XU Dongsheng
,
SONG Yan
,
LI Dong
,
HU Zhuangqi(Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang
,
China)(Northeastern University
,
Shenyang
,
China)
金属学报(英文版)
A method based on electronic structure calculation is proposed to predict the substitution behavior of elements in ordered intermetallics. The electronic structure of 20 alloying elements in TiAl is calculated using the DV-Xα cluster method The bond orders between alloying elements and surrounding atoms, Bo_Ti,Bo_Al, are used as parameters. Two lines on the Bo_Ti-Bo_Al diagram separate the elements into three groups. The elements located outside of the two lines substitute either Ti or Al atom regardless of the composition of TiAl. The substitution behavior of elements between the two lines will be affected by the Ti/Al ratio and the amount of alloying elements added Substituting sequence in multi-element alloy is discussed The prediction based on this method agrees well with the experimental results.
关键词:
: substitution behavior; site occupancy; intermetallic compound
,
null
LI Geping
,
GUAN Shaoxuan
,
WANG Qingjiang
,
LIU Yuyin
,
LI Dong
,
HU Zhuangqi (Institute of Metal Researeh
,
Chinese Academy of Sciences
,
Shenyang
,
China Manuscript received 23 January. 1995)
金属学报(英文版)
The morphologies of the Nd-rich phase particles in the Ti-5Al-4Sn-2Zn -1Mo-0.25Si-1Nd alloy after high temperature deformation are investigaied by optical microscope and transmission electron microscope. It is found that the Nd-rich phase particles are 1.0～14 μm in diameter and uniformly distributed in ihe matrix, and the majority of the particles are elliptical. Under high temperature deformaiton, high stress concentration occurs on the particles, the particles near to sphericity are obtained.
关键词:
: Ti alloy
,
null
,
null
LI Geping
,
LI Dong
,
LIU Yuyin
,
HU ZhuangqiInstitute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang
,
China
金属学报(英文版)
For the as-cast Ti-55 alloy, the morphology of the alloy riser consists of coarse dendrite zone and equiaxial grain zone. The second phase particles are 2.0-25 um in diameter. Some particles appear at grain boundaries, the others precipitate within grains. The shapes of the particles are mainly ellipsoids, and a few kinds of short needle-like and block v morphologies. The Nd-rich phase particles are enriched in the liquid before the inter face and are engulfed along the solidification plane-front. Finally, bands of Nd-rich phase par-ticles form parallel to the advancing solidification plane-front.
关键词:
Ti-55 alloy
,
null
,
null
李志宏
,
柳卫平
,
白希祥
,
郭冰
,
连钢
,
颜胜权
,
王宝祥
,
陆昀
,
曾晟
,
苏俊
原子核物理评论
doi:10.3969/j.issn.1007-4627.2005.01.006
利用8Li次级束测量了质心系能量7.8 MeV 2H(8Li, 9Li)1H反应的角分布, 导出了8Li(d, p)9Li反应的天体物理S因子及9Li→8Li+n虚衰变的渐近归一化系数.
关键词:
8Li(d,p)9Li反应
,
角分布
,
天体物理S因子
,
渐近归一化系数
HUANG Jianshun CHEN Junming Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai
,
China Research Associate
,
Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai 200050
,
China
金属学报(英文版)
Crystal structure of γ-Li_xFe_2O_3,inserted Li electrochemically,was studied by Moss- bauer spectroscopy together with X-ray diffraction,XPS and electrochemical method,On the insertion of Li at low current density,the crystal structure is keeping original spinel; while at higher current density or by thermal activation,owing to violent movement of Li~+ ions,part of crystal structure transforms into rock type similar to face-centered cubic structure of ferrous oxide.The transition channels during insertion of Li~+ ions and limitation of Li~+ ions inserted were discussed.
关键词:
null
,
null
,
null
Journal of Materials Research
The effect of Li(3)N additive on the Li-Mg-N-H system was examined with respect to the reversible dehydrogenation performance. Screening Study with varying Li(3)N additions (5, 10, 20, and 30 mol%) demonstrates that all are effective for improving the hydrogen desorption capacity. Optimally, incorporation of 10 mol% Li(3)N improves the practical capacity from 3.9 wt% to approximately 4.7 wt% hydrogen at 200 degrees C, which drives the dehydrogenation reaction toward completion. Moreover, the capacity enhancement persists well over 10 de-/rehydrogenation cycles. Systematic x-ray diffraction examinations indicate that Li(3)N additive transforms into LiNH(2) and LiH phases and remains during hydrogen cycling. Combined structure/property investigations suggest that the LiNH(2) "seeding" should be responsible for the capacity enhancement, which reduces the kinetic barrier associated with the nucleation of intermediate LiNH(2). In addition, the concurrent incorporation of LiH is effective for mitigating the ammonia release.
关键词:
complex hydrides;improvement;mixtures;imides;amide;h-2
MANG Weishi WANG Guozhi ZHANG Yongchang HU Zhuangqi SHI Changxu Institute of Metal Research
,
Academia Sinica
,
Shenyang
,
China Yongchang Associate Professor
,
Institute of Metal Research
,
Academia Sinica
,
Shenyang 110015
,
China
金属学报(英文版)
A rapidly solidified microcrystalline Al-Li-Cu-Mg-Zr alloy and its superplasicity have been investigated.An optimum tensile elongation of 585% was obtained at 540℃ and strain rate 1.67×10~(-2)s~(-1).The superplastic Al-Li alloy is manufaetured using thermomechanical pro- cessing:solution,overaging,warm rolling and recrystallization.Microstructural changes in thermomechanical processing and cavitation occurred during superplastic deformation have been observed.The superplastic failure of alloy may be caused mainly by nucleation and growth of cavities as well as the linkage around grains.
关键词:
superplasticity
,
null
,
null
,
null
