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Temperature Rise Characteristics of CarbonContaining Chromite Ore Fines in Microwave Field

LI Ning , CHEN Jin , YAN Hong , FENG Xiumei , CUI Huijun , LIU Jinying

钢铁研究学报(英文版)

To avoid the nonuniform phenomena of heat and mass transfer of metallurgical powdery materials caused by conventional heating method, the temperature rise characteristics of carboncontaining chromite ore fines in the microwave field were investigated using microwave heating in a microwave metallurgical furnace. The experimental results show that the carboncontaining chromite ore fines have better temperature rise characteristics in the microwave field at a frequency of 245 GHz. After heated in the microwave field of 10 kW, the temperature of 1 kg carboncontaining chromite ore fines rose up to 1 100 ℃ in 7 min, at a temperature rise rate of 1571 (℃·min-1·kg-1), whereas the temperature of 1 kg carboncontaining magnetite ore fines rose only up to 1 000 ℃ in 10 min, at a temperature rise rate of 100 (℃·min-1·kg-1). With increasing carbonfitting ratios and by adding calcic lime, their heating effects changed regularly.

关键词: carboncontaining chromite ore fine;carboncontaining magnetite ore fine;microwave field;temperature rise characteristics

Decarburization Thermodynamics of High-Carbon Ferromanganese Powders During Gas-Solid Fluidization Process

GUO Li-na , CHEN Jin , ZHANG Meng , LIANG Min

钢铁研究学报(英文版)

Thermodynamic conditions of reactions between high-carbon ferromanganese powders and gas decarbonizers like O2, CO2 and water vapor were studied by thermodynamic calculation. In O2, CO2 and water vapor atmosphere, high-carbon ferromanganese powders were decarburized in a fluidized bed. When the temperature is respectively higher than 273, 1226 and 1312 K, the gas-solid decarburization reaction will occur between ferromanganese carbide on the surface of the high-carbon ferromanganese powders and different gas decarbonizers. Since metal manganese is easy to be oxidized by O2, CO2 or water vapor, the decarburization reaction will transfer into a solid-solid phase reaction of ferromanganese carbide and ferromanganese oxide, promoting external diffusion of carbon to achieve a further decarburization of high-carbon ferromanganese powders.

关键词: gas-solid fluidization , high-carbon , ferromanganese powders , gas decarbonizer , solid-phase decarburization

Microstructure of Solid Phase Reduction on Manganese Oxide Ore Fines Containing Coal by microwave heating

CHEN Jin , TIAN Peng-fei

钢铁研究学报(英文版)

Microstructure of solid-phase reduction on manganese oxide ore fines containing coal (MOOFCC) is one of important kinetics conditions of influencing microwave heating. In the condition that an atomic molar ratio of rO: rC in MOOFCC is 1:1.06 as well as a molecular molar ratio of rSiO2: rCaO is 1:1.28, 1 kg of MOOFCC is heated by microwave to reach 1000~1300℃ and hold different time respectively. Experiments show that the metal phase takes the iron-based metal compounds containing manganese as the main content. The manganese content of metal phase increases with the rise of temperature. The partical size of the metal phase is within the range from 0.01 to 0.05mm. MO2 phase in the stuff is entirely changed into MnO phase and the slag phase is mainly composed of wollastonite and manganese olivine. The stuff reduced is loose and massive as a whole with porosity of it from 30 to 45 %. The low softening-melting property and the low density of the stuff impact, to some degree, the solid-phase reduction of powder by microwave heating.

关键词: manganese oxide ore fines containing coal(MOOFCC);microwave heating;solid phase reduction;microstructure

Kinetics of Voluminal Reduction of Chromium Ore Fines Containing Coal by Microwave Heating

CHEN Jin , WANG Shebin , ZHANG Meng , LIU Jinying , ZHOU Jianxiong

钢铁研究学报(英文版)

The kinetics of voluminal reduction of chromium ore fines containing coal (COFCC) by microwave heating was studied. When the molar ratio of carbon to oxygen was 084 and that of CaO to SiO2 was 039 in COFCC, the temperaturerising rate of COFCC by microwave heating was 625 ℃/min, 6875 ℃/min, 7059 ℃/min, and 7222 ℃/min at 1 000 ℃, 1 100 ℃, 1 200 ℃, and 1 300 ℃, respectively. The results show that the voluminal reduction of COFCC by microwave heating at solidsolid phase is first order reaction, with the apparent activation energy of 51480 kJ/mol. The limiting step of reaction rate for the overall reaction is the mass transfer of CO in the reduced product layer between dielectric particles of chromium ore and coal.

关键词: kinetics;microwave heating;voluminal reduction;chromium ore fine

Gas Ionizationon During Carbothermic Reduction in Microwave Field and Its Effect

CHEN Jin

钢铁研究学报(英文版)

Ionization of gas on carbothermic reduction of metal oxides containing coal by microwave heating is studied in the paper. The result of using the conventional heating method to conduct the carbothermic reduction of metal oxides containing coal is obviously weaker than that of the microwave heating in the term of the reduction time, temperature, atom mole ratio of carbon and oxygen. After studied on the cause, it is believed that gas is ionized in carbothermic reduction of solid-solid phrase between metal oxides and coals, which accelerates progress of carbon gasification and significantly improves kinetic conditions of carbothermic reduction.

关键词:

Chen系统的状态变量周期性反馈控制

李开明 , 李亚洲 , 冯维贵 , 林长

量子电子学报 doi:10.3969/j.issn.1007-5461.2007.05.014

采用非线性反馈控制,用附加了带参数的正弦项对Chen系统进行了有效的控制.随着参数k的逐渐增大,系统的动力学行为呈现出一系列的变化.数值研究结果表明:随控制参数的增大,驱动信号的强度渐大,混沌系统由混沌运动到周期轨道,最终到一相点.

关键词: 混沌 , Chen系统 , 不动点 , Lyapunov指数 , 反馈控制

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

第27卷B辑作者索引

金属学报

Volu扣ne 27SeriesB1991AUTHOR INDEX CCAO Guanghan(曹光旱)············……6一B科6CAo weijie(曹卫恋)..················……5一B32oCAO Yilin(曹益林)··················……6一B443CHANG Xin(常听)···············……1一B48CHE Guang邻n(车广灿)·············一6一B科0CHEN Erbao(陈二保)···············……6一B410CHEN Jia....

关键词:

EFFECTIVE-MEDIUM THEORY OF PIEZOELECTRIC COMPOSITES

Journal of Applied Physics

Based on the developed multiple-scattering theory [C.-W. Nan and F. S. Jin, Phys. Rev. B 48, 8578 (1993)], an effective-medium theory (EMT) is proposed to treat coupled electromechanical behavior in composite media. The explicit relations for determining effective behavior of piezoelectric composites are derived. To illustrate the technique, numerical results of piezoelectric ceramic/epoxy composites for various particle shapes are presented over the whole range of concentrations. The EMT estimates are shown to be in good agreement with available experimental results. Porous piezoelectric ceramics are also discussed. The EMT predicts a similar critical behavior for heterogeneous piezoelectric materials to recent experiments.

关键词: electromechanical properties;ceramics

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