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THEORETICAL PREDICTION OF THE KINETICS CURVES OF PEARLITIC TRANSFORMATION IN HYPO-PROEUTECTOID STRUCTURAL STEELS

Z.G. Li , H.B. Chang , T. Y. Hsu , Z. Y. Xu , and X. Y. Ruan (Department of Plasticity of Technology , Shanghai Jiao Tong University , Shanghai 200030 , China)(Department of Metallurgical Engineering , Shanghai Technical College of Metallurgy , Shanghai 200233 , China)(Department of Materials Science , Shanghai Jiao Tong University , Shanghai 200030 , China)

金属学报(英文版)

Supposing carbon contents of ferrite phases in pearlite precipitating from austenite in multicomponent steel at temperature T and in Fe-C ystem at T' are the same the pearlite formation temperature diference, can be calculated from the FeX phase diagrams and the equilibrium temperature Al. Using Tp and Fe-C binary thermodynamic model, the driving forces for phase transformation from austenite to pearlite in multicomponent steels have been successfully calculated. Through the combination of simplified Zener and Hillert's model for pearlite growth with Johnson-Mehl equation, using data from known TTT diagrams, the interfacial energy parameter and activation energy for pearlite formation can be determined and expressed as functions of chemical composition in steels by regression analysis. The calculated starting curves of pearlitic transformation in some commercial steels agree well with the experimental data.

关键词: pearlite formation temperature difference , null , null

Improving plasticity and toughness of Cu-Zr-Y-Al bulk metallic glasses via compositional tuning towards the CuZr

Journal of Materials Research

In this work, we propose a simple approach for designing plastic bulk metallic glasses (BMGs) by exploiting the ductility of intermetallic compounds involved in the BMG-forming system. Its validity was examined by investigating a series of quaternary CuZr-Y-Al alloys along the composition tie-line between Cu(42)Zr(44.4)Y(3.6)Al(10) (Y1) and the B2 CuZr phase, expressed as (Cu(0.5)Zr(0.5))(x)(M)(100-x) (M = Zr(0.15)Y(0.225)Al(0.625), 84 <= x <= 93). When tuning the composition towards the CuZr, the glass-forming ability of alloys is dramatically degraded, showing a reduction of critical diameter D(c) for BMG formation from 16 mm at x = 84 (Y1) to 2 mm at x = 93. As the composition of BMGs shifts to the CuZr terminal, the shear modulus mu of the BMGs decreases, whereas the Poisson's ratio nu increases. With respect to the Y1 BMG, compressive plasticity and toughness of the Y2 BMG (x = 92, D(c) = 4 mm) with a higher concentration of the CuZr are improved, which is consistent with its lower mu and higher nu values.

关键词: intermetallic compounds;forming ability;alloys;compression;brittleness;ductility;density;system;range;flow

On plasticity and fracture of nano structured Cu/X (X = Au, Cr) multilayers: The effects of length scale and interface/boundary

Acta Materialia

Plastic deformation and fracture behavior of two different types of Cu/X (X = Au, Cr) multilayers subjected to tensile stress were investigated via three-point bending experiments. It was found that the plastic deformation ability and fracture mode depended on layer thickness and interface/boundary. The Cu/Au multilayer showed significant features of plastic flow before fracture, and such plasticity was gradually suppressed by premature unstable shearing across the layer interface with decreasing layer thickness. In comparison, Cu/Cr multilayers were prone to a quasi-brittle normal fracture with decreasing layer thickness. Both experimental observations and theoretical analyses revealed differences in plasticity and fracture mode between the two types of metallic multilayers and the relevant physical mechanism transition due to length scale constraint and interface/boundary blocking of dislocation motion. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

关键词: Multilayers;Plastic deformation;Fracture;Length scale;Interface;thin-films;mechanical-properties;metallic multilayers;ag/cu;multilayers;composites;deformation;nanocrystalline;strength;behavior;nanoindentation

Mg-Cu-(Y,Nd) pseudo-ternary bulk metallic glasses: The effects of Nd on glass-forming ability and plasticity

Scripta Materialia

We report the improvement of glass-forming ability by using Nd to substitute Y in the Mg-Cu-Y bulk metallic glass (BMG). A search in the Mg-Cu-(Y,Nd) pseudo-ternary system located the best glass former at the Mg57Cu31Y6.6Nd5.4 composition, where the critical size for BMG formation (diameter D-c for copper mold casting) reached at least 14 mm. In comparison with the ternary Mg-Cu-Y glass, the Nd-containing BMG, without a significant change in Poisson's ratio, exhibits higher strength and improved compressive plasticity. (c) 2006 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

关键词: metallic glasses;bulk amorphous materials;magnesium;rare earth;ductility;mechanical-properties;amorphous-alloys;air atmosphere;gd;ag;strength

Development and application of universal formability technology

Yanwu Xu

材料科学技术(英文)

Using mathematical plasticity theories, universal formability (UF) technology has been developed and applied in the automotive stamping engineering and production. As a formability analysis tool, this technology is the major methodology for the development of stamping expert system (solution provider) for (a) product design and feasibility analysis, (b) material automatic selection using nomograms, (c) draw die design using pre-models, and (d) UF and robustness analysis of die performance in finite element analysis (FEA) environment.

