材料期刊网

Flow Control in Six-Straud Billet Continuous Casting Tundish With Different Configurations

ZHONG Liang-cai , WANG Ming-an , CHEN Bo-yu , et al

钢铁研究学报(英文版)

A 1:2.5 scale tundish model was set up in laboratory for a six-strand billet continuous casting tundish with different configurations to investigate fluid flowing characteristics under different operational conditions by measuring residence time distribution curves. It was known from the investigation that minimum residence time, maximum concentration time and average residence time of the three strands in the same side of the tundish with the former configuration under normal operation, that is, 6 strands were open, were small and non-uniform and the tundish had large dead volume fraction. Vortexes easily formed on the liquid surface in the pouring zone of the tundish. The fluid flow characteristics in the tundish with the optimal turbulence inhibitor and baffles were improved and became less non-uniform among the strands. Vortexes were not found on the pouring zone surface in the optimal tundish. Under un-normal operation, that is, one strand was close, it was important to choose which strand should be closed for flowing characteristics of the rest two strands. It was found from this investigation that fluid flowing characteristics in the optimal configuration tundish with closing strand 2 were better than those with closing strand 3 at the same side.

关键词: billet continuous casting;six strand tundish;physical modeling;flow characteristic;operational mode

Chen系统的状态变量周期性反馈控制

李开明 , 李亚洲 , 冯维贵 , 林长

量子电子学报 doi:10.3969/j.issn.1007-5461.2007.05.014

采用非线性反馈控制,用附加了带参数的正弦项对Chen系统进行了有效的控制.随着参数k的逐渐增大,系统的动力学行为呈现出一系列的变化.数值研究结果表明:随控制参数的增大,驱动信号的强度渐大,混沌系统由混沌运动到周期轨道,最终到一相点.

关键词: 混沌 , Chen系统 , 不动点 , Lyapunov指数 , 反馈控制

CaYO(BO3)3晶体坩埚下降法生长

罗军 , 钟真武 , 范世(马豈) , 王锦昌

人工晶体学报 doi:10.3969/j.issn.1000-985X.2000.01.005

本文首次报道了Ca4YO(BO3)3(YCOB)晶体的坩埚下降法生长.在1600～1650℃炉温下,固液界面处的纵向温度梯度为40～60℃/cm,以0.2～0.6mm/h的生长速率,在近封闭的Pt坩埚中生长出了直径达25mm、长度超过50mm的完整透明YCOB晶体.介绍了生长工艺和原料制备,观察发现晶体中的主要宏观缺陷是包裹体.分析了包裹体生成的原因.

关键词: 布里奇曼法 , Ca4YO(BO3)3晶体 , 非线性光学材料 , 包裹体

Synthesis, structure and magnetic properties of Fe-Gd nanocapsules coated with B2O3/H3BO3 and Fe3BO5+GdBO3

Physica B-Condensed Matter

Nanocapsules consisting of B2O3/H3BO3 encapsulating Fe-Gd cores have been synthesized by an arc-discharge process using metal-boron alloys as cathode. Most of the nanocapsules have a well-constructed shell/core structure with a uniform B2O3/H3BO3 shell. Heat-treatment induces reactions between the shell and the core, resulting in the formation of a Fe3BO5+GdBO3 matrix embedded with Fe nanoparticles, reduction of the metallic-core size and decrease of the blocking temperature T-B. Above T-B, the magnetization curves plotted vs. H/T overlap and show zero coercivity. Below T-B, the coercivity shows a linear dependence when plotted vs. T-1/2. However, the coercivity-T-1/2 curve below 60 K has a different slope from that above 60 K, indicating the existence of two different magnetic phases in the nanocapsules. Different from bulk Fe3BO5, nanoscale Fe3BO5 particles have a lower transition temperature to the weak-ferromagnetic state. and magnetic hysteresis is absent due to size effects. (C) 2004 Elsevier B.V. All rights reserved.

