材料期刊网

Gammasphere上裂变丰中子核核结构若干前沿领域的新进展(Ⅰ:第一和第二部分)

罗亦孝 , J.H.Hamilton , J.O.Rasmussen , A.V.Ramayya , C.Goodin , A.V.Daniel , N.J.Stone , 朱胜江 , J.K.Hwang , 刘少华 , C.J.Beyer , 李科 , H.L.Crowell , D.Almehed , S.Frauendorf , A.Covello , V.Dimitrov , 张敬业 , 车兴来 , 姜卓 , D.Fong , A.Gelberg , I.Stefanescu , A.Gargano , E.F.Jones , P.M.Gore , I.Y.Lee , G.M.Ter-Akopian , Yu.Ts.Oganessian , M.A.Stoyer , R.Donangelo , 马文超 , J.D.Cole , J.Kormicki , 张学谦 , S.C.Wu , J.Gilat , T.N.Ginter , S.J.Asztalos

原子核物理评论

使用Gammasphere多探测器系统对252Cf裂变源瞬发γ射线进行γ-γ-γ和γ-γ(θ)符合测量,裂变丰中子原子核核结构若干前沿领域的深入研究获得了新的进展.高达5.7×1011以上的三重和更高重符合事件的数据统计,以及更少压缩的三维数据为宽广未知丰中子核区的寻找和研究提供了有利的条件.在具有重要物理意义的若干丰中子核区首次建立,或显著扩展了一批包括转晕态和转晕附近能态的高自旋能级纲图.在偶-偶丰中子核110,112Ru和108Mo中鉴别出了手征对称破缺结构.丰中子110,112Ru附近核的三轴形变基态具有最低的能量,在它们之中已确认了接近最大值的三轴形变.在这些Ru和Mo同位素中观察到的手征双线能带展示出手征破缺的一切特征,特别是其理想的能量简并,表明它们在迄今已报道的手征破缺结构中,具有最好的手征特性.研究了手征结构从具有γ软度的108Ru到具有大三轴形变的110,112Ru的过渡.斜轴推转(TAC)和随机相近似(RPA)理论计算成功地拟合了在这些偶-偶丰中子核中观察到的手征双线能带的特性,并指定其为软手征振动态.在这些偶-偶核中观察到的手征破缺不可能归纳为奇-奇核中那样的简化的几何图像.前者来自闭壳外所有中子的相互作用.对双幻核132Sn附近N=83同中素链的系统研究为这个极富吸引力的核区提供了大量新的谱学信息.N=83同中素135Te(Z=52),134I(Z=53),137Xe(Z=54),138Cs(Z=55)和139Ba(Z=56)的最新能级信息,特别是首次建立的138Cs高自旋能级纲图和壳模型理论计算表明,Z=50质子闭壳外少数g7/2价质子激发同N=82中子闭壳外之唯一F7/2价中子的耦合对该核区能级结构具有关键作用.观察到了132Sn和208Pb附近核区谱学信息的相似性和相对应的三粒子和五粒子态.在135Te中观察到了磁转动,这是在双幻核132Sn附近观察到的首例磁转动.

关键词: 丰中子核 , 高自旋 , 转晕态 , 裂变 , 252Cf , γ射线三重符合 , 角关联 , Gammas-phere多探测器系统 , 手征对称破缺 , 三轴形变 , 斜轴推转(TAC)计算 , 软手征振动 , N=83同中数链 , 双幻核132Sn , 壳模型计算 , 磁转动 , 谱学相似性

Gammasphere上裂变丰中子核核结构若干前沿领域的新进展(II:第三和第四部分)

罗亦孝 , J.H.Hamilton , J.O.Rasmussen , A.V.Ramayya , C.Goodin , A.V.Daniel , N.J.Stone , 朱胜江 , J.K.Hwang , 刘少华 , C.J.Beyer , 李科 , H.L.Crowell , D.Almehed , S.Frauendorf , A.Covello , V.Dimitrov , 张敬业 , 车兴来 , 姜卓 , D.Fong , A.Gelberg , I.Stefanescu , A.Gargano , E.F.Jones , P.M.Gore , I.Y.Lee , G.M.Ter-Akopian , Yu.Ts.Oganessian , M.A.Stoyer , R.Donangelo , 马文超 , J.D.Cole , J.Kormicki , 张学谦 , S.C.Wu , J.Gilat , T.N.Ginter , S.J.Asztalos

原子核物理评论

使用Gammasphere多探测器系统对252Cf裂变源瞬发7射线进行γ-γ-γ和γ-γ(θ)符合测量,A～100(Z～40,N＞56)丰中子核区关于形状过渡、形状共存和形状突变的深入研究获得了新的进展.奇-Z核的系统研究揭示了从Z=39(Y)同位素的轴对称大四极形变到Z=43(Tc),44(Ru)和45(Rh)同位素中具有中等四极形变之大三轴形变的过渡.Nb(Z=41)同位素具有过渡核的特征.根据邻近同位素和同中素带交叉信息的系统性及推转壳模型(CSM)计算,Tc和Rh偶-N同位素中观察到的带交叉产生于一对h11/2中子的转动顺排.首次观察到100Nb(Z=41,N=59)的高自旋能级纲图和形变态,从而证实了100Nb中的形状共存,并确认,在Nb同位素链上,基态形状突变发生于N=58(球形)到N=59(大形变);而在Sr(Z=38),Y(Z=39)和Zr(Z=40)各同位素链上,基态形状突变均发生于N=59(球形)到N=60(大形变).100Nb具有大形变基态,同现有理论预言相矛盾,其大形变的基态及转动带所具有的很大的和不规则的转动惯量具有重要的理论意义. 对奇-质子Cs(Z=55)和La(Z=57)丰中子同位素八极激发的详细研究,发现了141,143,144Cs同位素链上电二极矩D.随中子数增加而减小的急剧变化,此前在145,147La中观察到的电二极矩Do的较缓和的减小似乎亦很陡地下延至148La.在Cs和La同位素中观察到的电二极矩D.的急剧下降很可能同偶-质子核146Ba和224Ra中观察到的电二极矩D.的急剧下降相类似,后者已获反射非对称平均场壳修正理论的成功解释.实验证明,141Cs具有很大电二极矩D.141Cs和142Xe中观测到的很大的电二极矩D.和仅在141Cs中观察到的电二极矩D.的simplex量子数相关性需要进一步的理论研究.根据转动频率比值ω-(I)/ω+(I)的检定,同Xe同位素一样,认定Cs同位素中包括号143Cs的八极激发为八极振动,而在La同位素中存在八极形变.

关键词: 形状过渡 , 轴对称形状 , 三轴形变 , 形状突变 , 带交叉 , 奇-质子 , 八极激发 , B(E1)/B(E2)比值 , 电二极矩D0 , 二极矩的下降 , 八极振动 , Cs,La同位素

CARBIDES IN STEEL 4335 V

ZHONG Jiaxiang ZHENG Xiuhua XU Zongrui Beijing Institute of Technology , Beijing , ChinaBAI Dezhong Nei Monggol Machine Works No.2 , Nei Monggol , China Beijing Institute of Technology , Beijing 100081 , China

金属学报(英文版)

Three types of alloy carbides have been observed in tempered steel 4335V:M_3C,M_7C_3 and M_4C_3.The precipitation temperatures are 200—700,400 and 500 ℃ respectively.The com- position,morphologies and distribution patterns of the carbides as well as the relationship be- tween them and as-quenched substructures have been investigated.The influence of the car- bides on the low temperature impact toughness of the steel has also been discussed.

关键词: steel 4335V , null , null

The Effect of Temperature on the Electrochemical Behavior of the V(IV)/V(V) Couple on a Graphite Electrode

International Journal of Electrochemical Science

The electrochemical behavior of the V(IV)/V(V) couple in an aqueous solution of 2 mol dm(-3) H(2)SO(4)+2 mol dm(-3) VOSO(4) on a graphite electrode at different temperatures is studied by steady-state polarization and electrochemical impedance spectroscopy. The results show that the diffusion coefficient (D) of V(IV) species increases from 1.60x10(-5) to 3.15x10(-5) cm(2) s(-1) with temperature from 15 to 70 degrees C and the activation energy for diffusion of V(IV) species is 10.52 kJ mol(-1). The anodic oxidation of V(IV) is a mixed kinetic-diffusion controlled process at the anodic polarization ranged from 32 to 132 mV vs. open circuit potential (OCP). The rate constant of charge transfer for the anodic oxidation of V(IV) increases from 1.2x10(-5) to 17.7x10(-5) cm s(-1) with temperature varied from 20 to 60 degrees C, and its activation energy is 52.4 kJ mol(-1).

关键词: Vanadium redox flow battery;graphite electrode;impedance;kinetic;parameter;activation energy;redox flow battery;positive half-cell;carbon electrodes;impedance;mechanism;state

Tetragonal distortion of the tetragonal V2+-V-M center in KBr : V2+ crystal

Journal of Physics and Chemistry of Solids

The tetragonal distortion for the tetragonal V2+-V-M center in KBr:V2+ crystal is estimated by analyzing its EPR data from two theoretical models, one is the two spin-orbit (S.O.) parameter model where the contributions to EPR parameters from both the S.O. coupling of the central metal ion and that of the ligands are considered and another is the conventional one-S.O.-parameter model where only the contribution from the S.O. coupling of the central metal ion is included. The result from the two-S.O.-parameter model is more than ten times that of the one-S.O.-parameter model. The reasonableness of the former is discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.