关键词:

Multiferroic phase diagram of Y partially substituted Dy(1-x)Y(x)MnO(3)

Applied Physics Letters

The effect of nonmagnetic Y partial substitution at the Dy site in Dy(1-x)Y(x)MnO(3) up to x=0.2 on magnetism, specific heat, and ferroelectricity is investigated, which resulted in a preliminary multiferroic phase diagram. It is revealed that the Y partial substitution suppresses the Dy-spin ordering point (T(Dy)) and ferroelectric ordering point (T(FE)) but enhances the Mn-spin ordering point (T(N)). The interaction between the spins of Dy and Mn is remarkably affected by Y substitution. The measured electrical polarization depends on the Y substitution in a complex way because the ferroelectricity is sensitive to the interaction between the spins of Dy and Mn. (c) 2011 American Institute of Physics. [doi: 10.1063/1.3536506]

关键词: ferroelectricity;polarization

Glass-forming ability for Nd(70-x)Fe(20)Al(10)Y(x) and Nd(60-x)Fe(30)Al(10)Y(x) alloys

材料科学技术(英文)

The glass-forming ability (GFA) of Nd(70-x)Fe(20)Al(10)Y(x) and Nd(60-x)Fe30Al(10)Y(x) (0 less than or equal to x less than or equal to15) alloys produced by Cu mold casting was investigated. Except Y = 5 at. pct, bulk amorphous Nd(70-x)Fe(20)Al(10)Y(x) alloys up to 2 mm in diameter were obtained. The GFA for Nd(60-x)Fe(30)Al(10)Y(x) alloys, however, was found to decrease with increase of Y due to the increasing compositional deviation from the original eutectic point of Nd(60)Fe(30)Al(10) alloy. The Nd(60)Fe(20)Al(10)Y(10) and Nd(60)Fe(30)Al(10) alloy exhibit the largest GFA and can be cast into bulk amorphous cylindrical specimens of 3 mm in diameter. The melting temperature or/and the reduced crystallization temperature is closely related to the GFA of Y-containing alloys. The bulk amorphous cylinder for the Nd(55)Fe(20)Al(10)Y(15) alloy shows a distinct glass transition temperature and a wide supercooled liquid region before crystallization. The crystallization temperature, T(g), and the supercooled liquid region, DeltaT(x), are 776 K and 58 K, respectively, The GFA and thermal stability of the Nd-Fe-Al-Y alloys were discussed.

关键词: Nd-based alloys;glass forming ability;liquidus temperature;thermal;stability;supercooled liquid region;bulk amorphous-alloys;metallic glasses;transition temperature;thermal-stability;atomic size;ni alloys;cu;alloys;diameter;tm

Y_2Fe_(17-x)Mn_x的结构和磁性

尹晓英 , 王寅岗 , 唐宁 , 杨伏明

金属学报

X射线衍射证实Y2Fe17-xMnx(x≤6.0)的结构与Y2Fe17相同.Y2Fe17-xMnx化合物的晶格常数、居里温度、饱和磁化强度的研究结果表明:晶格常数并非随Mn含量的增加而连续增大,而是在x=2.0处出现一最小值.居里温度由x=0的328K上升到x=0.3的342K,以后随Mn含量增加而下降.Y2Fe17-xMnx化合物的饱和磁化强度随Mn含量增加而急剧减小.

关键词: Y_2Fe_(17-x)Mn_x , X-ray diffraction , Curie temperature , magnetization

Study of properties of mixed ferro-ferrimagnetic ising compounds with (A(x)B(1-x))(y)C

Communications in Theoretical Physics

The magnetic properties of the mixed ferro-ferrimagnetic compounds with (A(x)B(1-x))(y)C-z where A(z) B-z and C are three different magnetic ions and form three different sublattices, are studied by using the standard mean-field theory. The phase diagram which is related to experimental work of molecule-based ferro-ferrimagnet ((NixMn1-xII)-Mn-II)(1.5)[Cr-III(CN)(6)].zH(2)O is obtained. The magnetization curves(z) internal energy(z) and specific heat of the same mixed (A(x)B(1-x))(y)C system are also investigated.

关键词: mixed ferro-ferrimagnet;Ising model;phase diagram;internal energy;specific heat;mean-field analysis;magnetic-properties;prussian blue;alloy

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