S.S. Xie
,
X.F. Pan
,
T.L. Wang
,
Z.X. Wang
,
H.C. Yang and Q. Wang ( School of Materials and Metallurgy
,
Northeastern Universityl Shenyang 110006
,
China)( School of Materials and Metallurgy
,
Northeastern Universityl Shenyang 110006
,
China)( School of Materials and Metallurgy
,
Northeastern Universityl Shenyang 110006
,
China)( School of Materials and Metallurgy
,
Northeastern Universityl Shenyang 110006
,
China)( Institute of Metal Research
,
The Chinese Academy of Science
,
Shenyang 110015
,
China)( Liaoning Machinery Industry Foreign Trade Co. Ltd.
,
Shenyang 110002
,
China)
金属学报(英文版)
Threshold stress values, muging from ～8 to 16MPa·m1/2 can be obtained in a Ni-base alloy GH586 by varying the microstructure through heat treatments. The threshold and low crack growth rate behaviors at room temperature, with varying groin size and γ'-distribution, have been investigated. The results indicate that grain size is an important microstructurol parameter that affects fatigue crack growth threshold and propagation behaviors, as the values of △Kth increase with increasing grain size, but the γ' -distribution also has important effect. Analyses show that the effects of groin size on threshold and low crack-growth rate behavior result from heterogeneous deformation and roughness-induced crack closure due to crystallographic slipping and cracking in coarse microstructure. The higher △Kth and lower fatigue crack growth rate with increasing amounts of fine γ' phases are closely related to less damage accumulation level in deformation zone of crack-tip resulted from heterogeneous deformation due to dislocations' shearing γ' precipitates.
关键词:
superalloy GH586; fatigue crack growth; threshold; grain size;γ'-distribution
ZHANG Yun
,
LIU Yulin
,
ZHAO Hong' en
,
HU Zhuangqi
,
Institute of Metal Research
,
Academia Sinica
,
Shenyang
,
ChinaZHU Zhiyong
,
WANG Zhengfu
,
Institute of Corrosion and Protection of Metals
,
Academia Sinica
,
Shenyang
,
China ZHANG Yun
,
Associate Professor
,
Institute of Metal Research
,
Academia Sinica
,
Shenyang 110015
,
China
金属学报(英文版)
The A1-2.79Li-1.3Cu-0.7Mg-0.12Zr(8090) alloy has excellent resistance to intergranular and exfoliation corrosion as naturally aged, worst as peak aged and rather better as underaged than as overaged. The corrosion behaviour of the alloy is closely dependent on its microstructure. Under the peak aging condition, the coarse T_2 phase, which is continuously distributed along grain boundaries, has so low corrosion potential in comparison with the ma- trix, this makes the corrosion resistance of the alloy to be deteriorated by anodic dissolution along grain boundaries.
关键词:
AI-Li alloy
,
null
,
null
,
null
Author C.D. Zhou1
,
2)
,
J.X. Yu1)
,
X.P. Dong1)
,
Y.H. Zhang1)
,
C.Q. Sun3) and T.F. Li4) 1) The State Education Commission Open Research Laboratory for High Temperature Materials and Testing
,
Shanghai Jiao Tong University
,
Shanghai 200030
,
China2) Shanghai Enhanced Lab of Ferrometallurgy
,
Shanghai University
,
Shanghai 200072
,
China3) Institute of Aeronautical Materials
,
Beijing 100095
,
China 4) Institute of Corrosion and Protection of Metals
,
The Chinese Academy of Sciences
,
Shenyang 110015
,
ChinaManuscript received 18 October 1998
金属学报(英文版)
An investigation has been made on the tensile fracture behavior of oriented single crystal DD100 superalloy at 850. The appearance of the fracture surface of DD100 reflects the glide plane decohension fracture mechanism, which is different from the fracture of oriented DD100. The tensile strength and elongation are lower than the oriented DD100. Oxygen in air has little effect on the strength of DD100 but reduces the tensile elongation obviously. Oxygen does not affect the fracture mode of DD100 but strongly accelerates the process of fracture.
