H.Z. Huang
,
X.Q. Wei
,
L. Zhou
,
null
,
null
金属学报(英文版)
The potential of using a hypoeutectic, instead of eutectic, Sn-Zn alloy as a lead-free solder has been discussed. The nonequilibrium melting behaviors of a series of Sn-Zn alloys were examined by differential thermal analysis. It was found that at a heating rate of 5℃ / min, Sn-6.5Zn exhibited no melting range. Dipping and spreading tests were carried out to characterize the wettability of Sn-Zn alloys on Cu. Both tests exhibited that Sn-6.5Zn has significantly better wettability on Cu than Sn-9Zn. The reaction layers formed during the spreading tests were examined. When the Zn concentration fell between 2.5wt%-9wt%, two reaction layers were formed at the interface, a thick and flat Cu5Zn8 adjacent to Cu and a thin and irregular Cu-Zn-Sn layer adjacent to the alloy. Only a Cu6Sn5 layer was formed when the Zn concentration decreased to 0.5wt%. The total thickness of the reaction layer(s) between the alloy and Cu was found to increase linearly with the Zn concentration.
关键词:
lead-free solder
,
Sn-Zn合金
,
润湿性
,
界面
,
金属间化
L. Zhou
,
X.Q. Wei
,
N.G. Zhou
金属学报(英文版)
Molecular dynamics simulations of high temperature annealing of copper bicrystals
have been carried out. The bicrystals have planar grain boundaries, and the gain
size varies in nano range. An EAM(Embedded Atom Method) potential of FS type is
used for calculating the interatomic forces. The results show that in nanocrystalline
copper, GB migration driven by inter-GB reaction can take place. A critical grain
size is identi¯ed, below which the inter-GB reaction becomes strong enough to trigger
GB motion, which accelerates rapidly and leads to annihilation of the grain bound-
aries. The critical size is found to be 16 atomic radii. A \through intermediate grain
mechanism" is identi¯ed for the nano-grain boundary motion observed, which is never
reported for GB migrations of conventional polycrystalline metals.
关键词:
grain boundary migration
,
null
,
null
原子核物理评论
研究了高电荷态离子~(40)Ar~(q+)(q=7-14)轰击金属Au表面产生的特征X射线谱.实验结果表明,在弱束流(nA量级)的情况下,对于动能相同的入射离子,当电荷态比较高(q=11)时,便能有效地激发靶原子的特征X射线,单离子的X射线产额高达10~(-8)量级.分析结果显示,入射离子的势能、动能和这种相互作用特有的镜像相互作用势能沉积在靶表面,使靶原子内壳层电子激发和电离,形成空穴和产生外壳层电子填充空穴辐射特征X射线,特征X射线的产额随入射离子的势能(电荷态)的增加而增加.
关键词:
高电荷态离子
,
X射线
,
产额
杜翠薇
,
王胜荣
,
刘智勇
,
李晓刚
,
朱敏
,
李琼
,
黄一中
,
刘明
腐蚀学报(英文)
doi:10.11903.1002.6495.2014.210
通过土壤理化性质分析、现场埋样的腐蚀形貌观察、腐蚀产物的扫描电镜观察和X射线衍射分析以及腐蚀失重实验等分析手段,研究了国产X70钢和Q235钢在新加坡土壤中现场埋样1a后的短期腐蚀行为特征.结果表明,新加坡土壤属于酸性土壤;埋样1a后Q235钢平均腐蚀速率略大于X70钢,两种钢以局部腐蚀为主,Q235钢的局部腐蚀较严重;两种钢的腐蚀产物组成相似,均为Fe2O3,Fe3O4,FeOOH和FeOCl,腐蚀产物表面粗糙,存在裂纹与空隙,从而加速局部腐蚀的进行.
