新型炭材料
The uptake of hydrogen in carbon nanotubes is a hot topic in carbon nanotube research. Currently there are two methods to store hydrogen in carbon nanotubes. One is based on gas phase hydrogen storage and the other is based on an electrochemical method. Fundamental principles, theoretical calculations, and the interaction between hydrogen and carbon nanotubes for electrochemical hydrogen storage are reviewed. In particular, an overview of the most recent progress on electrochemical hydrogen storage in both single-walled carbon nanotubes and multi-walled carbon nanotubes is given and the prospect of their use in high performance batteries is highlighted.
关键词:
carbon nanotubes;electrochemistry;gas storage;nanofibers;adsorption
新型炭材料
Electrochemical capacitors (ECs) store energy in eletric double-layers formed along the interface of electrode material and electrolyte, this produces an extremely large capacitance compared with the traditional capacitors. The fundamental principles of electrochemical capacitors are briefly introduced, and the key materials used like electrode materials, electrolytes, separator and current collector materials are summarized. Electrochemical capacitors with pseudocapacitance, such as metal oxides, polymers and hybrid capacitors, are also discussed. The characteristics, possible application fields, the development state, the future R&D prospects for electrochemical capacitors are highlighted.
关键词:
electrochemical capacitors;supercapacitors;storage of electric energy;principles
新型炭材料
The state-of-the-art research and development of various carbons for possible application as the electrode material in electrochemical capacitors (ECs) are summarized. The main factors affecting the properties of ECs are carefully reviewed, from the material characteristics such as specific surface area, pore size distribution and pore volume, surface functional groups and graphitic orientation of the carbon materials, to the electrode characteristics and electrochemical aspects such as electrode preparation process, electrode density and thickness, electrode conductivity and pseudo-capacitance, etc. In particular, an overview is given of the most recent progress in electrochemical capacitors using carbon nanotubes as the electrode material and the prospect of their use in this application is highlighted.
关键词:
electrochemical capacitors;carbon electrode;carbon nanotubes;double-layer capacitors;activated carbon;nanotube electrodes;supercapacitor electrodes;organic electrolyte;deposition;fiber
Gang YU
,
Xueyuan ZHANG
,
Yuanlong DU
材料科学技术（英文）
The principle, construction and application of two types of electrochemical sensors-amperometric and potentiometric are surveyed. Both types of sensors are very sensitive to changes in temperature. The accuracy of hydrogen measurement depends on both the precision of sensors developed and the reliable technique of installation and security of sensors. The two types of sensors have been used for in-situ determining hydrogen permeated in steels owing to a corrosive reaction, a hydrogen gas circumstance at elevated temperatures and high pressure or also a pretreatment process such as pickling and plating process, etc.
关键词:
材料科学技术（英文）
The principle, construction and application of two types of electrochemical sensors-amperometric and potentiometric are surveyed. Both types of sensors are very sensitive to changes in temperature. The accuracy of hydrogen measurement depends on both the precision of sensors developed and the reliable technique of installation and security of sensors. The two types of sensors have been used for in-situ determining hydrogen permeated in steels owing to a corrosive reaction, a hydrogen gas circumstance at elevated temperatures and high pressure or also a pretreatment process such as pickling and plating process, etc.
关键词:
monitoring hydrogen;probe
Corrosion Science
An electrochemical investigation was carried out to study the corrosion of pure magnesium in 1 N NaCl at different pH values involving electrochemical polarisation, scanning tunnel microscopy (STM), measurement of hydrogen gas evolution and measurement of the elements dissolved from the magnesium specimen which were determined by inductively coupled plasma atomic emission spectrophotometry (ICPAES). A partially protective surface film was a principal factor controlling corrosion. Film coverage decreased with increasing applied electrode potential. Application of a suitable external cathodic current density was shown to inhibit magnesium dissolution whilst at the same time the hydrogen evolution rate was relatively small. This showed that cathodic protection could be used to significantly reduce magnesium corrosion. A new definition is proposed for the negative difference effect (NDE). (C) 1997 Elsevier Science Ltd.
关键词:
magnesium;electrochemical corrosion;cathodic protection;STM;kinetics;behavior;mg
YANG Jilian ZHANC Baisheng DINC Yongfan China Institute of Atomic Engergy
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Beijing
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ChinaYANG Yingchang ZHANG Xiaodong Peking University
,
Beijing
,
ChinaPAN Shuming General Research Institute for Non-Ferrous Metals
,
Beijing
,
China associate professor
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P.O.Box 275
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Branch No.30
,
Beijing 102413
,
China
金属学报(英文版)
The N occupying sites and magnetic structures in R_2Fe_(17)N_x(R=Y,Dy,Nd)are de- termined by neutron diffraction.The effects of the site occupation of N on magnetic properties are discussed primarily.
关键词:
neutron diffraction
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