关键词:
single crystal superalloy
,
null
,
null
Y.Z. Yang
,
Y.H Luo
,
Q.S. Li
,
Y.L. Zhu
,
X.M. Ma
,
Y.D. Dong and Y.Z. Chuang(Department of Materials Science and Engineering
,
Guangdong University of Technology
,
Guangzhou510090
,
China)(Guangdong Educational College
,
Guangzhou 510084
,
China)(Department of Materials Science and Engineering
,
Shanghai University
,
Shanghai 200072
,
China)(Institute of Metal Research
,
The Chinese Academy of Sciences
,
Shenyang 110015
,
China)
金属学报(英文版)
The structural transformation in Fe-Cu powder induced by mechanically driven alloying has been monitored by the lattice constant measurements and Mossbauer spectroscopy. For the samples with Cu higher than 75at.% Mossbauer the spectra show a broad paramagnetic doublet; for samples with 50 and 60at.%Cu a new broad ferromagnetic sextet; for those with less than 30at.%Cu similar to those of α-Fe. The main peaks of the hyperfine field distribution significantly broaden and shift to a lower position with increasing Cu content due to the complex environments of iron atoms in the solid solutions and the reduction in the nearest neighbor Fe of a cental Fe atom, respectively. The saturation magnetization of Fe-Cu alloys monotonously decreases with Cu content. The complex composition dependence of coercive field for the milled samples is discussed with respect to the solid dissolution, grain size, interfacial state etc.. The increase of lattice constants with the solute content in the two terminal solid solutions has been explained by the volume-size factor theory or magnetovolume effect.
关键词:
mechanical alloying
,
null
,
null
,
null
HUANG Qizhong
,
YANG Qzaoqin and WU Lijun(Powder Metallurgy Research institute
,
Central Sonth University of Technology
,
Changsha 410083
,
China Materials Research and Test Center
,
Hnnan University
,
Changsha 410082
,
ChinaLab. of Atomic Imaging of Solids
,
Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang110015
,
ChinaState Key Laboratory for Corrosion and Protection
,
Institute of Corrosion and Protection of Metals
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)Manuscript received 4 August 1995
,
in revised form 6 April 1996
金属学报(英文版)
A Preliminary study of the effect of silicon additive on the structure and properites of C-B_4C-SiC composite was conducted. A liquid Phase has formed and the liquid Si reacts with C to form SiC at the grain boundary when sintering, which accelerates the sintering process and retards the grain growth. Consequently, the density and strength of the composite increase markedly. And the increase in the density increases the oxidation resistance and decreases the specific resistance of the composite. Furthermore,the C-B_4 C-SiC composite has good heat-shock resistance. The phenomena may be dueto the strengthening and toughening of microcracks.
关键词:
:Si additive
,
null
,
null
S.G. Tian
,
L.T. Zhang
,
H. M. Shao
,
L.J. Zou
,
T.F. Li
,
and H. C. Yang (Department of Materials Science
,
Shenyang Polytechnic University
,
Shenyang 110023
,
China) (Corrosion Science Laboratory
,
Institute of Corrosion and Protection of Metals
,
Chinese Academy ofSciences
,
Shenyang 110015
,
China) (Department of Materials Science
,
Northeastern University
,
Shenyang 110006
,
China)
金属学报(英文版)
In this paper, internal oxidation kinetics and the diffusion mechanism of oxygen in sintered Cu-Al alloy have been studied by means of scanning electron microscopy,transmission electron microscopy and heat-weighting scales. The results show that the kinetic curves obey the parabolic law in the initial stage and are linear in the late stage.The oxygen atoms are mainly transported in the from of grain boundary diffusion and volume diffusion in the process of internal oxidation. The plastic deformation of Cu matrix around oxide particles increases the probability of [O] atoms moving in accordance with dislocation diffusion mechanism. Meanwhile, the activation energy and diffusion coefficient in the process of internal oxidation are evaluated by means of kinetic method so as to obtain the velocity equations of reacting interface moving in different stage.
