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Corrosion Behavior and Protection Efficiency of 2024Al and SiCp2024Al Metal Matrix Composite

Chunlin HE , Changsheng LIU , Fengqin LI , Qingkui CAI , Zhiming SHI , Liqing CHEN , Jing BI

材料科学技术(英文)

The corrosion resistance of 2024 Al and SiC particle reinforced 2024 Al metal matrix composite (SiCp/2024Al MMC) in 3.5% NaCl solution was investigated with electrochemical method and immersion test, and the corrosion protection of sulfuric acid anodized coatings on both materials was evaluated by electrochemical impedance spectroscopy. The results showed that the SiCp/2024Al MMC is more susceptible to corrosion than its matrix alloy in 3.5% NaCl. For 2024Al, the anodized coating provides excellent corrosion resistance to 3.5% NaCl.The anodized coating on the SiCp/2024Al provides satisfactory corrosion protection, but it is not as effective as that for 2024Al because the structure of the anodized layer is affected by the SiC particulates.

关键词: 2024 Al , null , null , null

On the Strength of Silicon Carbide Particulate Reinforced Aluminium Alloy Matrix Composites

Mingjiu ZHAO , Yue LIU , Liqing CHEN , Jing BI

材料科学技术(英文)

In the present study, the modified continuum model, quench strengthening and dislocation pile-up model was respectively used to estimate the yield strength of SiCp/Al composites. The experimental results showed that the modified shear lag model or quench strengthening model would underestimate the yield strength of SiCp/Al composites. However, the modified Hall-Petch correlation on the basis of the dislocation pile-up model, expressed as σcy = 244 + 371λ-1/2, fitted very well with the experimental data, which indicated that the strength increase of SiCp/Al composites might be due to the direct blocking of dislocation motion by the particulate-matrix interface. Namely, the dislocation pile-up is the most possible strengthening mechanism for SiCp/Al composites.

关键词: Silicon carbide particulate , null , null , null

Corrosion Behavior of SiCp/2024 Al Matrix Composites in 3.5 wt pct Sodium Chloride

Chunlin HE , Changsheng LIU , Fengqin LI , Qingkui CAI Zhiming SHI , Liqing CHEN , Jing BI

材料科学技术(英文)

The influences of volume fraction and particle size of SiC particulate reinforcements on the corrosion characteristics of SiCp/2024 Al metal matrix composites in aerated 3.5 wt pct NaCl aqueous solution were investigated. The electrochemical behavior was investigated by potentiodynamic polarization and electrochemical impedance spectroscopy, the general corrosion behavior of the composites was studied further by immersion tests. The results showed that pitting susceptibility was about the same for the composites and the alloy. The corrosion potentials were also independent of SiC phase. The corrosion resistance for the composites decreased as the volume fraction increased or particle size decreased.

关键词: SiCp/2024Al matrix composites , null , null

Sn-Bi合金电镀

蔡积庆

表面技术 doi:10.3969/j.issn.1001-3660.2000.03.013

概述了Sn-Bi合金镀液,可以获得外观良好及合金组成稳定的Sn-Bi合金镀层.适用于印制板、电子元器件等的可焊性镀层,以取代传统含Pb的Sn-Pb合金镀层.

关键词: Sn-Bi合金 , 无Pb焊料镀层 , 添加剂

LIQUIDUS OF Ag-Cu-Bi SYSTEM

LIU Shuqi SUN Wenqing Deptrtment of Chemistry , Peking University , Beijing , China[Originally published in ACTA METALL SIN (CHINESE EDN) 24 (5) 1988 pp B376—B378 , received 8 September 1987]

金属学报(英文版)

The diagram of Ag-Cu-Bi system was constructed from the investigation of 12 internal sec- tions by DTA heating as well as cooling curves in an atmosphere of dry N_2.The composi- tion of ternary eutectic point melting at 258℃ lies in Ag(5.0)-Cu(0.5)-Bi(94.5) at.-%.The liquiduses of Ag-Cu,Ag-Bi and Cu-Bi binaries were reinvestigated.

关键词: Ag-Cu-Bi ternary system , null

Bi Layer Formation at the Anode Interface in Cu/Sn-58Bi/Cu Solder Joints with High Current Density

Hongwen He

材料科学技术(英文)

Bi layer formation in Cu/Sn{58Bi/Cu solder joints was investigated with different current densities and solder thickness. Uniform and continuous Bi layers were formed at the anode interface which indicated that Bi was the main diffusing species migrating from the cathode to the anode. The electromigration force and Joule heating took on the main driving forces for Bi diffusion and migration. In addition, two appearance types of  Bi layers, planar-type and groove-type, were found during current stressing. The morphology and thickness of Bi layers were affected by current density and current stressing time.

关键词: Bi layer formation , null , null , null

Bi含量对Al-Bi偏晶合金显微组织演变的影响

康智强 , 杨雪 , 冯国会 , 张林

材料研究学报 doi:10.11901/1005.3093.2016.227

结合数值模拟与实验研究了常规条件下Al-Bi偏晶合金难混溶区的凝固过程,分析了Bi含量对Al-Bi偏晶合金显微组织演变的影响.结果表明,成分为Al-10%Bi合金试样下部组织中富Bi液滴的平均直径和体积分数分别是成分为Al-5%Bi合金试样下部组织中富Bi液滴平均直径和体积分数的1.1倍和12.8倍,且Al-10%Bi合金试样下部聚集了大量的大尺寸富Bi液滴,其显微组织均匀性较差;成分为Al-5%Bi的合金试样中富Bi液滴的平均尺寸较小,显微组织较均匀;偏晶点成分的Al-3.4%Bi偏晶合金显微组织中无大尺寸富Bi液滴生成,显微组织均匀.分析表明,富Bi相含量的增加导致液滴受重力作用增强,加剧了难混溶区液-液相分离和分解的凝固行为,增大了富Bi液滴的尺寸和数量,液滴受到的Ostwald熟化和碰撞凝并的作用增强,促使大量的大尺寸富Bi液滴聚集在试样下部,加重了偏晶合金显微组织的宏观偏析.

关键词: 金属材料 , Al-Bi偏晶合金 , 合金成分 , 显微组织 , 重力迁移

Bi系带材性能研究

何砚发 , 吕朝阳 , 王金星

低温物理学报 doi:10.3969/j.issn.1000-3258.2003.z1.014

本文介绍一种能够迅速获得Bi系带材多种性能参数的方法.它采用计算机进行数据采集和控制,在不断改变外力和外场的同时,对样品施加缓慢变化的传输电流,从而连续测出样品在不同应变和外场下的临界电流.该方法可以方便地获得Bi系带材的应力-应变曲线,临界电流-应变曲线,外场-临界电流曲线,不同应变下的伏安特性曲线以及不同外场下的伏安特性曲线等.通过对几种带材性能的研究表明,该方法简单实用,数据可靠,可供广大材料研究者和材料应用研究人员使用.

关键词:

Mg_3Bi_2,Ca_3Bi_2,CaMg_2Bi_2及K_9Mg_6Bi_7的生成自由能

邹元爔

金属学报

<正> 鉛的去鉍可以用沉淀精炼的方法,用Ca,Mg,K等金属为沉淀剂,生成的金属間化合物有Mg_3Bi_2(s),Ca_3Bi_2(s),CaMg_2Bi_2(s)及K_9Mg_6Bi_7(s)等。本文目的是利用已有数据計算这些金属間化合物的标准生成自由能,以期对沉淀去鉍过程获得进一步的了解。 从Mg-Bi相图可見,在液相綫上Mg_3Bi_2(s)与熔液成平衡。因此,可以从Mg-Bi系的活度数据結合相图计算Mg_3Bi_2(s)的标准生成自由能,同样方法曾被用来計算InSb(s)的标准生成自由能。液相綫上的平衡可以用下式表示:

关键词:

SOLUBILITY CHARACTERISTICS OF GaAs IN Bi AND THEIR PHASE DIAGRAM

FENG Shuifu ZHO U Jicheng Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , China ZHOU Jicheng , Shanghai Institute of Metallurgy , Academia Sinica , Shanghai 200050 , China

金属学报(英文版)

A modified liquid phase epitaxy apparatus for semiconductor materials was used to measure the solubility of GaAs in Bi.Two phase diagrams rich in Bi under H_2 and N_2 atmospheres were obtained according to the results of measurement.A new phenomenon,in which the parameter Q value(quantity of GaAs dissolved in Bi in fixed time/saturation quantitu,of GaAs in Bi)was different from each other at various temperatures and there existed a maxi- mum Q value at definite temperature,was observed.This phenomenon may be regarded as a common feature of a simple binary metallic system which has the phase diagram similar to that of Bi-GaAs.The difference observed from the dependence of Q values on temperature in both H_2 and N_2 atmospheres was discussed.

关键词: solubility , null , null

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