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Densification of the Tungsten Heavy Alloys at 1473 K and Fabrication of W-Mo System FGM with Density Gradient

Huaping XIONG , Lianmeng ZHANG , Junguo LI , Runzhang YUAN

材料科学技术(英文)

The tungsten heavy alloys with Ni-Al and Fe-Al additives were sintered by hot-press method at 1473 K for 1 h. It was found that the relative density of the W-Fe alloy could be increased evidently by addition of Al. However, the relative density of W-Ni-Al alloy with low content of Al was conversely decreased considerably compared with that of W-Ni alloy. The causes have been studied. The sintering experiments of Mo alloy and W-Mo alloys with 3 wt pct Fe-1.5 wt pct Al additives were also carried out under the same sintering condition of low temperature. Finally, W-Mo system FGM with density gradient was successfully fabricated. Its density changed gradually from 17.0´103 kg/m3 to 9.5´103 kg/m3 within the middle 1.1 mm thickness range.

关键词:

Densification of Mo Alloys at 1473 K by Adding Ni-Cu Solid Solution

Daoren GONG , Zhongmin YANG , Qiang SHEN , Lianmeng ZHANG

材料科学技术(英文)

Mo is difficult to sinter densely at a relatively low temperature due to its high melting point. In the present paper, by adding different weight contents of Ni and Cu additives, Mo alloys have been densified at 1473 K for an hour by hot-pressing method, and the optimum contents of Cu and Ni additives have been acquired: when the contents of Ni and Cu are 3 and 2 wt pct respectively, the relative density of the sample reaches the maximum value. It was found that when the Ni-Cu solid solution was added into Mo alloys, the achieved density is higher than the case of Ni and Cu additives. The experimental results indicate that, Ni and Cu play different roles in the process of sintering, the Ni-Cu solid solution has the same function as Ni and Cu additives in the course of sintering Mo alloys, It shows more activating sintering feature for Mo than the Ni and Cu additives.

关键词: Mo alloys , null , null , null

Fabrication of Al/Al2O3 composites and FGM

Hong TAO , Chengji DENG , Lianmeng ZHANG , Runzhang YUAN

材料科学技术(英文)

Al/Al2O3 composites of different ratios were hot-press sintered at 575 similar to 640℃ under a pressure of 30 MPa for 2 h in a vacuum furnace. It was found that the relative density of the Al/Al2O3 composites could be increased evidently with the rise of sinter temperature. No reaction occurred between Al and Al2O3 at the sinter temperatures. Under 640℃-30 MPa-2 h experimental condition, Al/Al2O3 system FGM was successfully fabricated, and its density range changed quasi-continuously from 2.887x10(3) kg/m(3) to 3.1909x10(3) kg/m3 within the middle 1.0 mm thickness range.

关键词:

Synthesis and Sintering of ZrNiSn-based Half-Heusler Compounds

Qiang SHEN , Lianmeng ZHANG , Lidong CHEN , Takashi GOTO , Toshio HIRAI

材料科学技术(英文)

In contrary to the commonly used arc melting method, samples in the present paper were prepared by the solid state reaction from elemental powders at 1173 K under a flowing Ar atmosphere for 96~168 h. The constituent phases and the elemental compositions were determined and shown that the samples were of single phase and stoichiometry. Then the spark plasma sintering technique was used to consolidate them. It is found that, dense ZrNiSn-based compounds with fine grain size and homogeneous microstructure were achieved under the condition of 1123 K/40 MPa/25 min.

关键词: ZrNiSn , null , null , null

Calculation of the Composition Profile of a Functionally Graded Material Produced by Co-sedimentation

Zhongmin YANG , Lianmeng ZHANG , Qiang SHEN

材料科学技术(英文)

A sedimentation method is proposed to fabricate functionally graded materials (FGMs) with the continuous and smooth variations of composition. The relations between the compositional distribution of deposited body and the powder characteristics of raw materials as well as settling parameters are derived. Subsequently, the mathematical model of forming FGM based on the co-sedimentation has been established. At last, numerical simulations are conducted to explore the effects of the particle sizes of raw materials and suspension height on the compositional distribution of final products.

关键词: Calculation , null , null

Effect of Cu Addition on W-Ni-Fe Alloys Sintered at a Low Temperature

Chuanbin WANG , Qiang SHEN , Lianmeng ZHANG

材料科学技术(英文)

In this study, Cu was added as the third additive to lower the sintering temperature of W-Ni-Fe alloy. By adding 2 wt pct Cu, a dense 93W-3.5Ni-1.5Fe-2.0Cu tungsten alloy was obtained by hot-pressing at a low temperature of 1573 K which is a process of liquid-phase sintering. As a result, the morphology of W-Ni-Fe alloy changed obviously after the addition of Cu and the alloy had higher relative density and rupture strength. The mechanism of the densification of W-Ni-Fe-Cu alloy at the low temperature was then mainly investigated. It was found that, part sintering activators Ni and Fe could exist in liquid form at 1573 K due to the addition of Cu, which made it easy for Ni and Fe to dissolve W and thus the full densification of W-Ni-Fe-Cu alloy at the low temperature was realized.

关键词: W-Ni-Fe alloy , null , null

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

Broer-Kaup-Kupershmidt方程的新精确解

杨立娟 , 杨琼芬 , 杜先云

量子电子学报 doi:10.3969/j.issn.1007-5461.2012.02.003

CK方法是求解非线性发展方程的一种有效的直接方法.利用推广的CK方法,求得(2+1)维Broer-Kaup-Kupershmidt方程的Backlund公式,从而获得方程的大量新的精确解,推广了Xu和Zhang的结果.

关键词: 非线性发展方程 , Broer-Kaup-Kupershmidt方程 , 精确解 , CK方法 , Backlund变换

Three-dimensional (3D) Ising universality in magnets and critical indices at fluid-fluid phase transition

Phase Transitions

Experimental data for critical exponents in some magnetic materials are compared with recent theoretical results on the three-dimensional (3D) Ising model, as derived by one of us (ZDZ) based on two conjectures [Z.D. Zhang, Conjectures on the exact solution of three-dimensional (3D) simple orthorhombic Ising lattices, Phil. Mag. 87 (2007), pp. 5309-5419]. It is found that critical exponents in some bulk magnetic materials indeed form a 3D Ising universality. Our attention is then focused on the critical indices at fluid-fluid phase transition. We suggest to use Zhang's exponent = 3/8 to fit the experimental data over the wider asymptotic region near the critical point of a fluid-fluid phase transition. The 3D Ising universality should exist for critical indices in a certain class of magnets and at fluid-fluid phase transition.

关键词: magnetically ordered materials;fluid-fluid;phase transitions;order-disorder effects;ferromagnetic curie temperature;liquid critical phenomena;x-ray-scattering;critical exponents;critical-point;coexistence;curves;binary-solutions;ionic-solutions;behavior;equation

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