关键词: nanocapsules;transmission electron microscopy (TEM);X-ray;photoelectron spectroscopy (XPS);magnetic properties;arc-discharge;boric-acid;boron;carbon;oxide;nanoparticles;particles;diborane;iron

Na3La9O3(BO3)8的晶体结构

张国春 , 傅佩珍 , 李云阁 , 吴以成

人工晶体学报 doi:10.3969/j.issn.1000-985X.2005.05.001

以Na2CO3-H3BO3为助熔剂,用顶部籽晶法生长出Na3La9O3(BO3)8单晶.测定了Na3La9O3(BO3)8晶体结构,结果表明:该晶体属六方晶系,空间群:P62m,晶胞参数为a=b=0.89229(13)nm,c=O.87366(17)nm,α=β=90°,γ=120°,Z=1,V=0.60240(17)nm3,密度为5.066g/cm3.晶体结构中的硼氧基团是平面的BO3基团,BO3基团相互独立,通过与Na(1)O6、La(1)O9和La(2)O8的配位多面体连结形成层状结构,所有层平行于(001)面.描述了Na3La9O3(BO3)8晶体在非线性光学材料领域的应用前景.

关键词: Na3La9O3(BO3)8 , 晶体结构 , 倍频效应

Na3La2(BO3)3的晶体结构

张国春 , 李云阁 , 傅佩珍 , 潘世烈 , 常峰 , 吴以成

人工晶体学报 doi:10.3969/j.issn.1000-985X.2004.04.007

以Na2CO3-H3BO3-NaF为助熔剂,使用顶部籽晶法生长出Na3La2(BO3)3透明单晶.测定了Na3La2(BO3)3的晶体结构,该晶体属正交晶系,空间群:mm2(No.38),晶胞参数为a＝0.51580(10)nm,b=1.1350(2)nm,c=0.73230(15)nm,α＝β＝γ＝90°,V＝0.42871(15)nm3,密度:.053g/cm3.晶体结构中的硼氧基团是平面的BO3基团,BO3基团相互独立,且与Na(1)O6、Na(2)O8、Na(3)O6和La(1)O9配位多面体连结形成三维网络骨架结构.讨论了Na3La2(BO3)3的晶体结构与倍频效应的关系.

关键词: Na3La2(BO3)3 , 晶体结构 , 倍频效应

Ba7(BO3)3F5晶体结构及热分析

刘剑

人工晶体学报

采用高温溶液法从BaCO3,BaF2及H3BO3混合体系中生长出了一种氟硼酸钡晶体,Ba7(BO3)3F5晶体属六方晶系,空间群为P63mc,晶胞参数:a=1.11562(15) nm,c=0.72415(14) nm,Z=2,V=0.7805(2) nm3.Ba7(BO3)3F5晶体结构是由Ba(1)O7F3基团,Ba(2)O4F3基团,Ba(3)O6F4基团和独立的BO3基团相互连接形成的三维空间网络结构.Ba7(BO3)3F5的热分析分析结果表明Ba7(BO3)3F5在1070℃同成份熔化.

关键词: Ba7(BO3)3F5 , 晶体结构 , 高温溶液法

KBe2BO3F2和RbBe2BO3F2晶体中的孪晶缺陷

余金秋 , 王晓洋 , 罗思扬 , 刘丽娟 , 陈创天

人工晶体学报

通过化学腐蚀和偏光显微镜,对KBe2BO3F2(KBBF)和RbBe2BO3F2 (RBBF)晶体中存在的一种条状孪晶缺陷进行了研究,观察了孪晶习性,探讨了其孪晶律,并结合晶体生长情况对该孪晶的形成原因进行了分析.

关键词: KBBF , RBBF , 孪晶缺陷

YBaNa(BO3)2晶体的助熔剂法生长与表征

张天真 , 李静 , 王继扬 , 张洋

人工晶体学报

采用助熔剂自发成核法,探索了生长YBaNa(BO3)2晶体的不同助熔剂体系,从中选出2Na2CO3-4H3BO3-BaCO3做助熔剂,生长了YBaNa(BO3)2晶体.采用X射线衍射(XRD),红外吸收光谱和透过光谱,差热失重分析对生长的晶体进行了表征.结果表明,晶体属于六方晶系,空间群为R3,晶胞参数为a=0.53382(2) nm,c=3.58303(19) nm.BO3-3基团存在于晶体结构中,晶体的紫外截止波长在208 nm左右,晶体在800℃时有明显的相变点.

关键词: 自发成核 , 助熔剂 , YBaNa(BO3)2晶体

Professor XU Zhong-yu and his research activities

新型炭材料

关键词: