YC. Liu
,
G.C. Yang
,
YL. Lu and Z.G. Zhu (State Key Lab. of Solidification Processing
,
Northwestern Polytechnic University
,
Xi'an 710072
,
China Laboratory of Internal Friction and Defects in Solids
,
Chinese Academy of Science
,
Hefei 230031
,
China )
金属学报(英文版)
The effects of cerium modification and extrusion on the resultant damping behavior and mechanical properties of the as-sprayed high silicon alloy ZA27 were investigated in an thort to develop a new functional material possessing high damping capacity and good mechanical properties. The damping capacity, as well as the rslative dynamic modulus, was tneasured at frequencies of 1 and 4 Hertz over the 30 to 200℃runge. At below 80℃ the as-sprayed materials appear to be approximately Asquency independent. Above 80℃, the,naterials becotne temperature sensitive, exhibiting the highest damping for the lowest hequency. The extruded, as-sprayed high silicon alloy ZA27 modified by cerium has the highest damping capacity and elongation values among them. The micro8tructure of the as-sprayed high silicon alloy ZA27 modified by 0. 5 wt% cerium was made up of fine lamellar eutectoid, porositg, a light dot-like phase and a polygonal silicon-rich phase. Finally, the opemtive damping tnechanisms were discussed in light of the data obtained hem characterization of microstructure and damping capacity. The high damping capacity was attributed primarily to phase interface thermoelastic damping between the lamellar phases with various substrvctures,except for the grain refinement.
关键词:
spray deposition
,
null
,
null
,
null
Communications in Theoretical Physics
By using the theory of pressure-induced shifts and the eigenfunctions at normal and various pressures obtained from the diagonalization of the complete d(3) energy matrix adopting C-3v symmetry, g factors of the ground state of ruby and their pressure-induced shifts have been calculated. The results are in very good agreement with the experimental data. For the precise calculation of properties of the ground state, it is necessary to take into account the effects of all the excited states by the diagonalization of the complete energy matrix.
关键词:
crystal fields;g factors;ruby;high-pressure effects
Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing
The microstructural evolution during solidification and subsequent solid-state transformation of AISI 304 stainless steel is studied by directional solidification and quenching methods in this paper. The phase transformation sequence in the steel directionally solidified is that the precipitation of primary ferritic dendrites, ferrite-austenite eutectic reaction, and the direct formation of austenite occur in sequence during the directional solidification of the austenitic stainless steel. At the eutectic reaction stage, plenty of columnar and cellular eutectic colonies composed of the coupled growth of lamellar ferrite and austenite take place. During the course of subsequent solid-state transformation, austenite grows into ferrite gradually, resulting in the disappearing of eutectic colonies and thinning of primary ferritic dendrites, and dendrite cores of primary ferrite are retained as the final skeletal ferrite in the final microstructure. (c) 2006 Elsevier B.V. All rights reserved.
关键词:
austenitic stainless steel;directional solidification;eutectic colony;austenitic stainless-steel;cr-ni alloys;sequence;welds
Wenjing Yao
材料科学技术（英文）
The liquid-solid transitions of (Co2Si+CoSi) and (CoSi+CoSi2) eutectic alloys were realized in drop tube and the rapid eutectic growth mechanism of intermetallic compounds was examined. The experimental and calculated results indicate that with increasing Co content, the intermetallic compound prefers nucleating primarily. The eutectic microstructures experience the transitions of `lamellar-anomalous-divorced' eutectic with undercooling. In undercooled state, the growth of CoSi intermetallic compound always lags behind others, and no matter how large the undercooling is, this intermetallic compound grows under the solutal diffusion control. The calculated coupled zone demonstrates that (Co2Si+CoSi) eutectic can form within certain undercooling regime, when the composition is in the range from 23.6% to 25.4% Si. And the calculated coupled zone of (CoSi+CoSi2) covers a composition range from 40.8% to 43.8% Si.