关键词: inorganic compounds;crystal fields;defects;electron paramagnetic;resonance (EPR);epr parameters;transition;ions

THERMODYNAMICS OF V REDUCTION IN SMELTING REDUCTION SLAG FOR V-Ti-CONTAINING MAGNETITE

ZHANG Binhuai LIU Qingcai LI Changwei ZOU Deyu SUN Jinbiao Chongqing University , Chongqing , China professor , Department of Metallurgy and Materials Engineering , Chongqing University , Chongqing 630044 , China

金属学报(英文版)

For slag system of CaO-SiO_2-Al_2O_3-MgO-V_2O_5,the time of V reduction to appro ch the dynamical equilibrium is about 6 h,the equilibrium time is not evidently influenced by the ratio CaO/SiO_2 and shortens with the increase of temperature.It the ratio of the weight of slag to that of iron bath is 1/2,CaO/SiO_2 0.8 and tomperature 1773 K.the maxium distribution coefficeent of V reduction is 32.4 and maxium recovery of V is 96.1%.

关键词: magnetite , null , null , null

以Ti/V/Cu、V/Cu为中间层的TiAl合金

何鹏 , 张秉刚 , 冯吉才 , 钱乙余

宇航材料工艺 doi:10.3969/j.issn.1007-2330.2000.04.012

用真空扩散连接方法对TiAl/Ti/V/Cu/40Cr钢及TiAl/V/Cu/40Cr钢进行了研究。结果表明，以Ti/V/Cu作中间层的接头拉伸强度高于以V/Cu作中间层的接头强度。界面分析显示，Ti/V、V/Cu、Cu/40Cr钢的各个结合界面处未形成金属间化合物，而TiAl/Ti的结合界面上有Ti3Al产生；在TiAl/V的界面上有Ti3Al、Al3V两种金属间化合物产生；界面上脆性金属间化合物的产生是接头发生断裂的原因。

关键词: 扩散连接 , 界面反应 , TiAl , Ti3Al

高V钢中V(C,N)沉淀强化作用的研究

徐曼 , 孙新军 , 刘清友 , 董瀚 , 雍岐龙 , 黄金亮

钢铁钒钛 doi:10.3969/j.issn.1004-7638.2005.03.002

通过实验室轧钢试验,研究了三种高V钢轧制状态下的组织的和力学性能,并用透射电镜观察了V(C,N)析出的状况.结果表明,高V钢中可以获得单相的铁素体组织,并可以获得较高的强度,最高的屈服强度值达到525 MPa.对C3钢而言,由V(C,N)析出颗粒的沉淀强化造成的屈服强度增量最大可达244 MPa.透射电镜观察结果表明,高V钢中容易获得相间析出.试验获得的V(C,N)析出颗粒为4～10 nm,经计算分析,该尺寸在V(C,N)最大沉淀强化效果的范围.

关键词: 高V钢 , 单相铁素体组织 , 沉淀强化 , 相间析出

LATTICE PARAMETERS OF COMPLEX CARBONITRIDE CONTAINING Ti,Nb AND V

XU Wenchong SUN Fuyu Central Iron and Steel Research Institute , Ministry of Metallurgical Industry , Beijing , China XU Wenchong Senior Engineer , Dept.No.13 , Central Iron and Steel Research Institute , Ministry of Metallurgical Industry , Beijing 100081 , China

金属学报(英文版)

The lattice constants and chemical composition of Ti,Nb and V precipitates with different particle sizes have been measured hy means of CBED and EDAX.It was obtained that the concentration ratio Of Nb and V,C_(Nb)/C_V,and the lattice constants in the Nb-V steel de- crease with the decrease of the particle size of the precipitates,but there is no regularity for tattice constant of Ti,N b and V precipitate against their particle size in the Ti-V-Nb steel.

关键词: microalloyed steel , null , null

V元素对Ti-V-Cr系阻燃钛合金热强性的影响

辛社伟 , 赵永庆 , 曾卫东 , 吴欢 , 杨海瑛 , 李倩

稀有金属材料与工程

配制不同V含量的3种阻燃钛合金,分别测试其在不同热暴露和蠕变工艺下的热稳定性能和蠕变性能,并观察其显微组织.结果表明,随V元素含量的增加,合金热稳定性能和抗蠕变性能提高,并且V元素的含量对热稳定性能和蠕变性能的影响存在一个最佳含量,小于该含量时,V元素含量对热稳定性能和抗蠕变性能影响较大,大于该含量时,含量增加对其性能影响不大.在讨论中指出,V元素对热稳定性能和蠕变性能的影响主要表现在对β相稳定性的影响,对TiCr2相形成过程的影响和与空位的相互作用三个方面,并详细论述了其机理.

关键词: 阻燃钛合金 , 热稳定 , 蠕变 , 力学性能