developed by solving an equation group, consisting of 20 equations and 20 unknowns. The procedure for solving the equation group was carried out by introducing a simple way of reducing the numbers of the equations and the unknowns. The spin-wave spectra in the present system have been determined by performing the standard Holstein-Primakoff transformation and the Bogoliubov one. It has been found that the spin-wave spectra of the present system depend on the exchange constants and that the degeneracy of the spin-wave spectra remains. The results for a special case (J(ab) = J(bc)) i.e., an antiferromagnet are discussed briefly. The spin-wave spectra of the four-sublattice Heisenberg antiferromagnet are found to be degenerative also and they are linear in k for small k.

关键词: model

高分子专利j

高分子材料科学与工程

专利名称:具有改进的抗冲击性、尺寸稳定性和吹塑成形性能的热塑性ABS树脂组合物专利申请号:CN200580040787.3公开号:CN101065413申请日:2005.03.31公开日:2007.10.31申请人j韩国第一毛织株式会社根据本发明的热塑性ABS树脂组合物包括:(a)2

关键词: 专利名称 , 高分子 , 树脂组合物 , 专利申请号 , 尺寸稳定性 , 抗冲击性 , 株式会社 , 成形性能

Study on the Relationship Between J-Integral and COD

Y.G. Cao , X.Y. Sun

金属学报(英文版)

J-integral and crack opening displacement δ(COD) were important parameters for characterization of fractures in engineering materials. The relationship between J-integral and COD has been investigated for a long time and was enerally represented as J = m σyδ, where σy is the yield strength and m is a function of specimen geometry and material properties. To determine the value of m, extensive studies and experiments have been performed. The method that used the fracture-surface topography analysis (FRASTA) for determining J-integral from fracture surfaces of materials was introduced. On the basis of the relationship between COD and fracture surface average profile, the relationship between J-integral and COD was deduced and compared with the generally used equation. The method was experimentally confirmed to be able to provide a new way to determine the relationship between J-integral and COD.

关键词: FRASTA , null , null

S355J2W耐候钢的耐腐蚀性能

鲁二敬 , 卢峰华 , 许鸿吉 , 谢明 , 钮旭晶

机械工程材料

通过周期浸润腐蚀试验,对比研究了S355.12W耐候钢和Q345R低合金钢在NariSOs溶液中的耐腐蚀性能,并用扫描电镜对腐蚀产物进行了观察和分析。结果表明:在相同试验条件下,S355J2W耐候钢的腐蚀速率低于Q345R钢的;S355J2W耐候钢会在表面形成黑褐色锈层,而Q345R钢表面形成橘红色易剥落的疏松锈层;S355J2W耐候钢腐蚀产物微观形貌为沿放射性方向生长的针状晶体,Q345R钢为颗粒状聚合物堆积而成,形状无规则,颗粒之间有较大的空隙。

关键词: S355J2W耐候钢 , 周期浸润腐蚀试验 , 耐腐蚀性能

浅析CTOD和J积分的关系

周峰峦 , 郭震

物理测试 doi:10.13228/j.boyuan.issn1001-0777.20160084

推导了CTOD和J积分的关系,并且从试验角度利用三点弯曲试样进行CTOD试验,根据ASTM E1820对GB/T 21143-2014中公式34进行了评价,研究表明,在小屈服范围内,采用裂纹嘴张开位移可以同时得到CTOD和J积分,从而可以简化J积分的试验装置.

关键词: J积分 , CTOD , 小屈服

悬臂弯曲方法测定J_(Ic)和J_(Iscc)的探讨

null , null

金属学报

在工程上,经常由于应力腐蚀开裂和氢脆引起中强度钢结构件发生滞后破坏。这类脆断往往从结构件中预先存在的疲劳或焊接裂纹处开始,因此,运用传统的光滑试样的检验方法不能反映这类破坏的特点。 本文将弹塑性断裂力学中的J积分概念用于滞后破坏的研究,提出用带预制疲劳裂纹的悬臂弯曲试样测定J积分的临界值J_(Ic)和应力腐蚀开裂阈值J_(Iscc)的方法。测定了40CrNiMo钢的J_(Ic)值及其在硫化氢水溶液中的J_(Iscc)值。通过和三点弯曲方法测定的J_(Ic)值的对比,以及和满足线弹性条件时直接测定的应力强度因子K_I值的对比,说明这种方法的可靠性。最后,对悬臂弯曲方法的特点进行了讨论。

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