关键词:
Liquid-solid transition
Sen YANG
,
Yunpeng SU
,
Wenjin LIU
,
Weidong HUANG
,
Yaohe ZHOU
材料科学技术（英文）
The detailed laser surface remelting experiments of Cu-31.4 wt pct Mn and Cu-26.6 wt pct Mn alloys on a 5 kW CO2 laser were carried out to study the effects of processing parameters (scanning velocity, output power of laser) on the growth direction of microstructure in the molten pool and cellular spacing selection under the condition of ultra-high temperature gradient and rapid directional solidification. The experimental results show that the growth direction of microstructure is strongly affected by laser processing parameters. The ultra-high temperature gradient directional solidification can be realized on the surface of samples during laser surface remelting by controlling laser processing parameters, the temperature gradient and growth velocity can reach 106 K/m and 24.1 mm/s, respectively, and the solidification microstructure in the center of the molten pool grows along the laser beam scanning direction. There exists a distribution range of cellular spacings under the laser rapid solidification conditions, and the average spacing decreases with increasing of growth rate. The maximum, λmax, minimum, λmin, and average primary spacing, , as functions of growth rate, Vb, can be given by, λmax=12.54 , λmin=4.47 , =9.09 , respectively. The experimental results are compared with the current Hunt-Lu model for rapid cellular/dendritic growth, and a good agreement is found.
关键词:
Laser surface remelting
,
null
,
null
,
null
Communications in Theoretical Physics
By using the wavefunctions obtained from diagonalizing the complete d(3) energy matrix at normal and various pressures, the g factor of the ground state of SrTiO3:Cr3+ and its pressure-induced shift have been microscopically calculated. Only by taking the local strains around Cr3+ in SrTiO3:Cr3+ (which are about twice the bulk ones) and corresponding P-chi dependence, can we obtain a good agreement between the calculated result of pressure-induced shift of ground-state g factor and the experimental one. The physical origins of this pressure-induced shift have been explained. It is found that the change of Dq(-1) with pressure makes main contribution to the pressure-induced shift of ground-state g factor of SrTiO3:Cr3+. By using the wavefunctions obtained from diagonalizing the complete d3 energy matrix at normal pressure, the relevant matrix elements and accordingly strain-induced splittings of t(2)(3) E-2 and t(2)(3) (4)A(2) of SrTiO3:Cr3+ have been calculated. The important results of Y-c, Z(c), P-c and Q(c) have also been evaluated. It is the admixtures of basic wavefunctions resulted from the spin-orbit interaction and/or Coulomb interaction and/or Kramers degeneracy that make the strain-induced splittings of the levels nonzero. It is found that there are nonvanishing matrix elements of operators T2 xi, T2 eta and T2 zeta between wavefunctions with positive M-s and those with negative M-s', which have important effects on the strain-induced splittings of the levels.
关键词:
crystal fields;energy spectrum;g factors;high-pressure effect;strain-induced splitting;theoretical calculations;ruby;crystal
Journal of Materials Science
The Pd77.5Au6Si16.5 alloy was studied by drop-tube processing. Palladium solid-solution phase was found in smaller droplets (diameter D < 400 m), while in larger droplets, the intermetallic compound Pd3Si was observed. The difference in free energy between the undercooled liquid and the solid state, the activation energy for the formation of post-critical nuclei, the nucleation frequency and the crystal growth velocity, were calculated as functions of temperature for palladium solid solution and Pd3Si phases. These calculations led to time-temperature-transformation curves which were capable of describing the experimental findings on the kinetics of solidification of this alloy.
关键词:
metallic glasses;solidification
Chunju WANG
,
Debin SHAN
,
Bin GUO
,
Jian ZHOU
,
Lining SUN
材料科学技术（英文）
From the viewpoint of production engineering, microforming is considered as an effective process to fabricate various microparts. Several key problems in microforming processes were investigated. A new microforming apparatus with a high stiffness piezoelectric actuator as the punch driver was developed to produce microparts. To improve the forming abilities and locate the billets, a floating microdie was designed. The size effects of the billets and die cavities on the microforming abilities were studied with upsetting and coining tests, respectively. And the isothermal microforming process of microgears was performed with the developed microforming apparatus. Several analysis methods were used to evaluate the forming quality of the microparts.
关键词:
Microforming
,
尺寸效应
,
微塑性成形设备
,
浮动