关键词:
: Cu-Al alloy
,
null
,
null
J.H.Dong 1)
,
J.Y.Chen 2
,
3) and. C.N.Cao 1) 1) State Key Laboratory for Corrosion and Protection of Metals
,
Institute of Corrosion and Protection of Metals
,
The Chinese Academy of Sciences
,
Shenyang 110015
,
China 2) The International Center for Materials Physics
,
CAS
,
Shenyang 110015
,
China 3) Shenyang Normal College
,
Shenyang 110031
,
China
金属学报(英文版)
The effect of chloride ion on the corrosion inhibition of iron caused by dencylamine(DA), dipentylamine(DDA) and dodecylamine(DPA) has been investigated by measuring the inhibitory coefficients for the anodic and cathodic processes at corrosion potential. It has been shown that the major synergistic inhibition effects between amines and chloride ions occur in the cathodic process, very weak in the anodic process. The anodic inhibition mechanism follows the competing adsorptive model, while the cathodic inhibition mechanism follows the cooperative adsorptive model.
关键词:
synergistic inhibition
,
null
,
null
K. Zhang
,
YQ. Wang
,
B.L. Zhou
,
YH. Zhou and H.L. Li (Institute of Metal Research
,
Chinese Academy of Scie11ces
,
Shenyang 110015
,
China International Center of Materials Physics
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China Dept. of Materials Science and Engineering
,
Northwestern Polytechnical University
,
Xi'an 710072
,
China)
金属学报(英文版)
The mechanical properties and deformation mechanisms of unidirectional carbon fiber reiopreed magnesium composites under tensile loading are studied. Two different materials are used as fiber coatings: a single silica and a gradient C/SiC/SiO2. The results show that, under the same preparation conditions, composite with the former coating is broken in a non-cumulative mode and its failure stress is rather low. Conversely, the latter coating demonstrates much better efficiency and the cormsponding composite is broken in a cumttlative mode.
关键词:
tensile properties
,
null
,
null
F. Gesmundo
,
Y Niu
,
F. Vianiand D.L. Douglass(Universita di Genova
,
Fiera del Mare
,
Pad. D
,
16129 Genova
,
Italy)(State Key Lab. for Corrosion and Protection
,
Institute of Corrosion and Protection of Metals
,
theChinese Academy of Sciences
,
Shenyang 110015
,
China)(University of Arizona
,
4715 East Fort Lowell Road
,
TUcson
,
AZ 85712
,
USA)
金属学报(英文版)
The cormsion in air of a two-phase Cu-75Cr alloy was studied at 700-900℃. Thealloy cormded nearly parabolically at 700-800℃, but at 900℃ its instantaneousparabolic mte constant decreased with time. The scales were complex and consistedof an outermost layer of copper oxide generally followed bg a layer of the double ox-ide Cu2 Cr2 O4 sometimes containing particles of unoxidized chromium surmunded bya chromia layer. An innermost layer of chromia was also observed in some cases.Finally metallic copper was al8o frequently mixed with chromia particles. No Cr de-pletion was observed in the alloy close to the inteffoce with the scale. In any case,this alloy was not able to form an exclusive continuous protective chromia layer. Thespecial cormsion behavior Of this alloy is typical of two-phase binary systems with alange solubility gaP in which the outwaof dthesion fiux of the most-reactive componentin the alloy is strongly reduced and may be inswncient to fOrm a protective externallayer of the cormsponding oxide. In paTticular, the presence of particles of Cr withina double oxide layer is very unusual and is allowed only for the kinetic reason.
关键词:
copper-chromium
,
null
,
null
,
null
D. W Shi
,
J. Y Huang and Q. W Long(International Centre for Materials Physics
,
Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China Laboratory of Atomic Imaging of Solids
,
Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang 110015
,
ChinaState Key Laboratory for Fatigue and Fracture of Materials
,
Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China )
金属学报(英文版)
We proposed an equation of Langevin type to describe the interface evolution in crystals under nonequilibrium conditions(such as in Cu-Fe or Cu-Co system upon ball miling). The scaling property (H) of this equation is in good agreement with the Monte Carlo simulations decribed by Bellon and Averback. In this equation the volume dchsion and intedece diffusion are all important and this is consistent with some experimental results.
关键词:
scaling
,
null
,
null
,
null