关键词:
X70钢
,
Q235钢
,
酸性土壤
,
土壤腐蚀
王燕
,
闫永贵
,
董超芳
,
钱建华
,
李晓刚
腐蚀学报(英文)
通过腐蚀速率测定、腐蚀形貌观察、腐蚀坑深度测量及分形维数计算等方法,研究了杂散电流作用下涂层破损率对Q235、16Mn和X70钢腐蚀的影响.结果表明,杂散电流作用下,Q235钢腐蚀程度最严重,16Mn次之,X70最小;随杂散电流增大和涂层破损率减小,腐蚀速率和腐蚀坑深度均相应增大,腐蚀程度加剧;根据"盒子"维法测定杂散电流腐蚀形貌的分形维数,反映的腐蚀规律与实测腐蚀速率吻合,分形维数可定量表征杂散电流腐蚀形貌.
关键词:
杂散电流腐蚀
,
涂层破损率
,
腐蚀速率
,
分形维数
,
腐蚀坑深
田为中
,
钱蓉
,
喻筱静
,
齐鸣
功能材料与器件学报
doi:10.3969/j.issn.1007-4252.2007.06.019
在介电常数为2.20±0.02,厚度为254μm的Rogers5880衬底上用混合集成技术制作了9.5~10.5GHz平衡,I-Q矢量调制器.测试结果表明:各状态插入损耗为(7.5±1)dB,回波损耗大于16dB,均方根(RMS)相位误差小于5.,各状态之间的幅度不平衡小于0.5dB,可实现对9.5~10.5GHz载波信号的直接QPSK调制.文中还提出电路性能优化的一些方法.
关键词:
Rogers5880
,
I-Q矢量调制器
,
BPSK调制器
屈婧婧
,
魏星
,
经本钦
,
刘飞
,
袁昌来
无机材料学报
doi:10.15541/jim20150155
采用固相法制备了(1-x)(Sr0.2Nd0.208Ca0.488) TiO3-xNd(Ti0.5Mg0.5)O3(0.3≤x≤0.4,SNCT-NTMx)系微波介质陶瓷材料,并研究了该体系的相组成、显微结构、烧结性能和微波介电性能之间的关系.结果表明:在x=0.3~0.35范围内,SNCT-NTMx陶瓷形成了正交钙钛矿固溶体,并伴随有少量未知第二相;当x增至0.4时,第二相含量有所增加.介电性能研究结果显示:随着x的增加,体系介电常数(εr)减小,但品质因子(Q×f)得到改善;此外,体系谐振频率温度系数(τf)随NTM含量的增加逐渐向负值方向移动.当x=0.35,陶瓷样品在1520℃烧结4h得到的微波介电性能较优:εr=50.1,Q×f=44910 GHz,τf=-1.7× 10-6/℃.
关键词:
(Sr0.2Nd0.208Ca0.488)TiO3
,
Nd(Ti0.5Mg0.5)O3
,
钙钛矿
,
微波介电性能
裴锋
,
田野
,
刘平
,
田旭
腐蚀与防护
doi:10.11973/fsyfh-201609005
采用扫描电镜(SEM)、能谱(EDS)和X射线衍射(XRD)等技术对在红壤中服役多年的变电站接地网Q235碳钢进行了形貌观察和腐蚀产物分析,并通过电化学和模拟加速腐蚀试验对比研究了Q235碳钢在红壤中的腐蚀行为.0结果表明:接地网材料表面形成的腐蚀产物主要是铁的氧化物毒要有Fe2O3Fe3O4FeoOH,并且C1元素的存在会加剧Q235碳钢材料的腐蚀;当土壤含水率为20%(质量分数,下同)时,Q235碳钢在红壤中腐蚀速率最大,Q355碳钢的腐蚀电流密度随Cl与SO的变化规律基本一致,都是先增大后减小,并且可划分为3 个区间;Q235碳钢在红壤中的腐蚀速率随着试验时间的延长呈现先降低后小幅升高的趋势,该加速腐蚀试验,没有改变Q235碳钢在红壤中的腐蚀机理,且与现场有较好的相关性.
关键词:
接地网
,
Q235碳钢
,
红壤
,
电化学
,
加速腐蚀