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Gaseous Nitriding Process of Surface Nanocrystallized (SNCed) Steel

Duohui BEI , Jianfeng GU , Jiansheng PAN , Jian Leür , Ke LU

材料科学技术(英文)

The behavior of gaseous nitriding on the surface nanocrystallized (SNCed) steel was investigated.The mild steel discs were SNCed on one side by using the method of ultrasonic shot peening. The opposite side of the discs maintained the original coarse-grained condition. The gaseous nitriding was subsequently carried out at three different temperatures: 460,500 and 560°C. The compound layer growth and diffusion behavior were then studied. It was revealed that SNC pretreatment greatly enhances both diffusion coefficient D and surface reaction rate. As a result, nitriding time could be reduced to the half.It was also found that the growth of compound layer with nitriding time conformed with parabolic relationship from the start of nitriding process in the SNCed samples.

关键词: Nitriding process , null , null

Effect of Doping and High-Temperature Annealing on the Structural and Electrical Properties of Zn1-XNiXO(0≤X≤0.15) Powders

Hakan Colak

材料科学技术(英文)

This paper reported the synthesis, crystal structure and electrical conductivity properties of Ni-doped ZnO powders (i.e. Zn1-XNiXObinary system, X=0, 0.0025, 0.005, 0.0075 and in the range 0.01≤X≤0.15). I-phase samples, which were indexed as single phase with a hexagonal (wurtzite) structure in the Zn1-XNiXObinary system, were determined by X-ray diffraction (XRD). The widest range of the I-phase was determined as 0≤X≤0.03 at 1200°C; above this range the mixed phase was observed. The impurity phase was determined as NiO when compared with standard XRD data, using the PDF program. We focused on single I-phase ZnO samples which were synthesized at 1200°C because of the widest range of solubility limit at this temperature. It was observed that the lattice parameters a and c of the I-phase decreased with Ni doping concentration. The morphology of the I-phase samples was analyzed with a scanning electron microscope. The electrical conductivity of the pure ZnO and single I-phase samples were studied by using the four-probe dc method at temperatures between 100 and 950°C in air atmosphere. The electrical conductivity values of pure ZnO and 3 mol% Ni-doped ZnO samples at 100°C were 2×10-6 and 4.8×10-6Ω-1?cm-1, and at 950°C they were 1.8 and 3.6Ω-1?cm-1, respectively. In other words, electrical conductivity increased with Ni doping concentration.

关键词: II-VI semiconductors

Acoustic emission inspection of Portevin-Le Chatelier effect and deformation mechanisms of two Mg-Li-Al alloys

Journal of Materials Science

In this paper, Portevin-Le Chatelier (PLC) effect of LA41 magnesium alloy is reported. With increasing strain rate, both ultimate tensile stresses (sigma(b)) and 0.2% proof (sigma(0.2)) stresses increase, while serrations become less severe. Major acoustic emission (AE) peaks appear at the end of elastic region, and transform to burst type signals in the plastic range. In another alloy containing less Li (LA11), serrations are absent and major AE peak values are considerably lowered. Additionally, PLC effect disappears in LA41 after annealing. The role of twins is discussed in details. Actual causes for AE activity during deformation are also proposed.

关键词: tensile deformation;magnesium alloys;bands;az31

R-line thermal shift and thermal broadenings of R, R' and B lines for ruby

Communications in Theoretical Physics

The unified theoretical calculation of thermal shifts (TS) of R-1 and R-2 lines and thermal broadenings (TB) of R, R' and B lines for ruby was carried out for the first time. The calculated results are in very good agreement with a great number of experimental data. Especially by using quantum theory and taking into account all the admixtures of wavefunctions within d(3) electronic configuration, all the Gamma M in electron-phonon interaction (EPI), the electronic energy spectrum and lattice-vibration Spectrum, the very important contributions to TS and TB from single-phonon direct process were theoretically calculated in detail. The microscopic essentials of various contributions are revealed, and the mistakes in previous work are remedied.

关键词: diamond anvil cell;pressure measurement;spectroscopy;temperatures

Theoretical calculations of thermal broadenings and transition probabilities of R, R ' and B line-groups for ruby

Communications in Theoretical Physics

On the basis of the unified calculation of the thermal shifts of R-1 line, R-2 line and ground-state-splitting as well as the thermal broadenings of R, R' and B line-groups for ruby, by taking into account all the levels and admixtures of wavefunctions within d(3) electronic configuration and all the GammaM in electron-phonon interaction, the transition probabilities of direct and Raman processes have theoretically been calculated. The thermal broadenings, of R, R' and B line-groups have successfully been interpreted in terms of the direct and Raman processes of acoustic phonons. The theoretically predicted transition probabilities are in good agreement with the experimental ones.

关键词: crystal fields;electron-phonon interaction;thermal broadening;transition probability;direct and Raman processes;shifts

Phase diagram of R-Fe-Co pseudoternary system with R <= 33.3% (mole fraction, R = Sm0.5Dy0.5)

Transactions of Nonferrous Metals Society of China

Phase equilibria of the R-Fe-Co pseudoternary system with R less than or equal to 33.3% ( mole fraction, R = Sm0.5Dy0.5) were determined in an isothermal section at 1073 K and a vertical section of RFe2-RCo2 by using OM, X-ray diffractometer, EP-MA DTA techniques. There are seven intermetallic phases: (Sm, Dy) (Fe, Co)(2), (Sm, Dy) (Fe, Co)(3), (Sm, Dy)(6) (Fe, Co)(23), (Sm, Dy)(2) (Fe, Co)(7), (Sm, Dy) (Fe, Co)(5), Th2Ni17-type and Th2Zn17-type (Sm, Dy)(2)(Fe, Co)(17). The (Sm, Dy)(6)(Fe, Co)(23) phase dissolves 36% Co(mole fraction) at 1073 K. However, the (Sm, Dy)(2)(Fe, Co)(7) phase in R-2(Fe1-xCox)(7) alloys dissolves about 19% Fe(mole fraction) at 1073 K.

关键词: rare earth-iron-cobalt;phase diagram;structure;compounds;sm-co;magnetic-properties;binary-system;magnetostriction

SPIN REORIENTATION AND EXCHANGE INTERACTIONS IN (ND, R)2FE14B (R = Y, GD)

Journal of Magnetism and Magnetic Materials

Exchange fields in both (Nd, Y)2Fe14B and (Nd, Gd)2Fe14B series are determined by analyzing spin reorientation. Results calculated for the two systems suggest that the R-R exchange interactions between R ions are comparable with the crystal-field interaction and that their effect might be taken into account for reproducing the spin-reorientation temperature.

关键词: magnetization process;crystal;nd2fe14b;r2fe14b;transition

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