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ELECTROCHEMICAL STUDIES ON ANODIC DISSOLUTION OF SYNTHETIC NICKEL SULFIDES

FANG Zhaoheng CHEN Jiayong Institute of Chemical Metallurgy , Academia Sinica , Beijing , China CHEN Jiayong Institute of Chemical Metallurgy , Academia Sinica , Zhongguancun , Beijing , China

金属学报(英文版)

The anodic behavior of synthetic nickel sulfides in sulfuric acid solutions was studied.When the anodes of Ni_3S_2 ,Ni_7S_6 and NiS are actively dissolved respectively,a solid layer forms on the electrode surface with its nature and composition depending on the potentials applied. Based on the electrochemical phenomena,phase and elemental compositions of the solid layer formed on the electrode surface were determined.The apparent number of electrons transfer- red during dissolution of Ni~(2+)was also measured.It can be considered that there are three parallel reactions ocurred on the electrode:the reaction with formation of HSO_4~- or SO_4~(2-), the reaction with formation of sulfides as intermediates and the reaction of Jorming elemental sulfur.With NiS_2 as an anode,formation of SO_4~(2-)or HSO_4~- can be considered as the only re- action occurred on the electrode.

关键词: nickel sulfide , null , null

Guangzhou Institute of Energy Conversion,The Chinese Academy of Sciences,Guangzhou 510070,China

B.W. Wang , H. Shen

金属学报(英文版)

Ni-Cr System solar selective thin solid films were prepared by d.c. magnetron reactivesputtering under the atmosphere of O2 and N2. Ni-Cr alloy was chosen as targetmaterial and copper sheets as substrate. Using SEM, Spectrophotometer and Talystepto analyze the relations between the selective characteristic and the structure, theformation and the thickness of the thin films. The aim is to obtain good solar selectivethin films with high absorptance and low emittance, which is applied to flat plate solarheat collectors.

关键词: solar selective thin film , null , null , null

Recent developments in high temperature intermetallics research in China

Intermetallics

A comprehensive survey was made of various advances of intermetallics research in China. The investigation focussed on the fundamental research and materials development. Charge density distribution and site occupancy of alloying elements, environmental embrittlement and chemical reaction, interface structures and phase transformation at the atomic scale, nanocrystalline intermetallics and its thermal stability, superplastic behavior and anomalous yield strength peak are reviewed. Several Ti-Al and Ni-Al based alloys have been manufactured, and show good mechanical properties. Diverse components have been fabricated successfully. (C) 2000 Elsevier Science Ltd. All rights reserved.

关键词: aluminides, miscellaneous;hydrogen embrittlement;mechanical properties;at high temperatures;superplastic behavior;phase interfaces;grain-boundary fracture;in-situ composites;environmental;embrittlement;hydrogen embrittlement;ni3al;compression;alloys;co3ti;boron;feal

Application of Microwave Radiation to Extractive Metallurgy

LIU Chunpeng XU Yousheng HUA Yixin Kunming Institute of Technology , Kunming , 650093 , China.

材料科学技术(英文)

In applying the microwave radiation to extractive me- tallurgy,it is essential first of all to find the extent of microwave energy absorbed by various minerals experi- mentally.In this paper,more than 25 kinds of common useful minerals have been individually irradiated by a 500 W,2450 MHz microwave source in an enclosed quartz crucible to ascertain their heating temperature in a definite time.In addition,the reduction and cbloridization tests were also carried out on the titanomagnetite concentrate and pentlandite with microwave heating,respectively. These experiments indicate potential applications of util- izing microwave energy in extractive metallurgy.

关键词: microwave radiation , null , null , null

Chen系统的状态变量周期性反馈控制

李开明 , 李亚洲 , 冯维贵 , 林长

量子电子学报 doi:10.3969/j.issn.1007-5461.2007.05.014

采用非线性反馈控制,用附加了带参数的正弦项对Chen系统进行了有效的控制.随着参数k的逐渐增大,系统的动力学行为呈现出一系列的变化.数值研究结果表明:随控制参数的增大,驱动信号的强度渐大,混沌系统由混沌运动到周期轨道,最终到一相点.

关键词: 混沌 , Chen系统 , 不动点 , Lyapunov指数 , 反馈控制

MICROSTRUCTURE AND PROPERTIES OF SiC_w/6061Al COMPOSITE The Author is now with Institute of Metal Research,Academia Sinica,China

MA Zongyi YAO Zhongkai Harbin Institute of Technology , Harbin , China

金属学报(英文版)

The SiC_w/Al composite prepared by squeeze casting has a combination of superior room temperature specific strength and modulus together with excellent thermal properties.The extrusion can make an improvement on the strength and ductility of the composite from 582 MPa as squeeze casted up to 639 MPa,and on the transformation from isotropic to the anisotropic structure.This seems to be explained by the orientation of whiskers and the densification of dislocations in matrix.TEM observation indicates that the stacking fault is the usual planar defect on the SiC_w surface. composite;;SiC whisker;;Al alloy;;microstructure

关键词: composite , null , null , null

OXIDE METALLURGY-ITS PURPOSES AND PRACTICAL APPROACHES

Z. T. Ma and D. Janke(Institute of Iron and Steel Technology , Freiberg University of Mining and Technology , Germany)

金属学报(英文版)

Useder certain conditions, nonmctallic inclusions such as oxides, sulfides, nitrides and carbides are no longer harmful to sted service properties. With the new concept of oxide metallurgy, these properties can be improved by generating fine oxide inclusions which serve as heterogeneous nuclei for sulfide and fine ferrite[1-4]. A novel continuous casting (CC) process is expected to be created with the utilization of oxide metallurgy. This is also useful for the forthcoming technologies of direct rolling and near-net-shape casting. The main idea of oxide metallurgy consists of an alternative oxidation technology. It is based on steels treated by complex metals such as Ti, Zr, Ti-Zr alloys and rare earth metals. The selected deoxidants should follow the required conditions which are concluded in this paper.

关键词: oxide , null , null , null

Introduction to atmospheric corrosion research in China

Science and Technology of Advanced Materials

In this paper, we introduce the research on atmospheric corrosion in China. We describe the climate characteristics and the classification of atmospheric corrosivity across the whole country. We also describe the rusting evolution under simulated wet/dry cyclic conditions. (C) 2007 NIMS and Elsevier Ltd. All rights reserved.

关键词: atmospheric corrosion;corrosivity;rusting evolution;weathering steels;rust;mechanism;so2;o-3;no2

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