Junbao ZHANG
,
Guangwu WEN
,
Tingquan LEI
,
Dechang JIA
,
Jiancun RAO
材料科学技术（英文）
Si-B-O-N powder without B-O bonds synthesized by polymeric precursor were hot-pressed into ceramics at different temperatures. The variations of microstructure and mechanical properties of Si-B-O-N ceramics have been investigated. Crystallization of Si-B-O-N ceramics occurred at about 1400°C. Density, elastic modulus, and flexural strength of the ceramics increased with the increasing sintering temperatures, and reached to their maximum values at 1600°C. By contrast,hardness and fracture toughness of the ceramics monotonically changed with increasing sintering temperatures. Hardness decreased, while the fracture toughness increased. The principal toughening mechanisms including crack deflection, crack bridging and plate grain pulling-out effects are discussed
关键词:
Si-B-O-N ceramics
,
null
,
null
,
null
Jianjun WU
,
Yun ZHANG
,
Yutian SHEN
,
Guobin LI
,
Tingquan LEI
材料科学技术（英文）
The thermodynamics and kinetics of the internal oxidation in dilute Cu-Al alloy are investigated. The internal oxidation of copper alloy containing 0.2-1.2 wt pct Al is studied in the temperature range from 1073 K to 1273 K. A related equilibrium diagram is drawn. A mathematic model of oxidation layer depth is developed on the base of the experimental results. The experiments and investigation show that the formation rate of the internal oxidation layer is mainly controlled by the diffusion of O in matrix, the O concentration on the surface and the Al concentration in the alloy.
关键词:
Yujin WANG
,
Yu ZHOU
,
Guiming SONG
,
Tingquan LEI
材料科学技术（英文）
In order to improve the high temperature strength of tungsten, 30~vol. pct ZrC particles were added to the tungsten matrix to form a 30ZrCp/W composite. The tensile properties from 20℃ to 1880℃ of the composite were examined. It was shown that with increasing testing temperature, the nonlinearity of the stress strain curve of 30ZrCp/W composite becames obvious over 1200℃ and the Young’s modulus decreases and the elongation increases. The ultimate tensile strength increases at first and then decreases with increasing testing temperature. The maximum strength of 431 MPa was obtained at 1000℃. The strengthening mechanism at high temperatures is the load transfer to ZrC particles and dislocation strengthening of the tungsten matrix with an effect of grain boundary strengthening.
关键词:
ZrCp/W composite
,
null
,
null
,
null
Junbao ZHANG
,
Tingquan LEI
,
Guangwu WEN
,
Yu ZHOU
材料科学技术（英文）
Amorphous silicon oxynitride powders have been obtained by pyrolysis of polysiloxazane in a stream of anhydrous NH3 at the temperature up to 1000℃. The polysiloxazane is fabricated from ammonolysis of chloropolysiloxane that is produced by the hydrolysis of silicon tetrachloride. The conversion of polysiloxazane to silicon oxynitride and the structural features of the final powders have also been studied by infrared spectra, elemental composition and X-ray diffraction analysis and SEM observation.
关键词:
Yujin WANG
,
Yu ZHOU
,
Guiming SONG
,
Tingquan LEI
材料科学技术（英文）
The elevated temperature mechanical properties of TiCp/W composites produced using powder metallurgical technique were investigated. Results show that with increasing temperature, the strength of TiCp/W composites increases gradually and reaches its maximum value at 1000℃, which is much higher than that at room temperature. The strengthening mechanisms at high temperature are attributed to dislocation strengthening and load transfer between matrix and particles.
关键词:
Yingkui GUO
,
Yu ZHOU
,
Dongbo LI
,
Xiaoming DUAN
,
Tingquan LEI
材料科学技术（英文）
2Y-PSZ/TRIP steel composites have been sintered by hot-pressing method. Their microstructure and mechanical properties were investigated by means of SEM, TEM, XRD and static tension, split Hopkinson pressure bar method. The results showed that the strength and elastic modulus of 2Y-PSZ/TRIP steel composites at room temperature decreased with the increase of 2Y-PSZ content. The main reason was that the combining strength was quite weak between the grains of ZrO2. Distortion induced martensite transformation and plasticity during the dynamic loading increased the strength and distortion capability of the composites. The transformation was carried out mainly through twins formation. The shape of martensite induced by distortion was lamellate with substructures of twins. The habit plane was near {259}γ with no mid-ridge and no explosion phenomena. The interface was straight between the austenite and martensite induced by distortion. The increase of 2Y-PSZ content, on the one hand, made the composite dynamic flow stress improved. Thereby, the fracture strength was improved. On the other hand, it depressed both the distortion capability and the martensite transformation induced by distortion. This resulted in the decrease of dynamic fracture strength.
关键词:
2Y-PSZ/TRIP steel composites
,
null
Jiancun RAO
,
Jiancheng GU
,
Yu ZHOU
,
Feng YE
,
Tingquan LEI
材料科学技术（英文）
BAS glass-ceramic powders were prepared by sol-gel processing. SiC platelets reinforced BAS glass-ceramic matrix composites with high density and uniform microstructure could be made using hot-pressing method. The related processing parameters were studied in this work, including effects of additional seed on transformation from H to M of barium aluminosilicate. DTA method was used to determine exact time to press mixture powders during hot-pressing for the purpose of effective densification. Microstructure and mechanical properties of the composites were investigated by mean of SEM, XRD and TEM techniques as well as three points bending test and single edge notched beam measurement. The results showed that the flexural strength and fracture toughness value of the BAS glass-ceramic matrix composites could be effectively improved by the addition of the SiC platelets. But the relative densities of composites were slightly decreased. The main toughening mechanism is crack deflection, platelets' pull-out and bridging. The increased value of flexural strength is contributed to the load transition effect from matrix to SiC platelets.
关键词:
Jianjun WU. Yun ZHANG
,
Yanfei JIANG
,
Meiyun XUE
,
Tingquan LEI
材料科学技术（英文）
This work concerns with the high temperature deformation of internally oxidized Al2O3/Cu composites. The investigation revealed that dispersive alumina can obstruct dislocation sliding and define the subgrain size thereby improve significantly the strength of the materials at high temperature. The sliding of dislocations is a main deformation mechanism in the given temperature range. The sliding of grain boundary and diffusive creep play important roles at high temperature and low strain rate. The dispersoids can raise the recrystallization temperature to higher than 1223 K. Dynamic recovery is a main softening way under the experimental conditions. Higher deformation rate and lower deformation temperature imply a higher flow stress.
关键词:
